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Understanding and controlling collisions is crucial to the burgeoning field of ultracold molecules. All experiments so far have observed fast loss of molecules from the trap. However, the dominant mechanism for collisional loss is not well…

Ultra-cold RbCs molecules in high-lying vibrational levels of the a$^3\Sigma^+$ ground electronic state are confined in an optical trap. Inelastic collision rates of these molecules with both Rb and Cs atoms are determined for individual…

We show that the lifetime of ultracold ground-state $^{87}$Rb$^{133}$Cs molecules in an optical trap is limited by fast optical excitation of long-lived two-body collision complexes. We partially suppress this loss mechanism by applying…

Atomic Physics · Physics 2020-04-29 Philip D. Gregory , Jacob A. Blackmore , Sarah L. Bromley , Simon L. Cornish

Utilizing single-photon photoassociation, we have achieved ultracold rubidium molecules with a high number density that provides a new efficient approach toward molecular quantum degeneracy. A new detection mechanism for ultracold molecule…

Atomic Physics · Physics 2015-06-12 Jun-Ren Chen , Cheng-Yang Kao , Hung-Bin Chen , Yi-Wei Liu

Understanding collisions between ultracold molecules is crucial for making stable molecular quantum gases and harnessing their rich internal degrees of freedom for quantum engineering. Transient complexes can strongly influence collisional…

Measurements of interactions between cold molecules and ultracold atoms can allow for a detailed understanding of fundamental collision processes. These measurements can be done using various experimental geometries including where both…

Atomic Physics · Physics 2020-03-25 N. J. Fitch , L. P. Parazzoli , H. J. Lewandowski

We study inelastic collisions between CaF molecules and $^{87}$Rb atoms in a dual-species magneto-optical trap. The presence of atoms increases the loss rate of molecules from the trap. By measuring the loss rates and density distributions,…

The collision of molecules at ultracold temperatures is of great importance for understanding the chemical interactions at the quantum regime. While much theoretical work has been devoted to this, experimental data are only available…

Quantum Gases · Physics 2018-01-30 Xin Ye , Mingyang Guo , Maykel L. González-Martínez , Goulven Quéméner , Dajun Wang

We demonstrate the formation of a single RbCs molecule during the merging of two optical tweezers, one containing a single Rb atom and the other a single Cs atom. Both atoms are initially predominantly in the motional ground states of their…

We prepare mixtures of ultracold CaF molecules and Rb atoms in a magnetic trap and study their inelastic collisions. When the atoms are prepared in the spin-stretched state and the molecules in the spin-stretched component of the first…

We investigate collisional loss in an ultracold mixture of $^{40}$K$^{87}$Rb molecules and $^{87}$Rb atoms, where chemical reactions between the two species are energetically forbidden. Through direct detection of the KRb$_{2}^{*}$…

Atomic Physics · Physics 2021-06-01 Matthew A. Nichols , Yi-Xiang Liu , Lingbang Zhu , Ming-Guang Hu , Yu Liu , Kang-Kuen Ni

Exploring inelastic and reactive collisions on the quantum level is a main goal of the developing field of ultracold chemistry. We present first experimental studies of inelastic collisions of metastable ultracold triplet molecules in the…

Cold inelastic collisions between confined cesium (Cs) atoms and Cs$\_2$ molecules are investigated inside a CO$\_2$ laser dipole trap. Inelastic atom-molecule collisions can be observed and measured with a rate coefficient of $\sim 2.5…

Atomic Physics · Physics 2016-09-08 Nassim Zahzam , Thibault Vogt , Marcel Mudrich , Daniel Comparat , Pierre Pillet

Collisions between cold molecules are essential for studying fundamental aspects of quantum chemistry, and may enable formation of quantum degenerate molecular matter by evaporative cooling. However, collisions between trapped, naturally…

Ultracold polar molecules uniquely combine a rich structure of long-lived internal states with access to controllable long-range, anisotropic dipole-dipole interactions. In particular, the rotational states of polar molecules confined in…

Collisional complexes, which are formed as intermediate states in molecular collisions, are typically short-lived and decay within picoseconds. However, in ultracold collisions involving bialkali molecules, complexes can live for…

Chemical Physics · Physics 2023-01-13 Roman Bause , Arthur Christianen , Andreas Schindewolf , Immanuel Bloch , Xin-Yu Luo

Ultracold molecules undergo "sticky collisions" that result in loss even for chemically nonreactive molecules. Sticking times can be enhanced by orders of magnitude by interactions that lead to non-conservation of nuclear spin or total…

Atomic Physics · Physics 2022-12-07 Marijn P Man , Gerrit C Groenenboom , Tijs Karman

We theoretically explore photoassociation by Adiabatic Passage of two colliding cold ^{85}Rb atoms in an atomic trap to form an ultracold Rb_2 molecule. We consider the incoherent thermal nature of the scattering process in a trap and show…

Quantum Physics · Physics 2009-11-13 Evgeny A. Shapiro , Moshe Shapiro , Avi Pe'er , Jun Ye

The collisional stability of ultracold polar molecules in electrostatic traps is considered. Rate constants for collisions that drive molecules from weak-field-seeking to strong-field-seeking states are estimated using a simple model. The…

Atomic Physics · Physics 2009-11-06 John L. Bohn

We report optical trapping of laser-cooled molecules at sufficient density to observe molecule-molecule collisions for the first time in a bulk gas. SrF molecules from a red-detuned magneto-optical trap (MOT) are compressed and cooled in a…

Atomic Physics · Physics 2024-05-09 Varun Jorapur , Thomas K. Langin , Qian Wang , Geoffrey Zheng , David DeMille
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