Related papers: The Gibbs paradox
The Gibbs Paradox is essentially a set of open questions as to how sameness of gases or fluids (or masses, more generally) are to be treated in thermodynamics and statistical mechanics. They have a variety of answers, some restricted to…
The hypothesis of ``molecular chaos'' is shown to fail when applied to spatially inhomogeneous evolution of a low-density gas, because this hypothesis is incompatible with reduction of interactions of gas particles to ``collisions''. The…
The standard theory of ideal gases ignores the interaction of the gas particles with the thermal radiation (photon gas) that fills the otherwise vacuum space between them. This is an unphysical feature since every material absorbs and…
The probability distribution of the velocity of gas molecules in a closed container is described by the kinetic theory of gases. When molecules collide or impact the walls of a container, they exchange energy and momentum in accordance with…
The dynamics of rapidly collapsing bubbles are of great interest due to the high degree of energy focusing that occurs withing the bubble. Molecular dynamics provides a way to model the interior of the bubble and couple the gas dynamics…
We do not have a final answer to the question of why galaxies choose a particular internal mass distribution. Here we examine whether the distribution is set by thermodynamic equilibrium (TE). Traditionally, TE is discarded for a number of…
The ``Gibbs Paradox'' refers to several related questions concerning entropy in thermodynamics and statistical mechanics: whether it is an extensive quantity or not, how it changes when identical particles are mixed, and the proper way to…
The entropy of Boltzmann-Gibbs, as proved by Shannon and Khinchin, is based on four axioms, where the fourth one concerns additivity. The group theoretic entropies make use of formal group theory to replace this axiom with a more general…
By combining the upper and lower bounds to the free energy as given by the Gibbs inequality for two systems with the same intermolecular interactions but with external fields differing from each other only in a finite region of space Gamma,…
We investigate the overdamped stochastic dynamics of a particle in an asymptotically flat external potential field, in contact with a thermal bath. For an infinite system size, the particles may escape the force field and diffuse freely at…
In statistical mechanics Gibbs' paradox is avoided if the particles of a gas are assumed to be indistinguishable. The resulting entropy then agrees with the empirically tested thermodynamic entropy up to a term proportional to the logarithm…
Information (I) is defined as the amount of the data after data compression. The first law of information theory: the total amount of data L (the sum of entropy S and information I) of an isolated system remains unchanged. The second law of…
There is the Gibbs theorem in thermodynamics, according to which the entropy of the mixture of ideal gases is equal to the sum of the entropies of the components of the mixture. J. W. Gibbs proved this by a mathematical derivation from the…
This paper generalizes the entropy maximization problem leading to the Boltzmann-Gibbs distribution through the nonadditive entropy $S_{q,s}(p)=k_{s}\sum^{W}_{i\geq1}p_{i}\ln_{q}1/p_{i}$, $q\in(0,1)$, which is a rescaled version of $S_{q}$…
In the framework of the Gibbs statistical theory, the question of the size of the particles forming the statistical system is investigated. This task is relevant for a wide variety of applications. The distribution for particle sizes and…
The analysis of the arguments within the limits of the classical thermodynamics that lead to the Gibbs paradox was made. Features of preconditions used in the derivation of the entropy of mixing of ideal gases that caused the appearance of…
It is always some constraint that yields any nontrivial structure from statistical averages. As epitomized by the Boltzmann distribution, the energy conservation is often the principal constraint acting on mechanical systems. Here, we…
In kinetic theory, the classic $n \Sigma v$ approach calculates the rate of particle interactions from local quantities: the number density of particles $n$, the cross-section $\Sigma$, and the average relative speed $v$. In stellar…
The approach of an ideal gas to equilibrium is simulated through a generalization of the Ehrenfest ball-and-box model. In the present model, the interior of each box is discretized, {\it i.e.}, balls/particles live in cells whose occupation…
Microscopic formula to describe the entropy of biomolecular solutions are derived based on the Gibbs formula of entropy, and the generalized Langevin theory combined with the RISM/3D-RISM theory. Two formula are derived: one is concerned…