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Polaritonic chemistry has become a rapidly developing field within the last few years. A multitude of experimental observations suggest that chemical properties can be fundamentally altered and novel physical states appear when matter is…

Mesoscale and Nanoscale Physics · Physics 2020-11-09 Dominik Sidler , Christian Schäfer , Michael Ruggenthaler , Angel Rubio

Polaritons are quantum mechanical superpositions of photon states with elementary excitations in molecules and solids. The light-matter admixture causes a characteristic frequency-momentum dispersion shared by all polaritons irrespective of…

We derive the properties of polaritons in single-$\Lambda$ and double-$\Lambda$ media using a microscopic equation-of-motion technique. In each case, the polaritonic dispersion relation and composition arise from a matrix eigenvalue problem…

Atomic Physics · Physics 2008-03-04 Y. D. Chong , Marin Soljacic

Coupling between light and material excitations underlies a wide range of optical phenomena. Polaritons are eigenstates of a coupled system with hybridized wave function. Owing to their hybrid composition, polaritons exhibit at the same…

Optics · Physics 2022-12-27 Denis G. Baranov , Christian Schäfer , Maxim V. Gorkunov

Optical nonlinearities are crucial for advanced photonic technologies since they allow photons to be managed by photons. Exciton-polaritons resulting from strong light-matter coupling are hybrid in nature: they combine small mass and high…

The energetic positions of molecular electronic states at molecule/electrode interfaces are crucial factors for determining the transport and optoelectronic properties of molecular junctions. Strong light--matter coupling offers a potential…

Mesoscale and Nanoscale Physics · Physics 2023-05-10 Kuniyuki Miwa , Souichi Sakamoto , Akihito Ishizaki

Strong cavity coupling of gas-phase molecules will enable studies of benchmark chemical processes under strong light-matter interactions with a high level of experimental control and no solvent effects. We recently demonstrated the…

Chemical Physics · Physics 2023-10-26 Adam D. Wright , Jane C. Nelson , Marissa L. Weichman

Dressing quantum states of matter with virtual photons can create exotic effects ranging from vacuum-field modified transport to polaritonic chemistry, and may drive strong squeezing or entanglement of light and matter modes. The…

Quantum Physics · Physics 2023-09-14 J. Mornhinweg , L. Diebel , M. Halbhuber , M. Prager , J. Riepl , T. Inzenhofer , D. Bougeard , R. Huber , C. Lange

Reversible exchange of photons between a material and an optical cavity can lead to the formation of hybrid light--matter states where material properties such as the work function\cite{Hutchison_AM2013a}, chemical…

We examine the photoluminescence of highly-excited exciton-polariton condensates in semiconductor microcavities. Under strong pumping, exciton-polariton condensates have been observed to undergo a lasing transition where strong coupling…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 Natsuko Ishida , Tim Byrnes , Tomoyuki Horikiri , Franco Nori , Yoshihisa Yamamoto

Experiments show that light-matter strong coupling affects chemical properties, though the underlying mechanism remains unclear. We present an ab initio quantum electrodynamics coupled cluster method for the collective strong coupling…

Chemical Physics · Physics 2024-11-18 Matteo Castagnola , Marcus T. Lexander , Henrik Koch

Several years ago, it was shown that strong coupling between an electronic transition in organic molecules and a resonant photonic structure can modify the electronic landscape of the molecules and affect their chemical behavior. Since…

Exciton-polaritons provide a versatile platform for the study of a wide range of phenomena, including polariton lasers, topological polaritons, and bosonic condensation. Transition metal dichalcogenide monolayers host excitons with large…

Mesoscale and Nanoscale Physics · Physics 2026-05-15 Lukas Krelle , Lukas Husel , Kenji Watanabe , Takashi Taniguchi , Ismail Bilgin , Alexander Högele , Farsane Tabataba-Vakili

Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

Quantum Gases · Physics 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

The exploitation of the strong light-matter coupling regime and exciton-polariton condensates has emerged as a compelling approach to introduce strong interactions and nonlinearities into numerous photonic applications, ranging from…

Molecular polaritons, hybrid light-matter states resulting from strong cavity coupling of optical transitions, may provide a new route to guide chemical reactions. However, demonstrations of cavity-modified reactivity in clean benchmark…

Chemical Physics · Physics 2024-08-20 Liying Chen , Ashley P. Fidler , Alexander M. McKillop , Marissa L. Weichman

Ultrastrong light-matter coupling opens exciting possibilities to generate squeezed quantum states and entanglement. Here we propose a way to achieve this regime in superconducting hybrid nanostructures with ferromagnetic interlayers.…

Mesoscale and Nanoscale Physics · Physics 2023-06-07 Mikhail Silaev

Sub-wavelength thick photonic crystal (PhC) slabs coupled to 2D excitonic materials, such as transition metal dichalcogenides (TMDs), are a promising platform for highly tunable, room-temperature, on-chip optoelectronic devices. Unlike…

Exciton-polaritons are unique quasiparticles with hybrid properties of an exciton and a photon, opening ways to realize ultrafast strongly nonlinear systems and inversion-free lasers based on Bose-Einstein polariton condensation. However,…

A theoretical variation between the two distinct light-matter coupling regimes, namely weak and strong coupling, becomes uniquely feasible in open optical Fabry-P\'erot microcavities with low mode volume, as discussed here. In combination…

Applied Physics · Physics 2019-12-02 Franziska Wall , Oliver Mey , Lorenz Maximilian Schneider , Arash Rahimi-Iman
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