English

Autophoretic skating along permeable surfaces

Fluid Dynamics 2025-08-29 v2 Soft Condensed Matter

Abstract

The dynamics of self-propelled colloidal particles are strongly influenced by their environment through hydrodynamic and, in many cases, chemical interactions. We develop a theoretical framework to describe the motion of confined active particles by combining the Lorentz reciprocal theorem with a Galerkin discretisation of surface fields, yielding an equation of motion that efficiently captures self-propulsion without requiring an explicit solution for the bulk fluid flow. Applying this framework, we identify and characterise the long-time behaviours of a Janus particle near rigid, permeable, and fluid-fluid interfaces, revealing distinct motility regimes, including surface-bound skating, stable hovering, and chemo-hydrodynamic reflection. Our results demonstrate how the solute permeability and the viscosity contrast of the surface influence a particle's dynamics, providing valuable insights into experimentally relevant guidance mechanisms for autophoretic particles. The computational efficiency of our method makes it particularly well-suited for systematic parameter sweeps, offering a powerful tool for mapping the phase space of confined active particles and informing high-fidelity numerical simulations.

Keywords

Cite

@article{arxiv.2504.08702,
  title  = {Autophoretic skating along permeable surfaces},
  author = {Günther Turk and Rajesh Singh and Howard A. Stone},
  journal= {arXiv preprint arXiv:2504.08702},
  year   = {2025}
}

Comments

31 pages, 16 figures

R2 v1 2026-06-28T22:55:07.230Z