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Currently, Sb$_2$Se$_3$ thin films receive considerable research interest as a solar cell absorber material. When completed into a device stack, the major bottleneck for further device improvement is the open circuit voltage, which is the…

Copper indium disulfide (CuInS$_2$) grown under Cu-rich conditions exhibits high optical quality but suffers predominantly from charge carrier interface recombination resulting in poor solar cell performance. An unfavorable cliff like…

Metastable defects can decisively influence the diode factor and thus the efficiency of a solar cell. The diode factor is also influenced by the doping level and the recombination mechanisms in the solar cell. Here we quantify how the…

Applied Physics · Physics 2025-12-01 T. Wang , F. Ehre , T. P. Weiss , B. Veith-Wolf , V. Titova , N. Valle , M. Melchiorre , J. Schmidt , S. Siebentritt

Cu2ZnSnS(e)4 (CZTS(e)) solar cells have attracted much attention due to the elemental abundance and the non-toxicity. However, the record efficiency of 12.6% for Cu2ZnSn(S,Se)4 (CZTSSe) solar cells is much lower than that of Cu(In,Ga)Se2…

Applied Physics · Physics 2018-03-14 Shoushuai Gao , Zhenwu Jiang , Li Wu , Jianping Ao , Yu Zeng , Yun Sun , Yi Zhang

The presence of interface recombination in a complex multilayered thin-film solar structure causes a disparity between the internal open-circuit voltage (VOC,in), measured by photoluminescence, and the external open-circuit voltage (VOC,ex)…

Reducing the thickness of Cu(In,Ga)Se2 solar cells is a key objective in order to reduce production cost and to improve sustainability. The major challenge for sub-micron Cu(In,Ga)Se2 cells is the recombination at the backside. In standard…

Record efficiency in chalcopyrite-based solar cells Cu(In,Ga)(S,Se)2 is achieved using a gallium gradient to increase the band gap of the absorber towards the back side. Although this structure has successfully reduced recombination at the…

Organic solar cells are a promising avenue for renewable energy, and our study introduces a comprehensive model to investigate exciton dissociation processes at the donor-acceptor interface. Examining quantum efficiency and emitted phonons…

Materials Science · Physics 2025-02-05 Jouda Jemaa Khabthani , Khouloud Chika , Alexandre Perrin , Didier Mayou

There is evidence that interface recombination in Cu2ZnSnS4 solar cells contributes to the open-circuit voltage deficit. Our hybrid density functional theory calculations suggest that electron-hole recombination at the Cu2ZnSnS4/CdS…

Materials Science · Physics 2019-01-23 Ji-Sang Park , Sunghyun Kim , Samantha N. Hood , Aron Walsh

To advance knowledge of K bonding in Cu(In,Ga)(Se,S)2 (CIGS) photovoltaic (PV) absorbers, recent Cu-K-In-Se phase growth studies have been extended to PV performance. First, the effect of distributing K throughout bulk Cu1-xKxInSe2…

Mesoscale and Nanoscale Physics · Physics 2017-04-06 Christopher P. Muzzillo , Jian V. Li , Lorelle M. Mansfield , Kannan Ramanathan , Timothy J. Anderson

Traditional CdS buffer layer in selenium-free Cu(In,Ga)S2 solar cells leads to reduced open-circuit voltage because of a negative conduction band offset at the Cu(In,Ga)S2/CdS interface. Reducing this loss necessitates the substitution of…

Thin-film solar cells reach high efficiencies and have a low carbon footprint in production. Tandem solar cells have the potential to significantly increase the efficiency of this technology, where the bottom-cell is generally composed of a…

Applied Physics · Physics 2025-12-01 Thomas Paul Weiss , Mohit Sood , Aline Vanderhaegen , Susanne Siebentritt

Recent technical and commercial successes of existing thin film solar cell technologies motivates exploration of next-generation photovoltaic (PV) absorber materials. Of particular scientific interest are compounds like CuSbSe$_2$, which do…

Materials Science · Physics 2015-05-12 Adam Welch , Lauryn Baranowski , Pawel Zawadzki , Stephan Lany , Colin Wolden , Andriy Zakutayev

The ability to reduce energy loss at semiconductor surfaces through passivation or surface field engineering has become an essential step in the manufacturing of efficient photovoltaic (PV) and optoelectronic devices. Similarly, surface…

Chalcopyrite semiconductors are of considerable interest for application as absorber layers in thin-film photovoltaic cells. When growing films of these compounds, however, they are often found to contain CuAu- like domains, a metastable…

Materials Science · Physics 2017-04-05 Marnik Bercx , Nasrin Sarmadian , Rolando Saniz , Bart Partoens , Dirk Lamoen

Wide-gap Cu(In,Ga)S2 solar cells with In2O3:Sn (ITO) as transparent back contact are evaluated for the application as top cells in tandem devices. The effect of Na on the solar cell performance is investigated by supplying additional Na by…

Sulphurization processes in Cu(In,Ga)Se$_2$ thin-film solar cells has been intensively studied in the last decade as a viable alternative to the existing Ga-grading. The main advantage of using S grading is that by substituting Se with S we…

The buried interface between the electron transport layer and the perovskite layer suffers from severe interface defects and imperfect energy level alignment. To address this issue, this study employs a multifunctional organic molecule,…

Materials Science · Physics 2024-09-02 Xianhu Wu , Jieyu Bi , Guanglei Cu , Nian Liu , Gaojie Xia , Jilong Sun , Jiaxin Jiang , Ning Lu , Ping Li , Chunyi Zhao , Zewen Zuo , Min Gu

Thin-film solar cells suffer from various types of recombination, of which leakage current usually dominates at lower voltages. Herein, we demonstrate first a three-order reduction of the shunt loss mechanism in planar methylammonium lead…

Radiative and non-radiative charge carrier recombination in thin-film diodes plays a key role in determining the efficiency of electronic devices made of next generation semiconductors such as organic, perovskite and nanocrystals. In this…

Applied Physics · Physics 2019-08-06 Oskar J. Sandberg , Ardalan Armin
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