Mode-coupling theory of the glass transition for confined fluids
Abstract
We present a detailed derivation of a microscopic theory for the glass transition of a liquid enclosed between two parallel walls relying on a mode-coupling approximation. This geometry lacks translational invariance perpendicular to the walls, which implies that the density profile and the density-density correlation function depends explicitly on the distances to the walls. We discuss the residual symmetry properties in slab geometry and introduce a symmetry adapted complete set of two-point correlation functions. Since the currents naturally split into components parallel and perpendicular to the walls the mathematical structure of the theory differs from the established mode-coupling equations in bulk. We prove that the equations for the nonergodicity parameters still display a covariance property similar to bulk liquids.
Keywords
Cite
@article{arxiv.1208.1929,
title = {Mode-coupling theory of the glass transition for confined fluids},
author = {Simon Lang and Rolf Schilling and Vincent Krakoviack and Thomas Franosch},
journal= {arXiv preprint arXiv:1208.1929},
year = {2012}
}
Comments
16 pages; to be published in PRE