Related papers: The Gibbs paradox
We prove a proposition that the entropy of the system composed of finite $N$ molecules of ideal gas is the $q$-entropy or Havrda-Charv\'at-Tsallis entropy, which is also known as Tsallis entropy, with the entropic index…
Activation/deactivation by inelastic collisions have been extensively studied at unimolecular reactions in gas phase where they are crucial for equilibration. As equilibration means an increase of entropy, the mechanism can also be…
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…
We use a simple hard-core gas model to study the dynamics of small exploding systems. The system is initially prepared in a thermalized state in a spherical container and then allowed to expand freely into the vacuum. We follow the…
A generalization of the Gibbs entropy postulate is proposed based on the BBGKY hierarchy as the nonequilibrium entropy for a system of N interacting particles. This entropy satisfies the basic principles of thermodynamics in the sense that…
The Gibbs paradox is a conventional paradox in classical statistical mechanics, typically resolved by invoking quantum indistinguishability through the 1/N! correction. In this letter, we present a resolution within classical ensemble…
The dissipation rate due to inelastic collisions between equally charged, insulating particles in a granular gas is calculated. It is equal to the known dissipation rate for uncharged granular media multiplied by a Boltzmann-like factor,…
It is well known that equilibrium in a thermodynamic system results from a competition or balance between lowering the energy and increasing the entropy, or at least the product of the temperature and entropy. This is remarkably similar to…
The formulas for the entropy of ideal gases mixture and the entropy change in mixing of ideal gases on the basis of the third law of thermodynamics were obtained. It is shown that when using these formulas, the Gibbs paradox within the…
We consider a statistical mechanics of rotating ideal gas consisting of classical non-relativistic spinning particles. The microscopic structure elements of the system are massive point particles with a nonzero proper angular momentum. The…
By example of a particle interacting with ideal gas, it is shown that statistics of collisions in statistical mechanics at any degree of the gas rarefaction qualitatively differs from that conjugated with Boltzmann's hypothetical molecular…
Identical classical particles are distinguishable. This distinguishability affects the number of ways W a macrostate can be realized on the micro-level, and from the relation S = k ln W leads to a non-extensive expression for the entropy.…
This study investigates the steady Boltzmann equation in one spatial variable for a polyatomic single-component gas in a half-space. Inflow boundary conditions are assumed at the half-space boundary, where particles entering the half-space…
We consider the Statistical Mechanics of systems of particles satisfying the $q$-commutation relations recently proposed by Greenberg and others. We show that although the commutation relations approach Bose (resp.\ Fermi) relations for…
The BBGKY hierarchy of equations for a particle interacting with an ideal gas is investigated. Principal properties of its solutions are disclosed, as exact identities which connect probability distribution of path of the particle, its…
Defining the entropy of classical particles raises a number of paradoxes and ambiguities, some of which have been known for over a century. Several, such as Gibbs' paradox, involve the fact that classical particles are distinguishable, and…
It is argued that a Gibbsian formula for the space-time distribution of microscopic trajectories of a nonequilibrium system provides a unifying framework for recent results on the fluctuations of the entropy production. The variable entropy…
Dissipative processes cause collisionless plasmas in many systems to develop nonthermal particle distributions with broad power-law tails. The prevalence of power-law energy distributions in space/astrophysical observations and kinetic…
Statistical thermodynamics is valuable as a conceptual structure that shapes our thinking about equilibrium thermodynamic states. A cloud of unresolved questions surrounding the foundations of the theory could lead an impartial observer to…
The mixing of two different gases is one of the most common natural phenomena, with applications ranging from CO$_2$ capture to water purification. Traditionally, mixing is analyzed in the context of local thermal equilibrium, where systems…