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The idea that excitonic state (electronic) coherences are of fundamental importance to natural photosynthesis gained popularity when, a decade ago, slowly dephasing quantum beats were observed in the two-dimensional electronic spectra of…

During the first steps of photosynthesis, the energy of impinging solar photons is transformed into electronic excitation energy of the light-harvesting biomolecular complexes. The subsequent energy transfer to the reaction center is…

Photosynthetic antenna complexes are responsible for absorbing energy from sunlight and transmitting it to remote locations where it can be stored. Recent experiments have found that this process involves long-lived quantum coherence…

Atomic Physics · Physics 2011-08-29 Zachary B. Walters

Photosynthetic antenna complexes capture and concentrate solar radiation by transferring the excitation to the reaction center which stores energy from the photon in chemical bonds. This process occurs with near-perfect quantum efficiency.…

A remarkable amount of theoretical research has been carried out to elucidate the physical origins of the recently observed long-lived quantum coherence in the electronic energy transfer process in biological photosynthetic systems.…

Quantum Physics · Physics 2015-03-19 Sangwoo Shim , Patrick Rebentrost , Stéphanie Valleau , Alan Aspuru-Guzik

Photosynthetic light harvesting provides a natural blueprint for bioengineered and biomimetic solar energy and light detection technologies. Recent evidence suggests some individual light harvesting protein complexes (LHCs) and LHC subunits…

Biological Physics · Physics 2012-07-10 A. K. Ringsmuth , G. J. Milburn , T. M. Stace

The dynamics of coherent electron-phonon (el-ph) states is investigated for a suspended nanostructure. Exact quantum dynamics calculations reveal that electron and phonons (comprising a thermal bath) couple quantum mechanically to perform…

Quantum Physics · Physics 2007-11-13 Luis G. C. Rego

Photosynthetic antenna complexes achieve high quantum efficiency through exciton transport in coupled pigment networks. Conventional Frenkel-exciton models treat each chromophore as a structureless site and neglect internal electronic…

Optics · Physics 2026-04-01 Jingyu Liu , Tao-Yuan Du

The physical basis for observed long-lived electronic coherence in photosynthetic light-harvesting systems is identified using an analytically soluble model. Three physical features are found to be responsible for their long coherence…

Quantum Physics · Physics 2011-10-18 Leonardo A. Pachon , Paul Brumer

The striking efficiency of energy transfer in natural photosynthetic systems and the recent evidence of long-lived quantum coherence in biological light harvesting complexes has triggered much excitement, due to the evocative possibility…

Mesoscale and Nanoscale Physics · Physics 2015-10-13 Yonatan Dubi

Energy transfer within photosynthetic systems can display quantum effects such as delocalized excitonic transport. Recently, direct evidence of long-lived coherence has been experimentally demonstrated for the dynamics of the…

Quantum Physics · Physics 2008-12-06 Masoud Mohseni , Patrick Rebentrost , Seth Lloyd , Alán Aspuru-Guzik

Minimizing decoherence due to coupling of a quantum system to its fluctuating environment is at the forefront of quantum information science and photonics research. Nature sets the ultimate limit, however, given by the strength of the…

Mesoscale and Nanoscale Physics · Physics 2016-01-27 Galan Moody , Corey McDonald , Ari Feldman , Todd Harvey , Richard P. Mirin , Kevin L. Silverman

Photosynthesis is a highly efficient process, nearly 100 percent of the red photons falling on the surface of leaves reach the reaction center and get transformed into energy. Most theoretical studies on photosynthetic complexes focus…

Statistical Mechanics · Physics 2022-01-27 Naini Dudhe , Pratyush Kumar Sahoo , Colin Benjamin

The coupling between a two-level system and its environment leads to decoherence. Within the context of coherent manipulation of electronic or quasiparticle states in nanostructures, it is crucial to understand the sources of decoherence.…

Mesoscale and Nanoscale Physics · Physics 2015-05-27 P. Roulleau , S. Baer , T. Choi , F. Molitor , J. Güttinger , T. Müller , S. Dröscher , K. Ensslin , T. Ihn

A vibronic exciton model is developed to investigate the origin of long lived coherences in light-harvesting complexes. Using experimentally determined parameters and uncorrelated site energy fluctuations, the model predicts oscillations in…

Biological Physics · Physics 2012-06-07 Niklas Christensson , Harald F. Kauffmann , Tonu Pullerits , Tomas Mancal

We investigate the quantum dynamics of energy and charge transfer in a wheel-shaped artificial photosynthetic antenna-reaction center complex.This complex consists of six light-harvesting chromophores and an electron-acceptor fullerene. To…

Biological Physics · Physics 2015-05-28 Pulak Kumar Ghosh , Anatoly Yu. Smirnov , Franco Nori

Quantum coherence between electronic states of a photoionized molecule and the resulting process of ultrafast electron-hole migration have been put forward as a possible quantum mechanism of charge-directed reactivity governing the…

We present a study on the evolution of the Fenna-Matthews-Olson bacterial photosynthetic pigment-protein complex. This protein complex functions as an antenna. It transports absorbed photons - excitons - to a reaction center where…

The role of quantum coherence and the environment in the dynamics of excitation energy transfer is not fully understood. In this work, we introduce the concept of dynamical contributions of various physical processes to the energy transfer…

Quantum Physics · Physics 2009-07-18 Patrick Rebentrost , Masoud Mohseni , Alán Aspuru-Guzik

In this Article we perform a systematic study of the global entanglement and exciton coherence length dynamics coherence in natural light-harvesting system Fenna-Matthews-Olson (FMO) complex across various parameters of a dissipative…

Quantum Physics · Physics 2024-06-18 Luis E. Herrera Rodríguez , Alexei A. Kananenka
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