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We exactly calculate the fourth virial coefficient for hard spheres in even dimensions for D=4,6,8,10, and 12.

Statistical Mechanics · Physics 2016-10-06 N. Clisby , B. M. McCoy

The fourth virial coefficient is calculated exactly for a fluid of hard spheres in odd dimensions up to 11.

Statistical Mechanics · Physics 2009-11-10 I. Lyberg

We derive an exact, analytic expression for the fourth virial coefficient of a system of polydisperse spheres under the constraint that the smallest sphere has a radius smaller than a given function of the radii of the three remaining…

Soft Condensed Matter · Physics 2009-10-31 Ronald Blaak

Exact results are given for the fourth virial coefficient of hard spheres in even dimensions up through 12. The fifth and sixth virial coefficients are numerically computed for dimensions 2 through 50 and it is found that the sixth virial…

Statistical Mechanics · Physics 2007-05-23 N. Clisby , B. M. McCoy

We compute the fourth virial coefficient of a binary nonadditive hard-sphere mixture over a wide range of deviations from diameter additivity and size ratios. Hinging on this knowledge, we build up a $y$ expansion [B. Barboy and W. N.…

Soft Condensed Matter · Physics 2011-10-25 G. Pellicane , F. Saija , C. Caccamo , P. V. Giaquinta

The partition function and the one- and two-body distribution functions are evaluated for two hard spheres with different sizes constrained into a spherical pore. The equivalent problem for hard disks is addressed too. We establish a…

Statistical Mechanics · Physics 2010-05-07 Ignacio Urrutia

The composition-independent virial coefficients of a $d$-dimensional binary mixture of (additive) hard hyperspheres following from a recent proposal for the equation of state of the mixture [Santos, A., Yuste, S. B., and L\'opez de Haro,…

Statistical Mechanics · Physics 2007-05-23 A. Santos , S. B. Yuste , M. López de Haro

We present new results for the virial coefficients B_k with k <= 10 for hard spheres in dimensions D=2,...,8.

Statistical Mechanics · Physics 2016-10-06 Nathan Clisby , Barry M. McCoy

Several methods of extrapolating the virial coefficients, including those proposed in this work, are discussed. The methods are demonstrated on predicting higher virial coefficients of one-component hard spheres. Estimated values of the…

Statistical Mechanics · Physics 2012-07-16 M. Oncák , A. Malijevský , J. Kolafa , S. Labík

Using the first seven known virial coefficients and forcing it to possess two branch-point singularities, a new equation of state for the hard-sphere fluid is proposed. This equation of state predicts accurate values of the higher virial…

Soft Condensed Matter · Physics 2009-06-26 Andrés Santos , Mariano López de Haro

New proposals for the equation of state of four- and five-dimensional hard-hypersphere mixtures in terms of the equation of state of the corresponding monocomponent hard-hypersphere fluid are introduced. Such proposals (which are…

Soft Condensed Matter · Physics 2020-04-22 Mariano López de Haro , Andrés Santos , Santos B. Yuste

A new closed virial equation of state of hard-sphere fluids is proposed which reproduces the calculated or estimated values of the first sixteen virial coefficients at the same time as giving very good accuracy when compared with computer…

Chemical Physics · Physics 2016-07-14 Jianxiang Tian , Yuanxing Gui , Angel Mulero

We have computed by a Monte Carlo method the fourth virial coefficient of free anyons, as a function of the statistics angle theta. It can be fitted by a four term Fourier series, in which two coefficients are fixed by the known…

Statistical Mechanics · Physics 2009-10-30 Anders Kristoffersen , Stefan Mashkevich , Jan Myrheim , Kaare Olaussen

A recently derived method [R. D. Rohrmann and A. Santos, Phys. Rev. E. {\bf 76}, 051202 (2007)] to obtain the exact solution of the Percus-Yevick equation for a fluid of hard spheres in (odd) $d$ dimensions is used to investigate the…

Soft Condensed Matter · Physics 2008-07-05 Rene D. Rohrmann , Miguel Robles , Mariano Lopez de Haro , Andres Santos

We solve the Percus-Yevick equation in even dimensions by reducing it to a set of simple integro-differential equations. This work generalizes an approach we developed previously for hard discs. We numerically obtain both the pair…

Statistical Mechanics · Physics 2008-10-15 M. Adda-Bedia , E. Katzav , D. Vella

We propose a new semi empirical expression of the virial coefficients for a hard sphere fluid which is valid in the disordered phase over the whole density range. The results are in good agreement with the numerical data and better than…

Statistical Mechanics · Physics 2016-03-15 Richard Bonneville

An equation of state for a multicomponent mixture of non-additive hard spheres in $d$ dimensions is proposed. It yields a rather simple density dependence and constitutes a natural extension of the equation of state for additive hard…

Soft Condensed Matter · Physics 2007-05-23 A. Santos , M. Lopez de Haro , S. B. Yuste

Recent values for virial coefficients up to B12, when expressed in powers of density relative to maximum close packing,lead to a closed equation-of-state for the equilibrium fluid. The series obtained converges for all densities;it becomes…

Statistical Mechanics · Physics 2008-02-02 Leslie V. Woodcock

Virial coefficients for the two-dimensional hard-disk fluid, when expressed in powers of density relative to maximum close packing, lead to an accurate closed equation-of-state for the equilibrium fluid, analogous to that recently found for…

Statistical Mechanics · Physics 2008-04-07 Leslie V. Woodcock

Different theoretical approaches for the thermodynamic properties and the equation of state for multicomponent mixtures of nonadditive hard spheres in $d$ dimensions are presented in a unified way. These include the theory by Hamad, our…

Soft Condensed Matter · Physics 2010-05-27 Andrés Santos , Mariano López de Haro , Santos B. Yuste
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