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In multiferroic BiFeO3 thin films grown on highly mismatched LaAlO3 substrates, we reveal the coexistence of two differently distorted polymorphs that leads to striking features in the temperature dependence of the structural and…

Recent works have shown that the domain walls of room-temperature multiferroic BiFeO3 (BFO) thin films can display distinct and promising functionalities. It is thus important to understand the mechanisms underlying domain formation in…

Materials Science · Physics 2015-05-14 C. J. M. Daumont , S. Farokhipoor , A. Ferri , J. C. Wojdel , Jorge Iniguez , B. J. Kooi , B. Noheda

We measure the remnant polarization of ferroelectric domains in BiFeO3 films down to 3.6 nm using low energy electron and photoelectron emission microscopy. The measured polarization decays strongly below a critical thickness of 5-7 nm…

Materials Science · Physics 2013-01-04 J. E. Rault , W. Ren , S. Prosandeev , S. Lisenkov , D. Sando , S. Fusil , M. Bibes , A. Barthelemy , L. Bellaiche , N. Barrett

We have investigated the structural and magnetic properties of BiFeO$_3$ (BFO) thin films grown over (100)-oriented Si substrates by rf magnetron sputtering in a new route under O$_2$ free low pressure Ar atmosphere. Single-phase BFO films…

Materials Science · Physics 2018-04-03 G. A. Gomez-Iriarte , C. Labre , L. A. S. de Oliveira , J. P. Sinnecker

NiFe$_2$O$_4$ thin films with varying thickness were grown on SrTiO$_3$(001) by reactive molecular beam epitaxy. Soft and hard x-ray photoelectron spectroscopy measurements reveal a homogeneous cation distribution throughout the whole film…

Materials Science · Physics 2020-07-01 J. Rodewald , J. Thien , K. Ruwisch , F. Bertram , K. Kuepper , J. Wollschläger

Antiferromagnetic thin films are currently generating considerable excitement for low dissipation magnonics and spintronics. However, while tuneable antiferromagnetic textures form the backbone of functional devices, they are virtually…

A topological insulating phase has theoretically been predicted for the thermodynamically unstable perovskite phase of YBiO$_{3}$. Here, it is shown that the crystal structure of the Y-Bi-O system can be controlled by using a BaBiO$_{3}$…

We report on the evolution of the magnetic structure of BiFeO3 thin films grown on SrTiO3 substrates as a function of Sm doping. We determined the magnetic structure using neutron diffraction. We found that as Sm increases, the magnetic…

There is growing evidence that domain walls in ferroics can possess emergent properties that are absent in bulk materials. For example, 180 domain walls in the ferroelectric-antiferromagnetic BiFeO3 are particularly interesting because they…

Metastable manganite perovskites displaying the antiferromagnetic so-called E-phase are predicted to be multiferroic. Due to the need of high-pressures for the synthesis of this phase, this prediction has only been confirmed in bulk HoMnO3.…

Materials Science · Physics 2009-11-13 D. Rubi , Sriram Venkatesan , B. J. Kooi , J. Th. M. De Hosson , T. T. M. Palstra , B. Noheda

Thin films of (1-x)BiFeO<sub>3</sub>-xPbTiO<sub>3</sub> (BF-xPT) with x ~ 0.60 were fabricated on Pt/Si substrates by chemical solution deposition of precursor BF and PT layers alternately in three different multilayer configurations. These…

BiFeO$_3$ thin films can be epitaxially stabilized in a nearly-tetragonal phase under a high biaxial compressive strain. Here we investigate the polarized Raman spectra of constrained BiFeO$_3$ films with tetragonal-like (BFO-T),…

Materials Science · Physics 2015-05-18 M. N. Iliev , M. V. Abrashev , D. Mazumdar , V. Shelke , A. Gupta

We have combined neutron scattering and piezoresponse force microscopy to study the relation between the exchange bias observed in CoFeB/BiFeO3 heterostructures and the multiferroic domain structure of the BiFeO3 films. We show that the…

Materials Science · Physics 2009-11-13 H. Bea , M. Bibes , F. Ott , B. Dupe , X. -H. Zhu , S. Petit , S. Fusil , C. Deranlot , K. Bouzehouane , A. Barthelemy

The lattice of (001)-oriented BiFeO$_3$ epitaxial thin film has been identified by synchrotron x-ray diffraction. By choosing proper scattering zones containing the fixed (001) reflection, we have shown that low-symmetry phases similar to a…

Materials Science · Physics 2009-11-11 Guangyong Xu , H. Hiraka , G. Shirane , Jiefang Li , Junling Wang , D. Viehland

Here, we compare the stabilities of different III-V crystals configurations on stepped Si substrates, with or without anti-phase boundaries, for abrupt and compensated interfaces, using density functional theory. Thermodynamic stability of…

Materials Science · Physics 2024-08-29 D. Gupta , S. Pallikkara Chandrasekharan , S. Thébaud , C. Cornet , L. Pedesseau

We report a study on the thermodynamic stability and structure analysis of the epitaxial BiFeO3 (BFO) thin films grown on YAlO3 (YAO) substrate. First we observe a phase transition of MC-MA-T occurs in thin sample (<60 nm) with an utter…

Materials Science · Physics 2015-06-04 Heng-Jui Liu , Hsiang-Jung Chen , Wen-I Liang , Chen-Wei Liang , Hsin-Yi Lee , Su-Jien Lin , Ying-Hao Chu

In the present study we have demonstrated epitaxial stabilization of the metastable magnetically-hard $\varepsilon$-Fe$_2$O$_3$ phase on top of a thin MgO(111) buffer layer grown onto the GaN (0001) surface. The primary purpose to introduce…

Mesoscale and Nanoscale Physics · Physics 2019-09-11 Victor Ukleev , Mikhail Volkov , Alexander Korovin , Thomas Saerbeck , Nikolai Sokolov , Sergey Suturin

The presence of domains in ferroic materials can negatively affect their macroscopic properties and hence their usefulness in device applications. From an experimental perspective, measuring materials comprising multiple domains can…

Strongly Correlated Electrons · Physics 2019-02-20 N. Waterfield Price , A. M. Vibhakar , R. D. Johnson , J. Schad , W. Saenrang , A. Bombardi , F. P. Chmiel , C. B. Eom , P. G. Radaelli

Hexagonal LuFeO$_3$ has drawn a lot of research attention due to its contentious room-temperature multiferroicity. Due to the unstability of hexagonal phase in the bulk form, most experimental studies focused on LuFeO$_3$ thin films which…

Materials Science · Physics 2016-03-09 L. Lin , H. M. Zhang , M. F. Liu , Shoudong Shen , S. Zhou , D. Li , X. Wang , Z. B. Yan , Z. D. Zhang , Jun Zhao , Shuai Dong , J. -M. Liu

Ferroelectric films usually have phase states and physical properties very different from those of bulk ferroelectrics. Here we propose free-standing ferroelectric-elastic multilayers as a bridge between these two material systems. Using a…

Materials Science · Physics 2011-10-18 S. Prokhorenko , N. A. Pertsev