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We report the first detection on Titan of the small cyclic molecule cyclopropenylidene (c-C3H2) from high sensitivity spectroscopic observations made with the Atacama Large Millimeter/sub-millimeter Array (ALMA). Multiple lines of…

We have observed the HC3N (J=10-9) and N2H+ (J=1-0) lines toward the Vela C molecular clouds with the Mopra 22 m telescope to study chemical characteristics of dense cores. The intensity distributions of these molecules are similar to each…

AIM: We have recently developed a microscopic Monte Carlo approach to study surface chemistry on interstellar grains and the morphology of ice mantles. The method is designed to eliminate the problems inherent in the rate-equation formalism…

Astrophysics · Physics 2009-11-13 Q. Chang , H. M. Cuppen , E. Herbst

Solid state astrochemical reaction pathways have the potential to link the formation of small nitrogen-bearing species, like NH3 and HNCO, and prebiotic molecules, specifically amino acids. To date, the chemical origin of such small…

Astrophysics of Galaxies · Physics 2017-05-26 Gleb Fedoseev , Sergio Ioppolo , Dongfeng Zhao , Thanja Lamberts , Harold Linnartz

We report the first detection in the interstellar medium of a C$_2$H$_5$O$_2$N isomer: $syn$-glycolamide (NH$_2$C(O)CH$_2$OH). The exquisite sensitivity at sub-mK levels of an ultra-deep spectral survey carried out with the Yebes 40m and…

Star-forming regions host a large and evolving suite of molecular species. Molecular transition lines, particularly of complex molecules, can reveal the physical and dynamical environment of star formation. We aim to study the large-scale…

Astrophysics of Galaxies · Physics 2025-06-04 P. Freeman , S. Bottinelli , R. Plume , E. Caux , B. Mookerjea

We report the first laboratory and interstellar detection of the alpha-cyano vinyl radical (H2CCCN). This species was produced in the laboratory by an electric discharge of a gas mixture of vinyl cyanide, CH2CHCN, and Ne, and its rotational…

We report the results of subparsec-scale submillimeter observations towards an embedded high-mass young stellar object in the Small Magellanic Cloud (SMC) with ALMA. Complementary infrared data obtained with the AKARI satellite and the…

Titan's atmosphere is a natural laboratory for exploring the photochemical synthesis of organic molecules. Significant recent advances in the study of the atmosphere of Titan include: (a) detection of C$_3$ molecules: C$_3$H$_6$,…

Earth and Planetary Astrophysics · Physics 2022-07-27 Karen Willacy , SiHe Chen , Danica J. Adams , Yuk L. Yung

The recent detection of the hydrocarbon anion C6H- in the interstellar medium has led us to investigate the synthesis of hydrocarbon anions in a variety of interstellar and circumstellar environments. We find that the anion/neutral…

Astrophysics · Physics 2009-11-13 T. J. Millar , C. Walsh , M. A. Cordiner , R. Ní Chuimín , Eric Herbst

Two consecutive rotational transitions of the long cyanopolyyne HC11N, J=39-38, and J=38-37, have been detected in the cold dust cloud TMC-1 at the frequencies expected from recent laboratory measurements by Travers et al. (1996), and at…

Astrophysics · Physics 2009-10-30 M. B. Bell , P. A. Feldman , M. J. Travers , M. C. McCarthy , C. A. Gottlieb , P. Thaddeus

The studies of the complex organic molecular lines towards the hot molecular cores at millimeter and submillimeter wavelengths provide instructive knowledge about the chemical complexity in the interstellar medium (ISM). We present the…

Astrophysics of Galaxies · Physics 2023-06-01 Arijit Manna , Sabyasachi Pal

Long-chain hydrocarbon anions CnH- (n=4, 6, 8) have recently been found to be abundant in a variety of interstellar clouds. In order to explain their large abundances in the denser (prestellar/protostellar) environments, new chemical models…

Astrophysics of Galaxies · Physics 2015-06-04 M. A. Cordiner , S. B Charnley

We report the first detection in the interstellar medium of the Z-isomer of cyanomethanimine (HNCHCN), an HCN dimer proposed as precursor of adenine. We identified six transitions of Z-cyanomethanimine, along with five transitions of…

Titan harbors a dense, organic-rich atmosphere primarily composed of N$_2$ and CH$_4$, with lesser amounts of hydrocarbons and nitrogen-bearing species. As a result of high sensitivity observations by the Atacama Large…

Earth and Planetary Astrophysics · Physics 2020-11-11 A. E. Thelen , M. A. Cordiner , C. A. Nixon , V. Vuitton , Z. Kisiel , S. B. Charnley , M. Y. Palmer , N. A. Teanby , P. G. J. Irwin

We carried out line survey observations at the 26-30 GHz band toward the four high-mass star-forming regions containing hot cores, G10.30-0.15, G12.89+0.49, G16.86-2.16, and G28.28-0.36, with the Robert C. Byrd Green Bank Telescope. We have…

Quantum chemical cluster calculations show that reactions of C$^+$ with HCN or HNC embedded in the surface of an icy grain mantle can account for the formation of a recently detected molecule, glycolonitrile, which is considered to be an…

Astrophysics of Galaxies · Physics 2021-01-13 David E. Woon

The tentative detection of 3-hydroxypropanal (HO(CH$_2$)$_2$C(O)H) toward the Galactic center molecular cloud G+0.693-0.027 prompts a systematic survey in this source aimed at detecting all C$_3$H$_6$O$_2$ isomers with available…

The results of a survey of 63 galactic star-forming regions in the 6_K-5_K and 5_K-4_K methyl acetylene lines at 102 and 85 GHz, respectively, are presented. Fourty-three sources were detected at 102 GHz, and twenty-five at 85 GHz. Emission…

Astrophysics · Physics 2009-11-07 A. V. Alakoz , S. V. Kalenskii , V. G. Promislov , L. E. B. Johansson , A. Winnberg

Polycyclic aromatic hydrocarbons and polycyclic aromatic nitrogen heterocycles are thought to be widespread throughout the Universe, because these classes of molecules are probably responsible for the unidentified infrared bands, a set of…

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