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We present detailed calculations for the partition function and the free energy of the finite two-dimensional square lattice Ising model with periodic and antiperiodic boundary conditions, variable aspect ratio, and anisotropic couplings,…

Statistical Mechanics · Physics 2019-09-04 Hendrik Hobrecht , Alfred Hucht

Calculating free energy differences is a topic of substantial interest and has many applications including molecular docking and hydration, solvation, and binding free energies which is used in computational drug discovery. However, in…

Chemical Physics · Physics 2013-10-16 Asaf Farhi

A mixed basis approach based on density functional theory is extended to one-dimensional(1D) systems. The basis functions here are taken to be the localized B-splines for the two finite non-periodic dimensions and the plane waves for the…

Materials Science · Physics 2016-04-20 Chung-Yuan Ren , Yia-Chung Chang , Chen-Shiung Hsue

The gain of free energy upon unmixing is determined via application of Markov state modeling (MSM), using an Ising model with a fixed number of up- and down-spins. MSM yields reasonable estimates of the free energies. However, a closer look…

Computational Physics · Physics 2017-08-02 Myra Biedermann , Andreas Heuer

The free energy of the Penner model is shown to be closely related to the integral over the two diagonalizing unitary matrices of a complex rectangular matrix.

High Energy Physics - Theory · Physics 2015-06-26 M. Srednicki

We present a self-contained analysis of theories of discrete 2D gravity coupled to matter, using geometric methods to derive equations for generating functions in terms of free (noncommuting) variables. For the class of discrete gravity…

High Energy Physics - Theory · Physics 2008-11-26 Sean M. Carroll , Miguel E. Ortiz , Washington Taylor

Using the example of the two-dimensional (2D) Ising model, we show that in contrast to what can be done in configuration space, the tensor renormalization group (TRG) formulation allows one to write exact, compact, and manifestly local…

High Energy Physics - Lattice · Physics 2014-12-18 Yuzhi Liu , Y. Meurice , M. P. Qin , J. Unmuth-Yockey , T. Xiang , Z. Y. Xie , J. F. Yu , Haiyuan Zou

The site-random Ising spin glass model is investigated. We find a rigorous symmetry for the SG correlation and the free energy, which provides some restrictions in the phase diagram. Using the defect energies calculated by the numerical…

Condensed Matter · Physics 2009-10-28 Yukiyasu Ozeki , Yoshihiko Nonomura

In this paper a new approach to solving the Ising-Onsager problem in external magnetic field is investigated. The expression for free energy on one Ising spin in external field both for the twodimensional and threedimensional Ising model…

Statistical Mechanics · Physics 2007-05-23 Martin S. Kochman'ski

Using a formalism based on the spectral decomposition of the replicated transfer matrix for disordered Ising models, we obtain several results that apply both to isolated one-dimensional systems and to locally tree-like graph and factor…

Disordered Systems and Neural Networks · Physics 2014-08-04 Carlo Lucibello , Flaviano Morone , Tommaso Rizzo

We study the global influence of curvature on the free energy landscape of two-dimensional binary mixtures confined on closed surfaces. Starting from a generic effective free energy, constructed on the basis of symmetry considerations and…

Soft Condensed Matter · Physics 2019-09-11 Piermarco Fonda , Melissa Rinaldin , Daniela J. Kraft , Luca Giomi

We study the dynamics of macroscopic observables such as the magnetization and the energy per degree of freedom in Ising spin models on random graphs of finite connectivity, with random bonds and/or heterogeneous degree distributions. To do…

Disordered Systems and Neural Networks · Physics 2009-11-11 J. P. L. Hatchett , I. Pérez Castillo , A. C. C. Coolen , N. S. Skantzos

The absolute free energy -- or partition function, equivalently -- of a molecule can be estimated computationally using a suitable reference system. Here, we demonstrate a practical method for staging such calculations by growing a molecule…

Biological Physics · Physics 2009-01-31 Xin Zhang , Artem B. Mamonov , Daniel M. Zuckerman

A novel energy minimization formulation of electrostatics that allows computation of the electrostatic energy and forces to any desired accuracy in a system with arbitrary dielectric properties is presented. An integral equation for the…

Classical Physics · Physics 2009-11-13 O. I. Obolensky , T. P. Doerr , R. Ray , Yi-Kuo Yu

In this paper we present a new approach how to extract polarization-dependent exchange-correlation energy densities for two-dimensional systems from reference densities and energies of quantum dots provided by exact diagonalization.…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Andreas Wensauer , Ulrich Rössler

In this article we obtain some exact results for the 2D Ising model with a general boundary magnetic field and for a finite size system, by an alternative method to that developed by B. McCoy and T.T. Wu. This method is a generalization of…

Statistical Mechanics · Physics 2007-05-23 Maxime Clusel , Jean-Yves Fortin

This thesis is devoted to ab initio calculations of ground and excited state properties of different systems within density functional theory and time dependent density functional theory. From the numerical point of view we implemented an…

Materials Science · Physics 2012-11-28 Lucia Caramella

A mixed basis approach based on density functional theory is employed for low dimensional systems. The basis functions are taken to be plane waves for the periodic direction multiplied by B-spline polynomials in the non-periodic direction.…

Computational Physics · Physics 2015-05-20 Chung-Yuan Ren , Chen-Shiung Hsue , Yia-Chung Chang

We present an efficient algorithm for calculating the properties of Ising models in two dimensions, directly in the spin basis, without the need for mapping to fermion or dimer models. The algorithm gives numerically exact results for the…

Statistical Mechanics · Physics 2009-11-11 Y. L. Loh , E. W. Carlson

We propose an algorithm to obtain numerically approximate solutions of the direct Ising problem, that is, to compute the free energy and the equilibrium observables of spin systems with arbitrary two-spin interactions. To this purpose we…

Statistical Mechanics · Physics 2019-11-20 Simona Cocco , Giancarlo Croce , Francesco Zamponi