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Strong light-matter coupling gives rise to polaritons - hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article surveys the main architectures…

In organic microcavities, hybrid light-matter states can form with energies that differ from the bare molecular excitation energies by nearly 1 eV. A timely question, given recent advances in the development of thermally activated delayed…

Applied Physics · Physics 2019-03-25 Elad Eizner , Luis A. Martínez-Martínez , Joel Yuen-Zhou , Stéphane Kéna-Cohen

The coherent strong coupling of molecules with confined light fields to create polaritons - part matter, part light - is opening exciting opportunities ranging from extended exciton transport and inter-molecular energy transfer to modified…

Light-matter interactions are known to lead to the formation of polariton states through what is called strong coupling, leading to the formation of two hybrid states usually tagged as Upper and Lower Polaritons. Here, we consider a similar…

Singlet fission is an important candidate to increase energy conversion efficiency in organic photovoltaics by providing a pathway to increase the quantum yield of excitons per photon absorbed in select materials. We investigate the…

Exciton-polaritons are quasiparticles with mixed photon and exciton character that demonstrate rich quantum phenomena, novel optoelectronic devices and the potential to modify chemical properties of materials. Organic semiconductors are of…

We investigate theoretically the influence of strong light-matter coupling on the initial steps of the photo-triggered singlet-fission process. In particular we focus on intra-molecular singlet fission in a TIPS-pentacene dimer derivative…

Chemical Physics · Physics 2024-06-07 Lisamaria Wallner , Charlotte Remnant , Oriol Vendrell

Polaritons are compositional light-matter quasiparticles that arise as a result of strong coupling between a vacuum field of a resonant optical cavity and electronic excitations in quantum emitters. Reaching such a regime is often hard, as…

Recent experiments have demonstrated that molecular polaritons, hybrid states of light and matter formed by the strong coupling between molecular electronic or vibrational excitations and an optical cavity, can substantially modify the…

Chemical Physics · Physics 2021-07-08 Nguyen Thanh Phuc

The manipulation of molecular excited state processes through strong coupling has attracted significant interest for its potential to provide precise control of photochemical phenomena. However, the key limiting factor for achieving this…

In recent years it has become clear that the transport of excitons and charge carriers in molecular systems can be enhanced by coherent coupling with photons, giving rise to the formation of hybrid excitations known as polaritons. Such…

Materials Science · Physics 2023-01-19 M. Balasubrahmaniyam , Arie Simkovich , Adina Golombek , Guy Ankonina , Tal Schwartz

The concept of modifying molecular dynamics in strongly coupled exciton-polariton systems is an emerging topic in photonics due to its potential to produce customized chemical systems with tailored photophysical properties. However, before…

Materials Science · Physics 2020-10-09 Bin Liu , Vinod M. Menon , Matthew Y. Sfeir

Organic light-emitting diodes (OLEDs) have redefined lighting with their environment-friendliness and flexibility. However, only 25 % of the electronic states of organic molecules can emit light upon electrical excitation, limiting the…

Materials Science · Physics 2025-02-17 Olli Siltanen , Kimmo Luoma , Andrew J. Musser , Konstantinos S. Daskalakis

Exciton-polaritons in semiconductors are quasi-particles which have recently shown the capability to undergo phase transition into a coherent hybrid state of light and matter. The observation of such quasi-particles in organic microcavities…

Light-matter interactions can occur when an ensemble of molecular resonators is placed in a confined electromagnetic field. In the strong coupling regime the rapid exchange of energy between the molecules and the electromagnetic field…

Mesoscale and Nanoscale Physics · Physics 2020-08-10 Philip A. Thomas , Wai Jue Tan , Henry A. Fernandez , William L. Barnes

The hybridization of light and matter excitations in the form of polaritons has enabled major advances in understanding and controlling optical nonlinearities. Entering the quantum regime of strong interactions between individual photons…

Polaritons, formed as a result of strong hybridization of matter with light, are promising for important applications including organic solar cells, optical logic gates, and qubits. Owing to large binding energies of Frenkel excitons…

We theoretically designed and experimentally demonstrated a mechanism to protect a spatially segregated mixed light-matter state, known as intercavity exciton-polariton in strongly coupled optical cavities. This excitation, shared across…

Strong light-matter coupling is a quantum process in which light and matter are coupled together, generating hybridized states. This is similar to the notion of molecular hybridization, but one of the components is light. Here, we utilized…

Applied Physics · Physics 2024-02-20 Jhuma Dutta , Pooja Bhatt , Kuljeet Kaur , Daniel E. Gómez , Jino George

The regime of ultrastrong light-matter interaction has been investigated theoretically and experimentally, using zero-dimensional electromagnetic resonators coupled with an electronic transition between two confined states of a…

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