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Black phosphorus (BP), an emerging two-dimensional (2D) material with intriguing optical properties, forms a promising building block in optics and photonics devices. In this work, we propose a simple structure composed of BP sandwiched by…

Optics · Physics 2019-09-18 Tingting Liu , Xiaoyun Jiang , Chaobiao Zhou , Shuyuan Xiao

In this work we introduce a low-energy Hamiltonian for single layer and bilayer black phosphorus that describes the electronic states at the vicinity of the gamma point. The model is based on a recently proposed tight-binding description…

Mesoscale and Nanoscale Physics · Physics 2015-09-02 J. M. Pereira , M. I. Katsnelson

We report the quasiparticle band gap, excitons, and highly anisotropic optical responses of few-layer black phosphorous (phosphorene). It is shown that these new materials exhibit unique many-electron effects; the electronic structures are…

Mesoscale and Nanoscale Physics · Physics 2014-06-27 Vy Tran , Ryan Soklaski , Yufeng Liang , Li Yang

We studied the electronic structure and optic absorption of phosphorene (monolayer of black phosphorus) under strain. Strain was found to be a powerful tool for the band structure engineering. The in-plane strain in armchair or zigzag…

Mesoscale and Nanoscale Physics · Physics 2016-04-20 Houjian Duan , Mou Yang , Ruiqiang Wang

Layered transition-metal dichalcogenides have emerged as exciting material systems with atomically thin geometries and unique electronic properties. Pressure is a powerful tool for continuously tuning their crystal and electronic structures…

Phosphorene, a two-dimensional (2D) monolayer of black phosphorus, has attracted considerable theoretical interest, although the experimental realization of monolayer, bilayer, and few-layer flakes has been a significant challenge. Here we…

Pressure-induced insulator-to-metal transition (IMT) has been studied in the van der Waals compound iron thiophosphate (FePS3) using first-principles calculations within the periodic linear combination of atomic orbitals method with hybrid…

Materials Science · Physics 2020-04-27 R. A. Evarestov , A. Kuzmin

Recently, black phosphorus (BP) has joined the two dimensional material family as a promising candidate for photonic applications, due to its moderate bandgap, high carrier mobility, and compatibility with a diverse range of substrates.…

Intercalation offers a promising way to alter the physical properties of two-dimensional (2D) layered materials. Here we investigate the electronic and vibrational properties of 2D layered MoSe$_2$ intercalated with atomic manganese at…

Materials Science · Physics 2020-09-28 Shunda Chen , Virginia L. Johnson , Davide Donadio , Kristie J. Koski

Bi$_2$Se$_3$, a layered three dimensional (3D) material, exhibits topological insulating properties due to presence of surface states and a band gap of 0.3 eV in the bulk. We study the effect hydrostatic pressure $P$ and doping with rare…

Materials Science · Physics 2021-02-26 Sudip Kumar Saha , Hrishit Banerjee , Manoranjan Kumar

Van der Waals (vdW) polytypes of broken inversion and mirror symmetries were recently shown to exhibit switchable electric polarization even at the ultimate two-layer thin limit. Their out-of-plane polarization was found to accumulate in a…

Using both DFT as well as $G_0W_0$ calculations, we investigate static and dynamic effects on the phosphorene band gap upon deposition and encapsulation on/in BN multilayers. We demonstrate how competing long- and short-range effects cause…

Materials Science · Physics 2016-10-05 Lukas Eugen Marsoner Steinkasserer , Simon Suhr , Beate Paulus

We have calculated numerically electron exchange, correlation energies and dynamical polarization function for newly discovered silicene, germanene and black phosphorus (BP), consisting of puckered layers of elemental phosphorus atoms,…

Mesoscale and Nanoscale Physics · Physics 2016-05-30 Andrii Iurov , Godfrey Gumbs , Danhong Huang

The pressure-induced changes in the optical properties of $\beta$-Na$_{0.33}$V$_2$O$_5$ single crystals at room temperature were studied by polarization-dependent Raman and far-infrared reflectivity measurements under high pressure. From…

Strongly Correlated Electrons · Physics 2018-02-02 Simone Frank , Christine A. Kuntscher , Ivan Gregora , Touru Yamauchi , Yutaka Ueda

Using the tight-binding approach, we investigate the electronic properties of bilayer phosphorene (BLP) quantum dots (QDs) in the presence of perpendicular electric and magnetic fields. Since BLP consists of two coupled phosphorene layers,…

Mesoscale and Nanoscale Physics · Physics 2017-10-16 L. L. Li , D. Moldovan , W. Xu , F. M. Peeters

As a high mobility two-dimensional semiconductor with strong structural and electronic anisotropy, atomically thin black phosphorus (BP) provides a new playground for investigating the quantum Hall (QH) effect, including outstanding…

Mesoscale and Nanoscale Physics · Physics 2018-04-18 Jiawei Yang , Son Tran , Jason Wu , Shi Che , Petr Stepanov , Takashi Taniguchi , Kenji Watanabe , Hongwoo Baek , Dmitry Smirnov , Ruoyu Chen , Chun Ning Lau

Using diffusion Monte Carlo (DMC) and density functional theory (DFT) calculations, we examined the structural stability and interlayer binding properties of PtSe$_2$, a representative transition metal dichalcogenide (TMD) with strong…

V$_2$O$_5$ is a promising battery electrode material that can intercalate not only Li, but also more abundant alkaline metals such as Na and K, and even multivalent ions such as Al, Ca, Cu, Mg, and Zn. V$_2$O$_5$ exhibits several different…

Materials Science · Physics 2026-03-05 Sakthi Kasthurirengan , Hartwin Peelaers

The presence of finite bandgap and high mobility in semiconductor few-layer black phosphorus offers an attractive prospect for using this material in future two-dimensional electronic devices. Here we demonstrate for the first time fully…

We investigate the nonequilibrium photocarrier dynamics of WTe2 under pressure using the optical pump-probe spectroscopy. The pressure dependences of the electronic relaxation manifest anomalous changes around 0.8, 3.5, and 6 GPa,…

Strongly Correlated Electrons · Physics 2023-03-10 Kai Zhang , Fuhai Su , Dayong Liu , Wenjun Wang , Yongsheng Zhang , Zhi Zeng , Zhe Qu , Alexander F. Goncharov