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Graphynes are 2D porous structures deriving from graphene featuring triangular and regularly distributed subnanometer pores, which may be exploited to host small gaseous species. First principles adsorption energies of molecular hydrogen…

Chemical Physics · Physics 2015-10-06 Massimiliano Bartolomei , Estela Carmona-Novillo , Giacomo Giorgi

In this work we demonstrate the synthesis of millimetre-sized single-crystals of graphene, achievable in a commercially-available cold-wall CVD reactor, and several different approaches to transfer it from the growth substrate to a target…

Materials Science · Physics 2017-11-15 Vaidotas Miseikis , Shaohua Xiang , Stefano Roddaro , Stefan Heun , Camilla Coletti

Graphene nanoelectronics potential was limited by the lack of an intrinsic bandgap[1] and attempts to tailor a bandgap either by quantum confinement or by chemical functionalization failed to produce a semiconductor with a large enough band…

Mesoscale and Nanoscale Physics · Physics 2023-08-25 Jian Zhao , Peixun Ji , Yaqi Li , Rui Li , Kaiming Zhang , Hao Tian , Kaichen Yu , Boyue Bian , Luzhen Hao , Xue Xiao , Will Griffin , Noel Dudeck , Ramiro Moro , Lei Ma , Walt A. de Heer

Graphene has recently attracted a great deal of interest in both academia and industry because of its unique electronic and optical properties [1,2], as well as its chemical, thermal, and mechanical properties. The superb characteristics of…

Materials Science · Physics 2010-06-29 Mingsheng Xu , Daisuke Fujita , Keisuke Sagisaka , Eiichiro Watanabe , Nobutaka Hanagata

Terrace-sized, single-orientation graphene can be grown on top of a carbon buffer layer on silicon carbide by thermal decomposition. Despite its homogeneous appearance, a surprisingly large variation in electron transport properties is…

Mesoscale and Nanoscale Physics · Physics 2023-03-21 Tobias A. de Jong , Luuk Visser , Johannes Jobst , Ruud M. Tromp , Sense Jan van der Molen

Understanding interfacial interactions in two-dimensional (2D) heterostructures is essential for advancing optoelectronic and quantum technologies. We investigate metal-organic chemical vapor deposition (MOCVD)-grown WSe$_2$ films (one to…

Graphene and carbon nanotubes (CNTs) share the same atomic structure of hexagonal carbon lattice. Yet, their synthesis differs in many aspects, including the shape and size of the catalyst. Here, we demonstrate a floating-catalyst chemical…

Two-dimensional (2D) magnetic materials integrated with graphene offer a compelling platform for next-generation spintronic devices, yet nickel in its 2D form remains largely unexplored, due to fundamental synthesis limitations. Here, we…

Realization of post-CMOS graphene electronics requires production of semiconducting graphene, which has been a labor-intensive process. We present tailoring of silicon carbide crystals via conventional photolithography and microelectronics…

Materials Science · Physics 2015-05-18 M. Sprinkle , M. Ruan , X. Wu , Y. Hu , M. Rubio-Roy , J. Hankinson , N. K. Madiomanana , C. Berger , W. A. de Heer

Previous experimental observations for H intercalation under graphene on SiC surfaces motivate clarification of configuration stabilities and kinetic processes related to intercalation. From first-principles density-functional-theory (DFT)…

Mesoscale and Nanoscale Physics · Physics 2021-12-08 Yong Han , James W. Evans , Michael C. Tringides

Recently, a contamination-free dry transfer method for graphene grown by chemical vapor deposition (CVD) has been reported that allows to directly pick-up graphene from the copper growth substrate using a flake of hexagonal boron nitride…

Applied Physics · Physics 2017-07-25 Luca Banszerus , Kenji Watanabe , Takashi Taniguchi , Bernd Beschoten , Christoph Stampfer

Graphene, a flat monolayer of carbon atoms packed tightly into a two dimensional hexagonal lattice, has unusual electronic properties which have many promising nanoelectronic applications. Recent Low Energy Electron Microscopy (LEEM)…

Materials Science · Physics 2016-02-05 J H Lloyd-Williams

Remote epitaxy has garnered considerable attention as a promising method that facilitates the growth of thin films that replicate the crystallographic characteristics of a substrate by utilizing two-dimensional (2D) material interlayers…

We investigate the growth of the graphene buffer layer and the involved step bunching behavior of the silicon carbide substrate surface using atomic force microscopy. The formation of local buffer layer domains are identified to be the…

An operando investigation of graphene growth on (100) grains of polycrystalline nickel (Ni) surfaces was performed by means of variable-temperature scanning tunneling microscopy complemented by density functional theory simulations. A clear…

Chemical vapor deposition (CVD) on Cu foil is one of the most promising methods to produce graphene samples despite of introducing numerous grain boundaries into the perfect graphene lattice. A rich variety of GB structures can be realized…

Mesoscale and Nanoscale Physics · Physics 2013-10-28 Péter Vancsó , Géza I. Márk , Philippe Lambin , Alexandre Mayer , Chanyong Hwang , László P. Biró

Broadening the variety of two-dimensional (2D) materials and improving the synthesis of ultrathin films are crucial to the development of the semiconductor industry. As a state-of-the-art 2D material, Ga2Se2 has attractive optoelectronic…

Materials Science · Physics 2023-10-18 Mingyu Yu , Lottie Murray , Matthew Doty , Stephanie Law

Integrating high-mobility graphene grown by chemical vapor deposition (CVD) into spin transport devices is one of the key tasks in graphene spintronics. We use a van der Waals pickup technique to transfer CVD graphene by hexagonal boron…

Mesoscale and Nanoscale Physics · Physics 2017-10-11 Marc Drögeler , Luca Banszerus , Frank Volmer , Takashi Taniguchi , Kenji Watanabe , Bernd Beschoten , Christoph Stampfer

In view of the appreciable semiconducting gap of 0.26 eV observed in recent experiments, epitaxial graphene on a SiC substrate seems a promising channel material for FETs. Indeed, it is two-dimensional - and therefore does not require…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Martina Cheli , Paolo Michetti , Giuseppe Iannaccone

Three types of first generation epitaxial graphene field effect transistors (FET) are presented and their relative merits are discussed. Graphene is epitaxially grown on both the carbon and silicon faces of hexagonal silicon carbide and…

Materials Science · Physics 2010-05-02 Xuebin Li , Xiaosong Wu , Mike Sprinkle , Fan Ming , Ming Ruan , Yike Hu , Claire Berger , Walt A. de Heer