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Molecular polaritons are hybrid light-matter states that enable the exploration of potential cavity-modified chemistry. The development of dynamical, first-principles approaches for simulating molecular polaritons is important for…

Chemical Physics · Physics 2025-07-18 Millan F. Welman , Tao E. Li , Sharon Hammes-Schiffer

Dark and bright excitons are shown to appear naturally in a linear atomic super-lattice with two atoms per unit cell. In bringing the super-lattice into a strong coupling regime with a one-dimensional nanophotonic waveguide, bright excitons…

Quantum Physics · Physics 2015-02-23 Hashem Zoubi

The nature of trions and their interaction with light has remained a puzzle. The composition and dispersion of polaritons involving trions provide insights into this puzzle. Trions and excitons in doped two-dimensional (2D) materials are…

Mesoscale and Nanoscale Physics · Physics 2021-07-28 Okan Koksal , Minwoo Jung , Christina Manolatou , A. Nick Vamivakas , Gennady Shvets , Farhan Rana

The experimental observation of quantum phenomena in strongly correlated many particle systems is difficult because of the short length- and timescales involved. Obtaining at the same time detailed control of individual constituents appears…

Quantum Physics · Physics 2007-05-23 Michael J. Hartmann , Fernando G. S. L. Brandao , Martin B. Plenio

Solid-state semiconductor lasers underpin technologies from telecommunications and data storage to sensing, medical diagnostics, and emerging quantum communication. Polaritons-hybrid exciton-photon states have further extended this reach,…

Strong coupling of excitonic resonances with a cavity gives rise to exciton-polaritons which possess a modified energy landscape compared to the uncoupled emitter. However, due to the femtosecond lifetime of the so-called bright polariton…

Mesoscale and Nanoscale Physics · Physics 2022-05-19 Jan M. Lüttgens , Zhuoran Kuang , Nicolas F. Zorn , Tiago Buckup , Jana Zaumseil

We show that the appropriate on-off switching of Josephson coupling between exciton-polaritons in coupled semiconductor microcavities can reveal the full capacity for generating entanglement with a recently proposed method which essentially…

Mesoscale and Nanoscale Physics · Physics 2018-07-25 Dionisis Stefanatos , Emmanuel Paspalakis

Polaritons in metals, semimetals, semiconductors, and polar insulators, with their extreme confinement of electromagnetic energy, provide many promising opportunities for enhancing typically weak light-matter interactions such as multipolar…

We demonstrate experimentally an enhanced delayed fluorescence in tetracene single crystals strongly coupled to optical modes in open cavities formed by arrays of plasmonic nanoparticles. Hybridization of singlet excitons with collective…

Mesoscale and Nanoscale Physics · Physics 2019-07-23 Matthijs Berghuis , Alexei Halpin , Quynh Le-Van , Mohammad Ramezani , Shaojun Wang , Shunsuke Murai , Jaime Gómez Rivas

We demonstrate strong coupling between molecular excited states and surface plasmon modes of a slit array in a thin metal film. The coupling manifests itself as an anti-crossing behavior of the two newly formed polaritons. As the coupling…

Mesoscale and Nanoscale Physics · Physics 2012-08-17 Adi Salomon , Robert J. Gordon , Yehiam Prior , Tamar Seideman , Maxim Sukharev

We present a fully microscopic approach to the transition rate of two exciton-photon polaritons. The non-trivial consequences of the polariton composite nature -- here treated exactly through a development of our composite-exciton many-body…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 M. Combescot , M. -A. Dupertuis , O. Betbeder-Matibet

Following experimental realizations of room temperature polariton lasing with organic molecules, we present a microscopic model that allows us to explore the crossover from weak to strong matter-light coupling. We consider a non-equilibrium…

Quantum Gases · Physics 2018-11-14 Artem Strashko , Peter Kirton , Jonathan Keeling

Polaritonic chemistry offers the possibility of modifying molecular properties and even influencing chemical reactivity through strong coupling between vibrational transitions and confined light modes in optical cavities. Despite…

Chemical Physics · Physics 2025-05-16 Thomas Schnappinger , Markus Kowalewski

The formation of the composite photonic-excitonic particle, known as a polariton, is a phenomenon emerging in materials possessing strong coupling to light. The organic-based materials besides the strong light-matter coupling also…

Chemical Physics · Physics 2023-01-19 Vladimir Al. Osipov , Boris Fainberg

Interaction between light and molecular vibrations leads to hybrid light-matter states called vibrational polaritons. Even though many intriguing phenomena have been predicted for single-molecule vibrational strong coupling (VSC), several…

A series of experiments demonstrate that strong light-matter coupling between vibrational excitations in isotropic solutions of molecules and resonant infrared optical microcavity modes leads to modified thermally-activated kinetics.…

Chemical Physics · Physics 2020-06-23 Jorge A. Campos-Gonzalez-Angulo , Joel Yuen-Zhou

In the strong light-matter coupling regime realized e.g. by integrating semiconductors into optical microcavities, polaritons as new hybrid light-matter quasi-particles are formed. The corresponding change in the dispersion relation has a…

Materials Science · Physics 2022-09-08 Beatriz Ferreira , Roberto Rosati , Ermin Malic

Anisotropy plays a key role in science and engineering. However, the interplay between the material and engineered photonic anisotropies has hardly been explored due to the vastly different length scales. Here we demonstrate a matter-light…

Phase transitions, where observable properties of a many-body system change discontinuously, can occur in both open and closed systems. Ultracold atoms have provided an exemplary model system to demonstrate the physics of closed-system…

We demonstrate hybridization of optical cavity photons with atomic Rydberg excitations using electromagnetically induced transparency (EIT). The resulting dark state Rydberg polaritons exhibit a compressed frequency spectrum and enhanced…

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