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The recent renaissance of black phosphorus (BP) as a two-dimensional 2D layered material has generated tremendous interest in its tunable electronic band gap and highly anisotropic transport properties that offer new opportunities for…

Mesoscale and Nanoscale Physics · Physics 2016-03-08 Shan Dong , Anmin Zhang , Kai Liu , Jianting Ji , Y. G. Ye , X. G. Luo , X. H. Chen , Xiaoli Ma , Yinghao Jie , Changfeng Chen , Xiaoqun Wang , Qingming Zhang

At ambient pressure, lithium molybdenum purple bronze (Li0.9Mo6O17) is a quasi-one dimensional solid in which the anisotropic crystal structure and the linear dispersion of the underlying bands produced by electronic correlations possibly…

Strongly Correlated Electrons · Physics 2021-06-15 M. K. Tran , A. Akrap , J. Levallois , J. Teyssier , P. Schouwink , C. Besnard , P. Lerch , J. W. Allen , M. Greenblatt , D. van der Marel

High pressure is a proven effective tool for modulating inter-layer interactions in semiconducting transition metal dichalcogenides, which leads to significant band structure changes. Here, we present an extended infrared study of the…

Phosphorene and its components are highly reactive to oxygen when exposed to ambient conditions due to the presence of lone pairs of electrons on phosphorus atoms. Functionalization serves as a solution to prevent the chemical degradation…

The objective of this work is to study the effects of charge redistribution, applied layer-normal electric fields, applied strain, and layer engineering on the band alignment of Black Phosphorus (BP)/Molybdenum disulphide (MoS2)…

Materials Science · Physics 2022-12-28 Nupur Navlakha , Priyamvada Jadaun , Leonard F. Register , Sanjay K. Banerjee

Raman spectra of the MgB2 ceramic samples were measured as a function of pressure up to 32 GPa at room temperature. The spectrum at normal conditions contains a very broad peak at ~590 cm-1 related to the E2g phonon mode. The frequency of…

Materials Science · Physics 2009-11-07 K. P. Meletov , J. Arvanitidis , M. P. Kulakov , N. N. Kolesnikov , G. A. Kourouklis

The photo-induced band structure variation of a rare-earth-based semiconductor, samarium monosulfide (SmS), was investigated using high-harmonic-generation laser-based time-resolved photoelectron spectroscopy. A nonlinear photo-induced band…

The layer interdependence of transport in an undoped electron-hole bilayer (uEHBL) device was studied as a function of carrier density, interlayer electric field, and temperature. The uEHBL device consisted of a density tunable,…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 C. P. Morath , J. A. Seamons , J. L. Reno , M. P. Lilly

We propose the nano-scale displacement sensor with high resolution for weak-force systems could be realized based on vertical stacked two-dimensional (2D) atomic corrugated layer materials bound through Van der Waals (VdW) interaction.…

Materials Science · Physics 2015-06-11 Lin Hu , Jin Zhao , Jinlong Yang

Based on {\em ab initio} density functional calculations, we propose $\gamma$-P and $\delta$-P as two additional stable structural phases of layered phosphorus besides the layered $\alpha$-P (black) and $\beta$-P (blue) phosphorus…

Materials Science · Physics 2015-06-22 Jie Guan , Zhen Zhu , David Tománek

Black phosphorus is a quasi-two-dimensional layered semiconductor with a narrow direct band gap of 0.3 eV. A giant surface Stark effect can be produced by the potassium doping of black phosphorus, leading to a semiconductor to semimetal…

Materials Science · Physics 2021-07-21 G. Kremer , M. Rumo , C. Yue , A. Pulkkinen , C. W. Nicholson , T. Jaouen , F. O. von Rohr , P. Werner , C. Monney

Heterogeneous integration strategies are increasingly being employed to achieve more compact and capable electronics systems for multiple applications including space, electric vehicles, and wearable and medical devices. To enable new…

Preceding the current interest in layered materials for electronic applications, research in the 1960's found that black phosphorus combines high carrier mobility with a fundamental band gap. We introduce its counterpart, dubbed few-layer…

Mesoscale and Nanoscale Physics · Physics 2014-04-25 Han Liu , Adam T. Neal , Zhen Zhu , David Tomanek , Peide D. Ye

Phosphorene, a monolayer of black phosphorus, is promising for nanoelectronic applications not only because it is a natural p-type semiconductor but also it possesses a layer-number dependent direct bandgap (in the range of 0.3 eV~1.5 eV).…

Mesoscale and Nanoscale Physics · Physics 2014-03-26 Jun Dai , Xiao Cheng Zeng

We studied the pressure dependence of the room-temperature infrared reflectivity of (TMTTF)_2AsF_6 along all three optical axes. This anisotropic organic compound consists of molecular stacks with orbital overlap along the a direction; due…

Strongly Correlated Electrons · Physics 2007-05-23 A. Pashkin , M. Dressel , C. A. Kuntscher

We report on the mechanical properties of few-layer black phosphorus (BP) nanosheets, in high vacuum and as a function of time of exposure to atmospheric conditions [1]. BP flakes with thicknesses ranging from 4 to 30 nm suspended over…

Different phases of solid boron under high pressure are studied by first principles calculations. The $\alpha$-B$_{12}$ structure is found to be stable up to 270 GPa. Its semiconductor band gap (1.72 eV) decreases continuously to zero…

Materials Science · Physics 2009-11-07 Jijun Zhao , Jian Ping Lu

We investigated the out-of-plane magnetoresistance of pressurized black phosphorus (BP) with a longitudinal field configuration. Despite the absence of the Lorentz force in the present configuration, we observed a significant enhancement of…

Strongly Correlated Electrons · Physics 2025-12-19 Kazuto Akiba , Yuzuki Sega , Yuichi Akahama , Yuta Seo , Tomoki Machida , Masashi Tokunaga

Screening in reduced dimensions has strong consequences on the electronic properties in van der Waals semiconductors, impacting the quasiparticle band gap and exciton binding energy. Screening in these materials is typically treated…

Black phosphorus (BP) exhibits highly anisotropic properties and dynamical behavior that are unique even among two-dimensional and van der Waals (vdW) layered materials. Here, we show that an interlayer lattice contraction and concerted,…

Mesoscale and Nanoscale Physics · Physics 2022-07-27 Mazhar Chebl , Xing He , Ding-Shyue Yang
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