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In the past two decades, the revolutionary technologies of creating cold and ultracold molecules have provided cutting-edge experiments for studying the fundamental phenomena of collision physics. To a large degree, the recent explosion of…

Atomic Physics · Physics 2022-01-25 Yang Liu , Le Luo

Photoassociation of ultracold atoms is a resonant light-assisted collision process, in which two colliding atoms absorb a photon and form an excited molecule. Since the first observation about three decades ago, the photoassociation of…

Atomic Physics · Physics 2024-03-19 Jin Cao , Bo-Yuan Wang , Huan Yang , Zhi-Jie Fan , Zhen Su , Jun Rui , Bo Zhao , Jian-Wei Pan

We present a theoretical investigation of reactive and non-reactive collisions of Li and Rb atoms with C$_{2}^{-}$ molecular anions at low temperatures in the context of sympathetic cooling in hybrid trap experiments. Based on recently…

Chemical Physics · Physics 2020-08-26 M. Kas , J. Liévin , N. Vaeck , J. Loreau

We study the effect of resonances associated with complex molecular interaction of Rydberg atoms on Rydberg blockade. We show that densely-spaced molecular potentials between doubly-excited atomic pairs become unavoidably resonant with the…

Atomic Physics · Physics 2016-10-05 Andrei Derevianko , Péter Kómár , Turker Topcu , Ronen M. Kroeze , Mikhail D. Lukin

Supersonic beams are a prevalent source of cold molecules utilized in the study of chemical reactions, atom interferometry, gas-surface interactions, precision spectroscopy, molecular cooling and more. The triumph of this method emanates…

We present an accurate quantum mechanical study of molecule-molecule collisions in the presence of a magnetic field. The work focusses on the analysis of elastic scattering and spin relaxation in collisions of O2(3Sigma_g) molecules at cold…

Atomic Physics · Physics 2012-02-06 T. V. Tscherbul , Yu. V. Suleimanov , V. Aquilanti , R. V. Krems

We experimentally demonstrate optical spectroscopy of magnetically trapped atoms on an atom chip. High resolution optical spectra of individual trapped clouds are recorded within a few hundred milliseconds. Detection sensitivities close to…

Quantum Physics · Physics 2008-09-16 A. Günther , H. Bender , A. Stibor , J. Fortágh , C. Zimmermann

This article reviews the current state of the art in the field of cold and ultracold molecules and demonstrates that chemical reactions, inelastic collisions and dissociation of molecules at subKelvin temperatures can be manipulated with…

Atomic Physics · Physics 2015-06-26 R. V. Krems

We analyze collisional decoherence of atoms or molecules prepared in a coherent superposition of nondegenerate internal states at ultralow temperatures and placed in an ultracold buffer gas. Our analysis is applicable for an arbitrary bath…

Quantum Physics · Physics 2015-05-14 C. J. Hemming , R. V. Krems

Full control of molecular interactions, including reactive losses, would open new frontiers in quantum science. Here, we demonstrate extreme tunability of chemical reaction rates by using an external electric field to shift excited…

Cold inelastic collisions of atoms or molecules are analyzed using very general arguments. In free space, the deactivation rate can be enhanced or suppressed together with the scattering length of the corresponding elastic collision via a…

Atomic Physics · Physics 2007-05-23 V. A. Yurovsky , Y. B. Band

We calculate the rates of inelastic collisions for ultracold alkali-metal atoms in radiofrequency-dressed traps, using coupled-channel scattering calculations on accurate potential energy surfaces. We identify an rf-induced loss mechanism…

Atomic Physics · Physics 2017-10-18 Daniel J. Owens , Jeremy M. Hutson

We present a formalism for rigorous calculations of cross sections for inelastic and reactive collisions of ultracold atoms and molecules confined by laser fields in quasi-2D geometry. Our results show that the elastic-to-inelastic ratios…

Atomic Physics · Physics 2009-03-20 Z. Li , R. V. Krems

Ultracold molecular gases are promising as an avenue to rich many-body physics, quantum chemistry, quantum information, and precision measurements. This richness, which flows from the complex internal structure of molecules, makes the…

Atomic Physics · Physics 2015-06-18 A. M. Jayich , A. C. Vutha , M. T. Hummon , J. V. Porto , W. C. Campbell

We study the dynamics of atoms in optical traps when exposed to laser cooling light that induces light-assisted collisions. We experimentally prepare individual atom pairs and observe their evolution. Due to the simplicity of the system…

Atomic Physics · Physics 2015-06-17 P. Sompet , A. V. Carpentier , Y. H. Fung , M. McGovern , M. F. Andersen

Mergoassociation of two ultracold atoms to form a weakly bound molecule can occur when two optical traps that each contain a single atom are merged. Molecule formation occurs at an avoided crossing between a molecular state and the lowest…

Atomic Physics · Physics 2023-10-04 Robert C. Bird , C. Ruth Le Sueur , Jeremy M. Hutson

Ultracold hybrid ion-atom traps offer the possibility of microscopic manipulation of quantum coherences in the gas using the ion as a probe. However, inelastic processes, particularly charge transfer can be a significant process of ion loss…

Atomic Physics · Physics 2015-06-19 B. M. McLaughlin , H. D. L. Lamb , I. C. Lane , J. F. McCann

Efficient sub-Doppler laser cooling and optical trapping of YO molecules offer new opportunities to study collisional dynamics in the quantum regime. Confined in a crossed optical dipole trap, we achieve the highest phase-space density of…

We experimentally demonstrate cooling of trapped ions by collisions with co-trapped, higher mass neutral atoms. It is shown that the lighter $^{39}$K$^{+}$ ions, created by ionizing $^{39}$K atoms in a magneto-optical trap (MOT), when…

Atomic Physics · Physics 2017-03-23 Sourav Dutta , Rahul Sawant , S. A. Rangwala

We report here on the production of an ultracold gas of tightly bound Rb2 molecules in the ro-vibrational triplet ground state, close to quantum degeneracy. This is achieved by optically transferring weakly bound Rb2 molecules to the…

Quantum Physics · Physics 2009-11-13 F. Lang , K. Winkler , C. Strauss , R. Grimm , J. Hecker Denschlag
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