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Jahn-Teller (JT) electron-phonon coupling effects in the colossal magnetoresistance perovskite compounds $La_{1-x}A_xMnO_3$ are investigated. Electron-electron correlations between two degenerate Mn $e_g$ orbitals are studied in the…

Condensed Matter · Physics 2009-10-28 Jun Zang , A. R. Bishop , H. Roder

In the isostructural oxides Ca3CoMO6 (M = Co, Rh, Ir), the CoMO6 chains made up of face-sharing CoO6 trigonal prisms and MO6 octahedra are separated by Ca atoms. We analyzed the magnetic and electronic properties of these oxides on the…

Strongly Correlated Electrons · Physics 2011-01-05 Yuemei Zhang , Erjun Kan , Hongjun Xiang , Antoine Villesuzanne , Myung-Hwan Whangbo

We study an interplay between the orbital degeneracy and spin-orbit coupling giving rise to spin-orbital entangled states. As a specific example, we analyze the interaction of electrons occupying triply degenerate single-ion $t_{2g}$ levels…

Materials Science · Physics 2022-07-26 S. V. Streltsov , F. V. Temnikov , K. I. Kugel , D. I. Khomskii

Motivated by experimental and theoretical interest in realizing multipolar orders in $d$-orbital materials, we discuss the quantum magnetism of $J\!=\!2$ ions which can be realized in spin-orbit coupled oxides with $5d^2$ transition metal…

Strongly Correlated Electrons · Physics 2020-03-18 Arun Paramekanti , Dalini D. Maharaj , Bruce D. Gaulin

Ca3CoMnO6 is composed of CoMnO6 chains made up of face-sharing CoO6 trigonal prisms and MnO6 octahedra. The structural, magnetic, and ferroelectric properties of this compound were investigated on the basis of density functional theory…

Materials Science · Physics 2009-11-13 Y. Zhang , H. J. Xiang , M. -H. Whangbo

Ferroelectric control of altermagnetism in momentum space has been studied widely, while the control of magnetism in real space of altermagnets are still rare. We present a design rule to identify multiferroicity in n=2 Ruddlesden-Popper…

Materials Science · Physics 2025-08-20 Ying Zhou , Hui-Min Zhang , Cheng-Ao Ji , Hongjun Xiang , Shuai Dong , James M. Rondinelli , Xue-Zeng Lu

LaMnO$_3$ is considered as a prototypical Jahn-Teller perovskite compound, exhibiting a metal to insulator transition at $T_{JT} = 750K$ related to the joint appearance of an electronic orbital ordering and a large lattice Jahn-Teller…

Strongly Correlated Electrons · Physics 2020-07-01 Michael Marcus Schmitt , Yajun Zhang , Alain Mercy , Philippe Ghosez

In insulating lanthanides, unquenched orbital momentum and weak crystal-field (CF) splitting of the atomic $J$ multiplet at lanthanide ions result in a highly ranked (multipolar) exchange interaction between them and a complex…

Strongly Correlated Electrons · Physics 2022-04-05 Naoya Iwahara , Zhishuo Huang , Ivo Neefjes , Liviu F. Chibotaru

It is shown that the layered antiferromagnetic order in stoechiometric LaMnO_3 cannot be understood purely from electronic interactions. On the contrary, it mainly results from strong cooperative Jahn-Teller deformations. Those involve a…

Strongly Correlated Electrons · Physics 2009-10-31 M. Capone , D. Feinberg , M. Grilli

Spin-orbit coupling plays a pivotal role in condensed matter physics. For instance, spin-orbit interactions affect the magnetization and transport dynamics in solids, while spins and momenta are locked in topological matter. Alternatively,…

Strongly Correlated Electrons · Physics 2022-10-19 Alejandro S. Miñarro , Gervasi Herranz

We have analyzed the magnetic interactions of a five orbital model for iron superconductors treated both within Hartree-Fock and Heisenberg approximations. We have found that the exchange constants depend non-trivially on the Fe-As-Fe angle…

Strongly Correlated Electrons · Physics 2012-10-08 M. J. Calderon , G. Leon , B. Valenzuela , E. Bascones

The origin of the "hidden" quadrupolar and unconventional magnetic low-temperature orders observed in the spin-orbit double perovskite Ba$_2$MgReO$_6$ defies explanation through standard experimental and theoretical techniques. Here we…

Strongly Correlated Electrons · Physics 2024-11-07 Dario Fiore Mosca , Cesare Franchini , Leonid V. Pourovskii

Quantum magnets with spin $J=2$, which arise in spin-orbit coupled Mott insulators, can potentially display multipolar orders. We carry out an exact diagonalization study of a simple octahedral crystal field Hamiltonian for two electrons,…

Strongly Correlated Electrons · Physics 2020-04-17 Sreekar Voleti , Dalini D. Maharaj , Bruce D. Gaulin , Graeme Luke , Arun Paramekanti

Using DFT-based molecular dynamics simulation of Cu$^+$ cations flipping and In$^{3+}$ cations displacive dynamics, we clarify the dipole ordering of CuInP$_2$S$_6$ ferrielectrics through the second order Jahn-Teller effect which determines…

The Jahn-Teller effect refers to the symmetry-lowering geometrical distortion in a crystal (or non-linear molecule) due to the presence of a degenerate electronic state. Usually, the Jahn-Teller distortion is not polar. Recently, GaV4S8…

Materials Science · Physics 2015-10-28 Ke Xu , H. J. Xiang

We have used neutron powder diffraction to solve the magnetic structure of orthorhombic CoTi$_2$O$_5$, showing that the long-range ordered state below 26 K identified in our muon-spin rotation experiments is antiferromagnetic with…

Spin-phonon coupling and magnetodielectric effects of ZnCr2Se4 were investigated by means of infrared (IR) spectroscopy as a function of temperature and magnetic field. ZnCr2Se4 is dominated by ferromagnetic exchange but undergoes…

Strongly Correlated Electrons · Physics 2007-07-05 T. Rudolf , Ch. Kant , F. Mayr , J. Hemberger , V. Tsurkan , A. Loidl

To understand the orbital ordering of $LaMnO_3$ in the ground state, we study it in the A-type spin antiferromagnetic state. We calculate the two-dimensional response functions associated with the Jahn-Teller $Q_2$ and $Q_3$ distortions and…

Strongly Correlated Electrons · Physics 2007-05-23 Sudhakar Yarlagadda , Manidipa Mitra

We study the interplay between electron-electron interaction and a Jahn-Teller phonon coupling in a two-orbital Hubbard model. We demonstrate that the e-ph interaction coexists with the Mott localization driven by the Hubbard repulsion U,…

Strongly Correlated Electrons · Physics 2025-08-19 A. Scazzola , A. Amaricci , M. Capone

We analyze the spin-orbit and Jahn-Teller interactions in $T_d$ symmetry that are relevant for substitutional transition metal defects in semiconductors. We apply our theory to the substitutional nickel defect in diamond and compute the…

Materials Science · Physics 2023-10-16 Gergő Thiering , Adam Gali