Related papers: The Gibbs paradox
For an ideal gas consisting N molecules within a volume V, the volume accessible to each molecule at an instantaneous time is V/N. The rest of the volume, (N-1)(V/N), is occupied by other (N-1) molecules. The textbook assumption that a…
The article reveals the error that in classical thermodynamics leads to the Gibbs paradox. The essence of the error lies in the fact that the entropy of an ideal gas is attributed to additive quantities, but it is not correct. The value of…
Based on a reconsideration of the Gibbs paradox, we show that a residual, non-extensive term in entropy turns up upon mixing identical particles, whether they are indistinguishable or not. The positive contribution from this residual…
Gibbs paradox in the context of statistical mechanics addresses the issue of additivity of entropy of mixing gases. The usual discussion attributes the paradoxical situation to classical distinguishability of identical particles and credits…
This paper introduces the basic concepts of information theory. Based on these concepts, we regard the states in the state space and the types of ideal gases as the symbols in a symbol set to calculate the mixing entropy of ideal gas…
In the framework of Gibbs statistical theory, the issue of the distribution of particle sizes forming the statistical system and the moments of this distribution are considered. This task is relevant for a wide variety of applications. The…
A statistical thermodynamic approach of moving particles forming an elastic body is presented which leads to reveal molecular-mechanical properties of classical and nonextensive dynamical systems. We derive the Boltzmann-Gibbs (BG) entropy…
The paper analyzes the entropy of a system composed by non-interacting and indistinguishable particles whose quantum state numbers are modelled as independent and identically distributed classical random variables. The crucial observation…
We present a fully quantum solution to the Gibbs paradox (GP) with an illustration based on a gedanken experiment with two particles trapped in an infinite potential well. The well is divided into two cells by a solid wall, which could be…
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature of the theory since every material in…
This article presents the results of research into the causes of the Gibbs paradox in the formulation discussed by J. W. Gibbs himself. In this formulation, we are talking about an inexplicable (paradoxical) jump in the entropy of mixing of…
The issue of the Gibbs paradox is that when considering mixing of two gases within classical thermodynamics, the entropy of mixing appears to be a discontinuous function of the difference between the gases: it is finite for whatever small…
The classical Gibbs paradox concerns the entropy change upon mixing two gases. Whether an observer assigns an entropy increase to the process depends on their ability to distinguish the gases. A resolution is that an "ignorant" observer,…
The Gibbs entropy of a macroscopic classical system is a function of a probability distribution over phase space, i.e., of an ensemble. In contrast, the Boltzmann entropy is a function on phase space, and is thus defined for an individual…
In its continuous version, the entropy functional measuring the information content of a given probability density may be plagued by a "measure" problem that results from improper weighting of phase space. This issue is addressed…
It is shown that the BBGKY equations for a particle interacting with ideal gas imply exact relations between probability distribution of path of the particle, its derivatives in respect to the gas density and irreducible many-particle…
We show in this note that Gibbs paradox arises not due to application of thermodynamic principles, whether classical or statistical or even quantum mechanical, but due to incorrect application of mathematics to the process of mixing of…
The Gibbs paradox of the first kind (GP1) refers to the false increase in entropy which, in statistical mechanics, is calculated from the process of combining two gas systems S1 and S2 consisting of distinguishable particles. Presented in a…
As no heat effect and mechanical work are observed, we have a simple experimental resolution of the Gibbs paradox: both the thermodynamic entropy of mixing and the Gibbs free energy change are zero during the formation of any ideal…
The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…