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Context. Recent Monte Carlo simulations and laboratory studies of interstellar ices have proposed an alternative pathway involving the radical-molecule H-atom abstraction reaction in the overall mechanism of methanol (CH3OH) formation in…

Astrophysics of Galaxies · Physics 2026-01-14 K. -Y. Huang , E. Méndez-Robayo , S. Viti , Mario -A. Higuera -G

The study of hot corinos in Solar-like protostars has been so far mostly limited to the Class 0 phase, hampering our understanding of their origin and evolution. In addition, recent evidence suggests that planet formation starts already…

This review paper summarizes the state-of-the-art in laboratory based interstellar ice chemistry. The focus is on atom addition reactions, illustrating how water, carbon dioxide and methanol can form in the solid state at astronomically…

Astrophysics of Galaxies · Physics 2015-07-13 Harold Linnartz , Sergio Ioppolo , Gleb Fedoseev

Aims: The production of saturated organic molecules in hot cores and corinos is not well understood. The standard approach is to assume that, as temperatures heat up during star formation, methanol and other species evaporate from grain…

Astrophysics · Physics 2009-11-11 R. T. Garrod , E. Herbst

We have studied the dependence of the profiles of molecular abundances and line emission on the accretion flow in the hot ($\ga 100$K) inner region of protoplanetary disks. The gas-phase reactions initiated by evaporation of the ice mantle…

Astrophysics · Physics 2009-11-13 H. Nomura , Y. Aikawa , Y. Nakagawa , T. J. Millar

Experimental and computational chemistry are two disciplines to conduct research in Astrochemistry, providing essential reference data for both astronomical observations and modeling. These approaches not only mutually support each other,…

Comets have similar compositions to interstellar medium ices, suggesting at least some of their molecules maybe inherited from an earlier stage of evolution. To investigate the degree to which this might have occurred we compare the…

Earth and Planetary Astrophysics · Physics 2025-09-26 Karen Willacy , Liton Majumdar , Boncho Bonev , Erika Gibb , Neil Dello Russo , Michael DiSanti , Ronald J. Vervack , Nathan X Roth

In this paper we use observations of molecular tracers in metal rich and alpha-enhanced galaxies to study the effect of abundance changes on molecular chemistry. We selected a sample of metal rich spiral and star bursting objects from the…

Cosmology and Nongalactic Astrophysics · Physics 2015-06-15 Timothy A. Davis , Estelle Bayet , Alison Crocker , Selcuk Topal , Martin Bureau

The ALMA interferometer, with its unprecedented combination of high-sensitivity and high-angular resolution, allows for (sub-)mm wavelength mapping of protostellar systems at Solar System scales. Astrochemistry has benefited from imaging…

We report the detection of four new hot corino sources, G211.47-19.27S, G208.68-19.20N1, G210.49-19.79W and G192.12-11.10 from a survey study of Planck Galactic Cold Clumps in the Orion Molecular Cloud Complex with the Atacama Compact Array…

We use both chirped-pulse Fourier transform and frequency modulated absorption spectroscopy to study the rotational spectrum of 2-methoxyethanol in several frequency regions ranging from 8.7-500 GHz. The resulting rotational parameters…

Glycolaldehyde (HCOCH2OH) is the simplest sugar and an important intermediate in the path toward forming more complex biologically relevant molecules. In this paper we present the first detection of 13 transitions of glycolaldehyde around a…

Solar and Stellar Astrophysics · Physics 2015-06-11 Jes K. Jorgensen , Cecile Favre , Suzanne E. Bisschop , Tyler L. Bourke , Ewine F. van Dishoeck , Markus Schmalzl

Methanol is an important tracer to probe physical and chemical conditions in the interstellar medium of galaxies. Methanol is also the most sensitive target molecule for probing potential space-time variations of the proton-electron mass…

Astrophysics of Galaxies · Physics 2021-08-04 S. Muller , W. Ubachs , K. M. Menten , C. Henkel , N. Kanekar

The relative column densities of the structural isomers methyl formate, glycolaldehyde, and acetic acid are derived for a dozen positions towards the massive star-forming regions MM1 and MM2 in the NGC 6334I complex, which are separated by…

Astrophysics of Galaxies · Physics 2019-10-02 Samer J. El-Abd , Crystal L. Brogan , Todd R. Hunter , Eric R. Willis , Robin T. Garrod , Brett A. McGuire

Binary mixtures of two dimensional, site-based models of alcohols are investigated by computer simulations, with a focus on ideal mixing, local clustering and miscibility trends. Four representative systems are considered: methanol/ethanol,…

Chemical Physics · Physics 2026-04-28 Lydia Chelli , Aurélien Perera

We present the first census of the interstellar Complex Organic Molecules (iCOMs) in the low-mass Class I protostar SVS13-A, obtained by analysing data from the IRAM-30m Large Project ASAI (Astrochemical Surveys At IRAM). They consist of an…

We report the detection of interstellar methoxymethanol (CH$_3$OCH$_2$OH) in ALMA Bands 6 and 7 toward the MM1 core in the high-mass star-forming region NGC 6334I at ~0.1" - 1" spatial resolution. A column density of 4(2) x $10^{18}$…

Extensive molecular dynamics computer simulations have been conducted for ethanol-water liquid mixtures in the water-rich side of the composition range, with 10, 20 and 30 mol % of the alcohol, at temperatures between room temperature and…

Chemical Physics · Physics 2019-06-12 Szilvia Pothoczki , László Pusztai , Imre Bakó

Context: We investigated the molecular gas associated with 6.7 GHz methanol masers throughout the Galaxy using a J=1-0 transition of the CO isotopologues. Methods:Using the 13.7-meter telescope at the Purple Mountain Observatory (PMO), we…

Solar and Stellar Astrophysics · Physics 2014-09-05 Zhiyuan Ren , Yuefang Wu , Tie Liu , Lixin Li , Di Li , Binggang Ju

Class I methanol masers are collisionally pumped and are generally correlated with outflows in star forming sites in the Galaxy. Using the VLA in its A-array configuration, we present a spectral line survey to identify methanol…

Astrophysics of Galaxies · Physics 2016-12-14 W. Cotton , F. Yusef-Zadeh