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If a binary liquid mixture, composed of two alternative species with equal amounts, is quenched from a high temperature to a low temperature, below the critical point of demixing, then the mixture will phase separate through a process known…

Statistical Mechanics · Physics 2022-02-04 Thomas J. Longo , Mikhail A. Anisimov

In numerous solution-processed thin films, a complex morphology resulting from liquid-liquid phase separation (LLPS) or from polycrystallization arises during the drying or subsequent processing steps. The morphology has a strong influence…

Applied Physics · Physics 2022-06-28 Olivier J. J. Ronsin , Jens Harting

In this paper a generalization of the Cahn-Hilliard theory of binary liquids is presented for multi-component incompressible liquid mixtures. First, a thermodynamically consistent convection-diffusion type dynamics is derived on the basis…

Materials Science · Physics 2016-02-03 Gyula I. Toth , Mojdeh Zarifi , Bjorn Kvamme

This article examines the dynamic phase transitions and pattern formations attributed to binary systems modeled by the Cahn-Hilliard equation. In particular, we consider a two-dimensional lattice structure and determine how different…

Analysis of PDEs · Mathematics 2025-11-25 Jared Grossman , Evan Halloran , Shouhong Wang

Building upon the classical chemo-mechanical theory of Larch{\'e} and Cahn for equilibrium, numerous studies have investigated the transport of species in solids, with or without trapping phenomena. In most applications -- such as the…

Soft Condensed Matter · Physics 2025-12-24 Alberto Salvadori , Mattia Serpelloni , Robert M. McMeeking

During phase transitions certain properties of a material change, such as composition field and lattice-symmetry distortions. These changes are typically coupled, and affect the microstructures that form in materials. Here, we propose a 2D…

Materials Science · Physics 2018-04-25 Ananya Renuka Balakrishna , W. Craig Carter

The Cahn-Hilliard equation is a fundamental model that describes the phase separation process in multi-component mixtures. It has been successfully extended to many different contexts in several scientific fields. In this survey article, we…

Analysis of PDEs · Mathematics 2022-06-22 Hao Wu

Recent studies on metamorphic petrology as well as microstructural observations suggest the influence of mechanical effects upon chemically active metamorphic minerals. Thus, the understanding of such a coupling is crucial to describe the…

Geophysics · Physics 2021-08-04 Santiago P. Clavijo , Luis Espath , Adel Sarmiento , Victor M. Calo

We present a multiscale theoretical framework to investigate the interplay between diffusion and finite lattice deformation in phase transformation materials. In this framework, we use the Cauchy-Born Rule and the Principle of Virtual Power…

Materials Science · Physics 2023-09-06 Tao Zhang , Delin Zhang , Ananya Renuka Balakrishna

The evolution of the microstructure due to spinodal decomposition in phase separated mixtures has a strong impact on the final material properties. In the late stage of coarsening, the system is characterized by the growth of a single…

Soft Condensed Matter · Physics 2021-12-09 Björn König , Olivier J. J. Ronsin , Jens Harting

During the intercalation of lithium in layered host materials such as graphite, lithium atoms can move within the plane between two neighboring graphene sheets, but cannot cross the sheets. Repulsive interactions between atoms in different…

Materials Science · Physics 2024-09-06 Antoine Cordoba , Marion Chandesris , Mathis Plapp

We present a phenomenological treatment of diffusion-driven martensitic phase transformations in multi-component crystalline solids that arise from non-convex free energies in mechanical and chemical variables. The treatment describes…

Chemical Physics · Physics 2016-09-29 Shiva Rudraraju , Anton Van der Ven , Krishna Garikipati

The Cahn-Hilliard equation is a fundamental model that describes phase separation processes of binary mixtures. In this paper we focus on the dynamics of these binary media, when the underlying temperature is not constant. The aim of this…

Analysis of PDEs · Mathematics 2022-10-03 Francesco De Anna , Chun Liu , Anja Schlömerkemper , Jan-Eric Sulzbach

Motivated by recent experimental and theoretical work on the control of phase separation by (electro-)autocatalytic reactions, we analyze pattern formation in externally driven phase separating systems described by a generalization of the…

Chemical Physics · Physics 2023-10-03 Hongbo Zhao , Martin Z. Bazant

In this paper we propose a mathematical model of phase separation for a quasi-incompressible binary mixture where the spinodal decomposition is induced by an heat flux governed by the Cattaneo-Maxwell equation. As usual, the phase…

Mathematical Physics · Physics 2013-06-04 A. Berti , I. Bochicchio , M. Fabrizio

The Cahn--Hilliard equation is a widely used model that describes amongst others phase separation processes of binary mixtures or two-phase flows. In the recent years, different types of boundary conditions for the Cahn--Hilliard equation…

Numerical Analysis · Mathematics 2021-03-04 Stefan Metzger

A typical phase field approach for describing phase separation and coarsening phenomena in alloys is the Cahn-Hilliard model. This model has been generalized to the so-called Cahn-Larch\'e system by combining it with elasticity to capture…

Analysis of PDEs · Mathematics 2015-02-23 Christian Heinemann , Christiane Kraus

This paper investigates a Cahn-Hilliard-Swift-Hohenberg system, focusing on a three-species chemical mixture subject to physical constraints on volume fractions. The resulting system leads to complex patterns involving a separation into…

Analysis of PDEs · Mathematics 2024-10-02 Harald Garcke , Kei Fong Lam , Robert Nürnberg , Andrea Signori

Motivated by the possibility of electrochemical control of phase separation, a variational theory of thermodynamic stability is developed for driven reactive mixtures, based on a nonlinear generalization of the Cahn-Hilliard and Allen-Cahn…

Chemical Physics · Physics 2017-11-01 Martin Z. Bazant

We investigate the Cahn-Hilliard equation with nonlinear diffusion and non-degenerate mobility modeling phase separation phenomena in complex systems (e.g., crystals and polymers). Previous results in the literature on this model relied on…

Analysis of PDEs · Mathematics 2025-10-10 Monica Conti , Stefania Gatti , Andrea Giorgini , Giulio Schimperna
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