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We report precise measurements of ground-state, $\lambda$-doublet microwave transitions in the hydroxyl radical molecule (OH). Utilizing slow, cold molecules produced by a Stark decelerator we have improved over the precision of the…

Atomic Physics · Physics 2009-11-11 Eric R. Hudson , H. J. Lewandowski , Brian C. Sawyer , Jun Ye

We discuss the possibility of trapping polar molecules in the standing-wave electromagnetic field of a microwave resonant cavity. Such a trap has several novel features that make it very attractive for the development of ultracold molecule…

Atomic Physics · Physics 2009-11-10 D. DeMille , D. R. Glenn , J. Petricka

We discuss techniques to engineer effective long-range interactions between polar molecules using external static electric and microwave fields. We consider a setup where molecules are trapped in a two-dimensional pancake geometry by a…

Quantum Physics · Physics 2009-11-13 A. Micheli , G. Pupillo , H. P. Büchler , P. Zoller

We report optical trapping of laser-cooled molecules at sufficient density to observe molecule-molecule collisions for the first time in a bulk gas. SrF molecules from a red-detuned magneto-optical trap (MOT) are compressed and cooled in a…

Atomic Physics · Physics 2024-05-09 Varun Jorapur , Thomas K. Langin , Qian Wang , Geoffrey Zheng , David DeMille

We propose and analyze an electrostatic-optical nano-scale trap for cold diatomic polar molecules. The main ingredient of our proposal is an square-array of ferroelectric nano-rods {with alternating polarization}. We show that, in contrast…

Quantum Gases · Physics 2018-02-21 Omjyoti Dutta , Geza Giedke

Recently, the extremely sensitive torsion-rotation transitions in methanol have been used to set a tight constraint on a possible variation of the proton-to-electron mass ratio over cosmological time scales. In order to improve this…

In weakly bound diatomic molecules, energy levels are closely spaced and thus more susceptible to mixing by magnetic fields than in the constituent atoms. We use this effect to control the strengths of forbidden optical transitions in…

Atomic Physics · Physics 2015-12-22 B. H. McGuyer , M. McDonald , G. Z. Iwata , W. Skomorowski , R. Moszynski , T. Zelevinsky

We propose a method of stimulated laser cooling of diatomic molecules by counter-propagating $\pi$-trains of ultrashort laser pulses. The cooling cycles occur on the rovibrational transitions inside the same ground electronic manifold, thus…

Atomic Physics · Physics 2015-03-13 Ekaterina Ilinova , Jonathan Weinstein , Andrei Derevianko

We study the feasibility of nearly-degenerate two-photon rovibrational spectroscopy in ensembles of trapped, sympathetically cooled hydrogen molecular ions using a resonance-enhanced multiphoton dissociation (REMPD) scheme. Taking advantage…

Hyperfine-structures of highly charged ions (HCIs) are favourable spectroscopic targets for exploring fundamental physics as well as nuclear properties. Recent proposals of HCI atomic clocks highlight their importance, especially for…

We demonstrate Faraday spectroscopy with high duty cycle and sampling rate using atoms confined to a blue-detuned optical trap. Our trap consists of a crossed pair of high-charge-number hollow laser beams, which forms a dark, box-like…

Quantum Physics · Physics 2009-11-13 Matthew L. Terraciano , Mark Bashkansky , Fredrik Fatemi

Two-dimensional electronic spectroscopy provides information on coupling and energy transfer between excited states on ultrafast timescales. Only recently, incoherent fluorescence detection has made it possible to combine this method with…

Optics · Physics 2025-05-14 Sanchayeeta Jana , Simon Durst , Lucas Ludwig , Markus Lippitz

We report on the optical polarizability of microwave-shielded ultracold NaCs molecules in an optical dipole trap. While dressing a pair of rotational states with a microwave field, we observe a marked dependence of the optical…

Quantum Gases · Physics 2025-01-16 Siwei Zhang , Weijun Yuan , Niccolò Bigagli , Claire Warner , Ian Stevenson , Sebastian Will

It has been roughly three decades since laser cooling techniques produced ultracold atoms, leading to rapid advances in a vast array of fields. Unfortunately laser cooling has not yet been extended to molecules because of their complex…

Atomic Physics · Physics 2015-05-27 E. S. Shuman , J. F. Barry , D. DeMille

We investigate theoretically the application of tailored incoherent far-infrared fields in combination with laser excitation of a single rovibrational transition for rotational cooling of translationally cold polar diatomic molecules. The…

Atomic Physics · Physics 2009-11-10 I. S. Vogelius , L. B. Madsen , M. Drewsen

Cavity cooling of an atom works best on a cyclic optical transition in the strong coupling regime near resonance, where small cavity photon numbers suffice for trapping and cooling. Due to the absence of closed transitions a straightforward…

Quantum Physics · Physics 2012-11-13 R. J. Schulze , C. Genes , H. Ritsch

We study laser cooling of $^{24}$Mg atoms in dipole optical trap with pumping field resonant to narrow $(3s3s)\,^1S_0 \rightarrow \, (3s3p)\,^{3}P_1$ ($\lambda = 457$ nm) optical transition. For description of laser cooling of atoms in the…

Atomic Physics · Physics 2017-06-07 Oleg Prudnikov

Magnetic trapping of bromine atoms at temperatures in the milliKelvin regime is demonstrated for the first time. The atoms are produced by photodissociation of Br$_2$ molecules in a molecular beam. The lab-frame velocity of Br atoms is…

Atomic Physics · Physics 2014-02-21 C. J. Rennick , J. Lam , W. G. Doherty , T. P. Softley

We demonstrate single-shot imaging and narrow-line cooling of individual alkaline earth atoms in optical tweezers; specifically, strontium-88 atoms trapped in $515.2~\text{nm}$ light. We achieve high-fidelity single-atom-resolved imaging by…

The direct laser cooling of neutral diatomic molecules in molecular beams suggests that trapped molecular ions can also be laser cooled. The long storage time and spatial localization of trapped molecular ions provides the opportunity for…

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