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Photosynthesis powers life on our planet. The basic photosynthetic architecture comprises antenna complexes to harvest solar energy and reaction centers to convert the energy into a stable charge separated state. In oxygenic photosynthesis,…

Biological Physics · Physics 2013-10-07 Franklin D. Fuller , Jie Pan , S. Seckin Senlik , Daniel E. Wilcox , Jennifer P. Ogilvie

We model energy transfer between two coupled four-level chromophores with arbitrarily spaced energy levels. Our analysis takes into account the crucial---yet often ignored---process of initial excitation by light that is incident on the…

Quantum Physics · Physics 2012-02-17 Chi-Han Chang , Agata M. Branczyk , Gregory D. Scholes , Daniel F. V. James

We study the temperature-dependent dephasing rate of excitons in chains of chromophores, accounting for scattering on static disorder as well as acoustic phonons in the host matrix. From this we find a powerlaw temperature dependence of the…

Other Condensed Matter · Physics 2007-05-23 D. J. Heijs , V. A. Malyshev , J. Knoester

The effects resulting due to dressing of an exciton with phonons are analysed as the source of unavoidable decoherence of orbital degrees of freedom in quantum dots. The dressing with longitudinal optical phonons results in energetic shift…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. Jacak , A. Janutka , J. Krasnyj , P. Machnikowski , A. Radosz

We study the effect of the exciton fine-structure splitting on the polarisation-entanglement of photon pairs produced by the biexciton cascade in a single quantum dot. The entanglement is found to persist despite separations between the…

The electronic excitation population and coherence dynamics in the chromophores of the photosynthetic light harvesting complex 2 (LH2) B850 ring from purple bacteria (Rhodopseudomonas acidophila) have been studied theoretically at both…

Chemical Physics · Physics 2012-08-29 Shu-Hao Yeh , Jing Zhu , Sabre Kais

We investigate the role of long-lasting quantum coherence in the efficiency of energy transport at room temperature in Fenna-Matthews-Olson photosynthetic complexes. The excitation energy transfer due to the coupling of the light harvesting…

Mesoscale and Nanoscale Physics · Physics 2015-03-19 G. L. Celardo , F. Borgonovi , M. Merkli , V. I. Tsifrinovich , G. P. Berman

Photoionization using attosecond pulses can lead to the formation of coherent superpositions of the electronic states of the parent ion. However, ultrafast electron ejection triggers not only electronic but also nuclear dynamics---leading…

Chemical Physics · Physics 2017-03-29 Caroline Arnold , Oriol Vendrell , Robin Santra

The present review is devoted to our recent studies on the excitonic motion in photosynthetic systems. In photosynthesis, the light photon is absorbed to create an exciton in the antenna complex of the photosynthetic pigments. This exciton…

Statistical Mechanics · Physics 2012-03-02 Navinder Singh

Due to their high energy, hot electrons in quantum Hall edge states can be considered as single particles that have the potential to be used for quantum optics-like experiments. Unlike photons, however, electrons typically undergo…

Mesoscale and Nanoscale Physics · Physics 2020-10-20 Lewis A. Clark , Masaya Kataoka , Clive Emary

Establishing the fundamental chemical principles that govern molecular electronic quantum decoherence has remained an outstanding challenge. Fundamental questions such as how solvent and intramolecular vibrations or chemical…

Chemical Physics · Physics 2024-01-03 Ignacio Gustin , Chang Woo Kim , David W. McCamant , Ignacio Franco

Long qubit coherence and efficient atom-photon coupling are essential for advanced applications in quantum communication. One technique to maintain coherence is dynamical decoupling, where a periodic sequence of refocusing pulses is…

Quantum Physics · Physics 2021-02-02 Chang Hoong Chow , Boon Long Ng , Christian Kurtsiefer

The mechanism of decoherence for a quantum system with rotational degrees of freedom is studied. From a simple model of elastic scattering, we show that the non-diagonal density matrix elements of the system exponentially decay. The decay…

Quantum Physics · Physics 2016-11-18 Changchun Zhong , F. Robicheaux

We present a detailed theoretical study of the transfer of electronic excitation energy through the Fenna-Matthews-Olson (FMO) pigment-protein complex, using the new developed modified scaled hierarchical approach [Shi Q. et al, J Chem Phys…

Chemical Physics · Physics 2011-03-17 Jing Zhu , Sabre Kais , Patrick Rebentrost , Alán Aspuru-Guzik

Light-harvesting and excitation energy transfer in photosynthesis generally involve chlorophyll-molecules, maintained by their host proteins at short distances from each other, this resulting in excitonic coupling. The transfer of…

We investigate multichromophoric energy transfer allowing for bath-induced fluctuations at different sites to be correlated. As a prototype system we consider a light-harvesting antenna surrounding a reaction center. We show that the…

Quantum Physics · Physics 2010-07-16 Francesca Fassioli , Ahsan Nazir , Alexandra Olaya-Castro

Employing instanton technique we evaluate equilibrium persistent current (PC) produced by a quantum particle moving in a periodic potential on a ring and interacting with a dissipative environment formed by diffusive electron gas. The model…

Mesoscale and Nanoscale Physics · Physics 2009-10-13 Andrew G. Semenov , Andrei D. Zaikin

Recent evidence of electronic coherence during energy transfer in photosynthetic antenna complexes has reinvigorated the discussion of whether coherence and/or entanglement has any practical functionality for these molecular systems. Here…

Quantum Physics · Physics 2015-03-13 Francesca Fassioli , Alexandra Olaya-Castro

Recently it has been discovered---contrary to expectations of physicists as well as biologists---that the energy transport during photosynthesis, from the chlorophyll pigment that captures the photon to the reaction centre where glucose is…

Quantum Physics · Physics 2015-05-27 Apoorva D. Patel

The interplay between coherence and system-environment interactions is at the basis of a wide range of phenomena, from quantum information processing to charge and energy transfer in molecular systems, biomolecules, and photochemical…

Quantum Physics · Physics 2025-11-30 Diego Fallas Padilla , Visal So , Abhishek Menon , Roman Zhuravel , Han Pu , Guido Pagano