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Graphene is a material of great potential in a broad range of applications, for each of which specific tuning of the materials properties is required. This can be achieved, for example, by covalent functionalization. We have exploited two…

The controlled functionalization of graphene is critical for tuning and enhancing its properties, thereby expanding its potential applications. Covalent functionalization offers a deeper tuning of the geometric and electronic structure of…

Materials Science · Physics 2025-05-07 Ylea Vlamidis , Carmela Marinelli , Aldo Moscardini , Paolo Faraci , Stefan Heun , Stefano Veronesi

Optical extinction and absorption enhancement in the infrared range of a monolayer graphene sheet by patterning split ring resonators (SRRs) is studied. It is found that the electric mode is stronger in enhancing infrared extinction and…

Optics · Physics 2014-07-31 Yuancheng Fan , Zeyong Wei , Zhengren Zhang , Hongqiang Li

Graphene monolayer grown by Si evaporation from the 0001 surface of SiC displays a moir\'e pattern of corrugation whose structure is ambiguous: different measurements and theoretical studies show either protruding bumps surrounded by…

Mesoscale and Nanoscale Physics · Physics 2018-04-27 Tommaso Cavallucci , Valentina Tozzini

A one-dimensional dielectric grating, based on a simple geometry, is proposed and investigated to enhance light absorption in a monolayer graphene exploiting guided mode resonances. Numerical findings reveal that the optimized configuration…

X-ray photoelectron spectroscopy of graphene is important both for its characterization and as a model for other carbon materials. Despite great recent interest, the intrinsic photoemission of its single layer has not been unambiguously…

We present a multiscale quantum mechanics/classical (QM/MM) approach for modeling surface-enhanced infrared absorption (SEIRA) spectra of molecules adsorbed on plasmonic nanostructures. The molecular subsystem is described at the density…

Chemical Physics · Physics 2025-11-05 Sveva Sodomaco , Piero Lafiosca , Tommaso Giovannini , Chiara Cappelli

Detecting trace molecules remains a significant challenge. Surface-enhanced infrared absorption (SEIRA) based on plasmonic nanostructures, particularly graphene, has emerged as a promising approach to enhance sensing sensitivity. While…

The covalent functionalization of graphene represents a main topic in the growing field of nano materials. The reductive exfoliation of graphite with concomitant functionalization of the respective graphenide intermediates provides a…

Chemical Physics · Physics 2018-05-31 Philipp Vecera , Konstantin Edelthalhammer , Frank Hauke , Andreas Hirsch

We calculate the properties of a graphene monolayer on the Ir(111) surface, using the model in which the periodicities of the two structures are assumed equal, instead of the observed slight mismatch which leads to a large superperiodic…

Mesoscale and Nanoscale Physics · Physics 2015-05-19 R. Brako , D. Sokcevic , P. Lazic , N. Atodiresei

Surface-enhanced spectroscopy techniques are the method-of-choice to characterize adsorbed intermediates occurring during electrochemical reactions, which are crucial in realizing a green sustainable future. Characterizing species with low…

Mesoscale and Nanoscale Physics · Physics 2023-07-21 Malo Duportal , Luca M. Berger , Stefan A. Maier , Andreas Tittl , Katharina Krischer

The vibrational frequency of carbon monoxide (CO) adsorbed on ceria-based catalysts serves as a sensitive probe for identifying exposed surface facets, provided that experimental reference data on well-defined single-crystal surfaces and…

The non-covalent functionalisation of graphene is an attractive strategy to alter the surface chemistry of graphene without damaging its superior electrical and mechanical properties. Using the facile method of aqueous-phase…

We calculate the potential energy surfaces for graphene adsorbed on Cu(111), Ni(111), and Co(0001) using density functional theory and the Random Phase Approximation (RPA). For these adsorption systems covalent and dispersive interactions…

Materials Science · Physics 2012-08-24 T. Olsen , J. Yan , J. J. Mortensen , K. S. Thygesen

We investigate advanced CMOS-compatible Graphene/Silicon active metasurfaces based on guided-mode resonance filters. The simulated results show a high extinction ratio (>25 dB), narrow linewidth (~1.5 nm @1550 nm), quality factor of Q~1000,…

Monolayer graphene was deposited on a Si wafer substrate decorated with SiO2 nanoparticles (NPs) and then exposed to aryl radicals that were generated in situ from their diazonium precursors. Using micro-Raman mapping, the aryl radicals…

Materials Science · Physics 2012-11-28 Q. Wu , Y. Wu , Y. Hao , J. Geng , M. Charlton , S. Chen , Y. Ren , H. Ji , H. Li , D. W. Boukhvalov , R. D. Piner , C. W. Bielawski , R. S. Ruoff

The reflectivity of low energy electrons from graphene on copper substrates is studied both experimentally and theoretically. Well-known oscillations in the reflectivity of electrons with energies 0 - 8 eV above the vacuum level are…

Mesoscale and Nanoscale Physics · Physics 2015-06-15 N. Srivastava , Qin Gao , M. Widom , R. M. Feenstra , Shu Nie , K. F. McCarty , I. V. Vlassiouk

We report semiconducting behavior of monolayer graphene enabled through plasma activation of substrate surfaces. The graphene devices are fabricated by mechanical exfoliation onto pre-processed SiO2/Si substrates. Contrary to pristine…

This work presents an innovative magnetoelastic (ME) biosensor using graphene functionalized with the SARS-CoV-2 N protein for antibody detection via magnetoelastic resonance. Graphene was chosen for its biocompatibility and high surface…

We report a non-contact method for conductivity and sheet resistance measurements of graphene samples using a high Q microwave dielectric resonator perturbation technique, with the aim of fast and accurate measurement of microwave…

Materials Science · Physics 2015-06-15 L Hao , J Gallop , S Goniszewski , A Gregory , O Shaforost , N Klein , R Yakimova
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