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We predict that it is possible to cool rotational, vibrational and translational degrees of freedom of molecules by coupling a molecular dipole transition to an optical cavity. The dynamics is numerically simulated for a realistic set of…

Quantum Physics · Physics 2007-08-13 Giovanna Morigi , Pepijn W. H. Pinkse , Markus Kowalewski , Regina de Vivie-Riedle

We study theoretically the behavior of laser-cooled calcium monofluoride (CaF) molecules in an optical molasses and magneto-optical trap (MOT), and compare our results to recent experiments. We use multi-level optical Bloch equations to…

Atomic Physics · Physics 2021-05-18 J. A. Devlin , M. R. Tarbutt

We provide a theory of the deflection of polar and non-polar rotating molecules by inhomogeneous static electric field. Rainbow-like features in the angular distribution of the scattered molecules are analyzed in detail. Furthermore, we…

Chemical Physics · Physics 2015-05-20 E. Gershnabel , I. Sh. Averbukh

We suggest a protocol for the sympathetic cooling of a molecular asymmetric top rotor co-trapped with laser-cooled atomic ions, based on resonant coupling between the molecular ion's electric dipole moment and a common normal mode of the…

Quantum Physics · Physics 2026-02-04 Monika Leibscher , Alexander Blech , Christiane P. Koch

The last few years have seen rapid progress in the application of laser cooling to molecules. In this review, we examine what kinds of molecules can be laser cooled, how to design a suitable cooling scheme, and how the cooling can be…

Atomic Physics · Physics 2021-12-14 N. J. Fitch , M. R. Tarbutt

We introduce a scheme for deep laser cooling of molecules based on robust dark states at zero velocity. By simulating this scheme, we show it to be a widely applicable method that can reach the recoil limit or below. We demonstrate and…

Atomic Physics · Physics 2019-07-24 L. Caldwell , J. A. Devlin , H. J. Williams , N. J. Fitch , E. A. Hinds , B. E. Sauer , M. R. Tarbutt

The resonant laser cooling of circular accelerator beams of relativistic charged particle is studied. It is shown that in the approximation of the given external electromagnetic wave amplitude (small gain free electron laser) the emittance…

Accelerator Physics · Physics 2007-05-23 R. V. Tumanian

We report laser cooling of fermionic K-40 atoms, with temperatures down to (15 +/- 5) microK, for an enriched sample trapped in a MOT and additionaly cooled in optical molasses. This temperature is a factor of 10 below the Doppler-cooling…

Statistical Mechanics · Physics 2009-10-31 G. Modugno , C. Benko , P. Hannaford , G. Roati , M. Inguscio

The term `laser cooling' is applied to the use of optical means to cool the motional energies of either atoms and molecules, or micromirrors. In the literature, these two strands are kept largely separate; both, however suffer from severe…

Optics · Physics 2018-06-05 André Xuereb

We propose to sympathetically slow and cool polar molecules in a cold, low-density beam using laser-cooled Rydberg atoms. The elastic collision cross sections between molecules and Rydberg atoms are large enough to efficiently thermalize…

Several laser techniques have been suggested and demonstrated recently for preparing polarizable molecules in rapidly spinning states with a disc-like angular distribution. We consider motion of these spinning discs in inhomogeneous fields,…

Chemical Physics · Physics 2015-05-20 Johannes Floss , Erez Gershnabel , Ilya Sh. Averbukh

Laser cooling of molecules employing broadband optical pumping involves a timescale separation between laser excitation and spontaneous emission. Here, we optimize the optical pumping step using shaped laser pulses. We derive two…

Quantum Physics · Physics 2013-12-24 Daniel M. Reich , Christiane P. Koch

Gray molasses is a powerful tool for sub-Doppler laser cooling of atoms to low temperatures. For alkaline atoms, this technique is commonly implemented with cooling lasers which are blue-detuned from either the D1 or D2 line. Here we show…

Atomic Physics · Physics 2017-04-13 G. D. Bruce , E. Haller , B. Peaudecerf , D. A. Cotta , M. Andia , S. Wu , M. Y. H. Johnson , B. W. Lovett , S. Kuhr

Cooling the rotation and the vibration of molecules by broadband light sources was possible for trapped molecular ions or ultracold molecules. Because of a low power spectral density, the cooling timescale has never fell below than a few…

Atomic Physics · Physics 2018-06-06 A. Cournol , P. Pillet , H. Lignier , D. Comparat

We have studied a general technique for laser cooling a cloud of polarized trapped atoms down to the Doppler temperature. A one-dimensional optical molasses using polarized light cools the axial motional degree of freedom of the atoms in…

Quantum Physics · Physics 2016-08-16 Piet O. Schmidt , Sven Hensler , Jörg Werner , Thomas Binhammer , Axel Görlitz , Tilman Pfau

A general scheme for rotational cooling of diatomic heteronuclear molecules is proposed. It uses a superconducting microwave cavity to enhance the spontaneous decay via Purcell effect. Rotational cooling can be induced by sequentially…

Quantum Physics · Physics 2009-11-10 C. H. Raymond Ooi

We propose and analyze a scheme for sympathetic cooling of the translational motion of polar molecules in an optical lattice, interacting one by one with laser-cooled ions in a radio-frequency trap. The energy gap between the excitation…

Atomic Physics · Physics 2015-05-19 Zbigniew Idziaszek , Tommaso Calarco , Peter Zoller

We propose a scheme for laser cooling of negatively charged molecules. We briefly summarise the requirements for such laser cooling and we identify a number of potential candidates. A detailed computation study with C$\_2^-$, the most…

Atomic Physics · Physics 2015-06-23 Pauline Yzombard , Mehdi Hamamda , Sebastian Gerber , Michael Doser , Daniel Comparat

Following excitation by a strong ultra-short laser pulse, molecules develop coordinated rotational motion, exhibiting transient alignment along the direction of the laser electric field, followed by periodic full and fractional revivals…

Quantum Physics · Physics 2007-05-23 Sharly Fleischer , Ilya. Sh. Averbukh , Yehiam Prior

We demonstrate slowing and longitudinal cooling of a supersonic beam of CaF molecules using counter-propagating laser light resonant with a closed rotational and almost closed vibrational transition. A group of molecules are decelerated by…