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The Random First Order Transition (RFOT) theory of glasses provides a unified framework for explaining the observed correlations of the kinetic and thermodynamic behaviors of glass-forming liquids having a wide variety of chemical…

Soft Condensed Matter · Physics 2025-07-29 M. H. Brown , P. G. Wolynes

It has recently been shown that a free energy for Baxter's sticky hard sphere fluid is uniquely defined within the framework of fundamental measure theory (FMT) for the inhomogeneous hard sphere fluid, provided that it obeys scaled-particle…

Soft Condensed Matter · Physics 2015-06-03 Hendrik Hansen-Goos , Mark A. Miller , J. S. Wettlaufer

Collective motion over increasing length scales is a signature of the vitrification process of liquids. We demonstrate the emergence of distinct static and dynamic length scales probed near the free surface in fully equilibrated…

Statistical Mechanics · Physics 2022-11-28 Hailong Peng , Huashan Liu , Thomas Voigtmann

The number of compact structures of a single condensed polymer (SCP), with similar free energies, grows exponentially with the degree of polymerization. In analogy with structural glasses (SGs), we expect that at low temperatures chain…

Soft Condensed Matter · Physics 2021-04-07 Hyun Woo Cho , Guang Shi , T. R. Kirkpatrick , D. Thirumalai

Quantum systems of indistinguishable particles are commonly described using the formalism of second quantisation, which relies on the assumption that any admissible quantum state must be either symmetric or anti-symmetric under particle…

Quantum Physics · Physics 2023-07-13 Benjamin Yadin , Benjamin Morris , Kay Brandner

The equations of fluctuating nonlinear hydrodynamics for a two component mixture are obtained with a proper choice of slow variables which correspond to the conservation laws in the system. Using these nonlinear equations we construct the…

Statistical Mechanics · Physics 2016-01-20 Madhu Priya , Neeta Bidhoodi , Shankar P. Das

We compare dynamical heterogeneities in equilibrated supercooled liquids and in the nonequilibrium glassy state within the framework of the random first order transition theory. Fluctuating mobility generation and transport in the glass are…

Statistical Mechanics · Physics 2014-01-21 Apiwat Wisitsorasak , Peter G. Wolynes

The thermodynamic entropy of coarse-grained (CG) models stands as one of the most important properties for quantifying the missing information during the CG process and for establishing transferable (or extendible) CG interactions. However,…

Chemical Physics · Physics 2024-04-10 Jaehyeok Jin , David R. Reichman

We perform stringent tests of thermodynamic theories of the glass transition over the experimentally relevant temperature regime for several simulated glass-formers. The swap Monte Carlo algorithm is used to estimate the configurational…

Statistical Mechanics · Physics 2019-10-03 Misaki Ozawa , Camille Scalliet , Andrea Ninarello , Ludovic Berthier

In the context of the random first order transition theory we use an extended mode coupling theory of the glass transition that includes activated events to account for spatiotemporal structures in aging and rejuvenating glasses. We…

Disordered Systems and Neural Networks · Physics 2015-06-15 Apiwat Wisitsorasak , Peter G. Wolynes

Kinetic facilitated models and the Mode Coupling Theory (MCT) model B are within those systems known to exhibit a discontinuous dynamical transition with a two step relaxation. We consider a general scaling approach, within mean field…

Statistical Mechanics · Physics 2016-05-26 Antonio de Candia , Annalisa Fierro , Antonio Coniglio

We uncover emergent universality arising in the equilibration dynamics of multimode continuous-variable systems. Specifically, we study the ensemble of pure states supported on a small subsystem of a few modes, generated by Gaussian…

Quantum Physics · Physics 2024-12-25 Chang Liu , Qi Camm Huang , Wen Wei Ho

We present a detailed derivation of a microscopic theory for the glass transition of a liquid enclosed between two parallel walls relying on a mode-coupling approximation. This geometry lacks translational invariance perpendicular to the…

Soft Condensed Matter · Physics 2012-08-16 Simon Lang , Rolf Schilling , Vincent Krakoviack , Thomas Franosch

We discuss a Statistical Mechanics approach in the manner of Edwards to the ``inherent states'' (defined as the stable configurations in the potential energy landscape) of glassy systems and granular materials. We show that at stationarity…

Statistical Mechanics · Physics 2009-11-07 Annalisa Fierro , Mario Nicodemi , Antonio Coniglio

We study quantum and classical many-body Hamiltonian systems that combine integrable contact interactions with generic long-range two-body potentials. We show that the dynamics of local observables can be cast into a generalized…

Statistical Mechanics · Physics 2026-01-22 Leonardo Biagetti , Maciej Lebek , Milosz Panfil , Jacopo De Nardis

We show that a fluid under strong spatially periodic confinement displays a glass transition within mode-coupling theory (MCT) at a much lower density than the corresponding bulk system. We use fluctuating hydrodynamics, with confinement…

Soft Condensed Matter · Physics 2013-03-14 Saroj Kumar Nandi , Sarika Maitra Bhattacharyya , Sriram Ramaswamy

A recent mode coupling theory of higher-order correlation functions is tested on a simple hard-sphere fluid system at intermediate densities. Multi-point and multi-time correlation functions of the densities of conserved variables are…

Statistical Mechanics · Physics 2009-11-07 Ramses van Zon , Jeremy Schofield

We give a brief introduction to the mode-coupling theory of the glass transition, a theory which was proposed a while ago to describe the dynamics of supercooled liquids. After presenting the basic equations of the theory, we review some of…

Statistical Mechanics · Physics 2008-02-03 W. Kob

We introduce a system of self-propelled agents (active Brownian particles) with velocity alignment in two spatial dimensions and derive a mean-field theory from the microscopic dynamics via a nonlinear Fokker-Planck equation and a moment…

Statistical Mechanics · Physics 2011-09-26 Pawel Romanczuk , Lutz Schimansky-Geier

The dynamics of self-propelled colloidal particles are strongly influenced by their environment through hydrodynamic and, in many cases, chemical interactions. We develop a theoretical framework to describe the motion of confined active…

Fluid Dynamics · Physics 2025-08-29 Günther Turk , Rajesh Singh , Howard A. Stone