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We propose an innovative, easy-to-implement approach to synthesize large-area singlecrystalline graphene sheets by chemical vapor deposition on copper foil. This method doubly takes advantage of residual oxygen present in the gas phase.…

In ceria-based catalysis, the shape of the catalyst particle, which determines the exposed crystal facets, profoundly affects its reactivity. The vibrational frequency of adsorbed carbon monoxide (CO) can be used as a sensitive probe to…

Surface Enhanced Infrared Absorption (SEIRA) is an experimental method where trace amount of a compound can be detected with high sensibility. This high detection sensibility is the result of the interaction of the molecules with a…

The adoption of graphene in electronics, optoelectronics and photonics is hindered by the difficulty in obtaining high quality material on technologically-relevant substrates, over wafer-scale sizes and with metal contamination levels…

Electron wavefunctions in twisted bilayer graphene may have a strong single layer character or be intrinsically delocalized between layers, with their nature often determined by how energetically close they are to the Dirac point. In this…

Mesoscale and Nanoscale Physics · Physics 2014-10-06 Chi-Ken Lu , H. A. Fertig

When light is absorbed by a semiconductor, photoexcited charge carriers enhance the absorption of far-infrared radiation due to intraband transitions. We observe the opposite behavior in monolayer graphene, a zero-gap semiconductor with…

Mesoscale and Nanoscale Physics · Physics 2013-04-02 A. J. Frenzel , C. H. Lui , W. Fang , N. L. Nair , P. K. Herring , P. Jarillo-Herrero , J. Kong , N. Gedik

We present a hybrid surface-enhanced Raman spectroscopy (SERS) platform based on dielectric silicon metasurfaces integrated with functionalized graphene for the selective detection of biomolecules such as prolactin and SARS-CoV-2…

We continue the study of surface corrugations influence on the monolayer graphene local electromagnetic response in terahertz range we started earlier. The effects of radiative decay, double-valley structure of charge carriers spectrum in…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Yu. A. Firsov , N. E. Firsova

Two different types of boron-doped graphene/copper interfaces synthesized using two different flow rates of Ar through the bubbler containing the boron source were studied. X-ray photoelectron spectra (XPS) and optically stimulated electron…

We present a method where a bioactive functional layer on an electrically conductive thin film with high sheet resistance can be effectively used for complementary electrochemical impedance spectroscopy biosensing. The functional layer's…

Materials Science · Physics 2025-04-04 Munis Khan , Ivan Mijakovic , Santosh Pandit , August Yurgens

We investigate theoretically the adhesion and electronic properties of graphene on a muscovite mica surface using the density functional theory (DFT) with van der Waals (vdW) interactions taken into account (the vdW-DF approach). We found…

Mesoscale and Nanoscale Physics · Physics 2011-01-25 A. N. Rudenko , F. J. Keil , M. I. Katsnelson , A. I. Lichtenstein

Mid-infrared (mid-IR) photo-detection has been recently growing in importance because of its multiple applications, including vibrational spectroscopy and thermal imaging. We propose and demonstrate a novel pyro-resistive photo-detection…

Results of a study on the electrochemical properties of exfoliated single and multilayer graphene flakes are presented. Graphene flakes were deposited on silicon/silicon oxide wafers to enable fast and accurate characterization by optical…

Mesoscale and Nanoscale Physics · Physics 2011-10-11 Anna T. Valota , Ian A. Kinloch , Kostya S. Novoselov , Cinzia Casiraghi , Axel Eckmann , Ernie W. Hill , Robert A. W. Dryfe

We present an environmentally benign methodology for the covalent functionalization (arylation) of reduced graphene oxide (rGO) nanosheets with arylazo sulfones. A variety of tagged aryl units were conveniently accommodated at the rGO…

Graphene has been suggested as an ultimately thin functional coating for metallurgical alloys such as steels. However, even on pure iron (Fe), the parent phase of steels, growth of high quality graphene films remains largely elusive to…

Surface-enhanced infrared absorption (SEIRA) spectroscopy exploits the field enhancement near nanophotonic structures for highly sensitive characterization of (bio)molecules. The vibrational signature observed in SEIRA spectra is typically…

The monolithic integration of novel nanomaterials with mature and established technologies has considerably widened the scope and potential of nanophotonics. For example, the integration of single semiconductor quantum dots into photonic…

As the synthesis of graphene on copper became one of the primary preparation methods for both fundamental research and industrial application, Raman spectra of graphene/Cu systems need to be quantitatively understood regarding how their…

Materials Science · Physics 2020-08-07 Jieun Choi , Seonghyun Koo , Myeongin Song , Daeyool Jung , Sungyool Choi , Sunmin Ryu

Non-destructive and rapid evaluation of graphene directly on the growth substrate (Cu foils) by dark field (DF) optical microscopy is demonstrated. Without any additional treatment, graphene on Cu foils with various coverages can be quickly…

We measure the adsorption height of hydrogen-intercalated quasi-free-standing monolayer graphene on the (0001) face of 6H silicon carbide by the normal incidence x-ray standing wave technique. A density functional calculation for the full…