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The fourth virial coefficient of asymmetric nonadditive binary mixtures of hard disks is computed with a standard Monte Carlo method. Wide ranges of size ratio ($0.05\leq q\leq 0.95$) and nonadditivity ($-0.5\leq \Delta\leq 0.5$) are…

Soft Condensed Matter · Physics 2012-05-17 Franz Saija , Andrés Santos , Santos B. Yuste , Mariano López de Haro

We evidence via a computation in the reciprocal space the asymptotic behaviour of the high order virial coefficients for a hard sphere system. These coefficients, if their order is high enough, are those of a geometric series. We thus are…

Statistical Mechanics · Physics 2015-03-23 Richard Bonneville

We evaluate the virial coefficients B_k for k<=10 for hard spheres in dimensions D=2,...,8. Virial coefficients with k even are found to be negative when D>=5. This provides strong evidence that the leading singularity for the virial series…

Statistical Mechanics · Physics 2016-10-06 N. Clisby , B. M. McCoy

The asymptotic expansion method is extended by using currently available accurate values for the first ten virial coefficients for hard sphere fluids. It is then used to yield an equation of state for hard sphere fluids, which accurately…

Chemical Physics · Physics 2019-03-27 Jianxiang Tian , Hua Jiang , Yuanxing Gui , A. Mulero

We develop an extension of the original Reiss-Frisch-Lebowitz scaled particle theory that can serve as a predictive method for the hard sphere pair correlation function g(r). The reversible cavity creation work is analyzed both for a single…

Statistical Mechanics · Physics 2009-11-11 Frank H. Stillinger , Pablo G. Debenedetti , Swaroop Chatterjee

We study different dimensional fluids inspired by noncommutative geometry which admit conformal Killing vectors. The solutions of the Einstein field equations examined specifically for five different set of spacetime. We calculate the…

General Relativity and Quantum Cosmology · Physics 2015-04-15 Farook Rahaman , Anirudh Pradhan , Nasr Ahmed , Saibal Ray , Bijan Saha , Mosiur Rahaman

A new method of estimating high-order virial coefficients for fluids composed of equal three-dimensional rigid spheres is proposed. The predicted $B_{11}$ and $B_{12}$ values are in good agreement with reliable estimates previously…

Statistical Mechanics · Physics 2014-03-07 C. C. F. Florindo , A. B. M. S. Bassi

We construct universal geometric coefficients for the cluster algebra associated to the four-punctured sphere and obtain, as a by-product, the g-vectors of cluster variables. We also construct the rational part of the mutation fan. These…

Combinatorics · Mathematics 2026-05-13 Emily Barnard , Emily Meehan , Nathan Reading , Shira Viel

We study the diffusion equation on the surface of a 4D sphere and obtain a Kubo formula for the diffusion coefficient.

Statistical Mechanics · Physics 2007-05-23 J. -M. Caillol

The problem of demixing in a binary fluid mixture of highly asymmetric additive hard spheres is revisited. A comparison is presented between the results derived previously using truncated virial expansions for three finite size ratios with…

Soft Condensed Matter · Physics 2013-05-03 Mariano López de Haro , Carlos F. Tejero , Andrés Santos

Virial expansion is a traditional approach in statistical mechanics that expresses thermodynamic quantities, such as pressure $p$, as power series of density or chemical potential. Its radius of convergence can serve as a potential…

Statistical Mechanics · Physics 2025-01-28 Kiyoharu Kawana

Various solutions of the kinetic equation for the equilibrium of a gravitating sphere of uniform density with a quadratic gravitational potential and a linear dependence of gravitational force on radius are examined. New analytic solutions…

Astrophysics of Galaxies · Physics 2021-07-21 G. S. Bisnovatyi-Kogan

The question of whether the known virial coefficients are enough to determine the packing fraction $\eta_\infty$ at which the fluid equation of state of a hard-sphere fluid diverges is addressed. It is found that the information derived…

Statistical Mechanics · Physics 2011-02-25 Miguel Ángel G. Maestre , Andrés Santos , Miguel Robles , Mariano López de Haro

A new analytical approach to derive an approximate equation of state and the virial coefficients for simple fluids is presented. Starting from the usual expression of the partition function, we first perform a Fourier transformation, and…

General Physics · Physics 2017-06-30 Richard Bonneville

Based on the survey of the literatures on the new improvements on the equation of state (EOS) for the hard sphere fluids, we here compare lots of different EOSs and present a very accurate equation of state for this kind of fluids. The new…

Soft Condensed Matter · Physics 2025-12-08 Can Cui , Jianxiang Tian

We review a virial-type estimate which bounds the strength of interaction for a gas of $N$ hard spheres (billiard balls) dispersing into Euclidean space $\mathbb{R}^d$. This type of estimate has been known for decades in the context of…

Analysis of PDEs · Mathematics 2018-07-10 Ryan Denlinger

Here we present new results obtained for the equation of state with induced surface and curvature tensions. The explicit formulas for the first five virial coefficients of system pressure and for the induced surface and curvature tension…

Nuclear Theory · Physics 2020-12-22 Nazar S. Yakovenko , Kyrill A. Bugaev , Larissa V. Bravina , Evgeny E. Zabrodin

A simple recipe to derive the compressibility factor of a multicomponent mixture of d-dimensional additive hard spheres in terms of that of the one-component system is proposed. The recipe is based (i) on an exact condition that has to be…

Statistical Mechanics · Physics 2019-05-23 A. Santos , S. B. Yuste , M. Lopez de Haro

Given a quaternionic slice regular function $f$, we give a direct and effective way to compute the coefficients of its spherical expansion at any point. Such coefficients are obtained in terms of spherical and slice derivatives of the…

Complex Variables · Mathematics 2021-12-22 Amedeo Altavilla

We provide analytical expressions for the second virial coefficients of hard, convex, monoaxial solids of revolution in ${\mathbb{R}^{4}}$. The excluded volume per particle and thus the second virial coefficient is calculated using…

Statistical Mechanics · Physics 2025-02-14 Markus Kulossa , Joachim Wagner