Solution of the Percus-Yevick equation for hard hyperspheres in even dimensions
Abstract
We solve the Percus-Yevick equation in even dimensions by reducing it to a set of simple integro-differential equations. This work generalizes an approach we developed previously for hard discs. We numerically obtain both the pair correlation function and the virial coefficients for a fluid of hyper-spheres in dimensions and 8, and find good agreement with available exact results and Monte-Carlo simulations. This paper confirms the alternating character of the virial series for , and provides the first evidence for an alternating character for . Moreover, we show that this sign alternation is due to the existence of a branch point on the negative real axis. It is this branch point that determines the radius of convergence of the virial series, whose value we determine explicitly for . Our results complement, and are consistent with, a recent study in odd dimensions [R.D. Rohrmann et al., J. Chem. Phys. 129, 014510 (2008)].
Keywords
Cite
@article{arxiv.0807.4465,
title = {Solution of the Percus-Yevick equation for hard hyperspheres in even dimensions},
author = {M. Adda-Bedia and E. Katzav and D. Vella},
journal= {arXiv preprint arXiv:0807.4465},
year = {2008}
}
Comments
Accepted for publication in J. Chem. Phys. (11 pages, 6 figures)