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The Flory-Huggins theory is a well-established lattice model that is commonly used to study the mixing of distinct chemical species. It can successfully predict phase separation phenomena in blends of incompatible materials. However, it is…

Materials Science · Physics 2025-12-19 Maxime Siber , Olivier J. J. Ronsin , Jens Harting

An existence result is proved for a nonlinear diffusion problem of phase-field type, consisting of a parabolic system of two partial differential equations, complemented by Neumann homogeneous boundary conditions and initial conditions.…

Analysis of PDEs · Mathematics 2012-02-24 Pierluigi Colli , Gianni Gilardi , Paolo Podio-Guidugli , Jürgen Sprekels

New insights into phase separation in colloidal suspensions are provided via a new dynamical theory based on the Polydisperse Lattice-Gas model. The model gives a simplified description of polydisperse colloids, incorporating a hard-core…

Soft Condensed Matter · Physics 2017-08-03 Pablo de Castro , Peter Sollich

We propose and investigate a model for lipid raft formation and dynamics in biological membranes. The model describes the lipid composition of the membrane and an interaction with cholesterol. To account for cholesterol exchange between…

Analysis of PDEs · Mathematics 2016-03-15 Harald Garcke , Johannes Kampmann , Andreas Rätz , Matthias Röger

The process of phase separation of binary systems is described by the Cahn-Hilliard equation. The main objective of this article is to give a classification on the dynamic phase transitions for binary systems using either the classical…

Mathematical Physics · Physics 2009-03-12 Tian Ma , Shouhong Wang

A non-isothermal phase field model that captures both displacive and diffusive phase transformations in a unified framework is presented. The model is developed in a formal thermodynamic setting, which provides guidance on admissible…

Materials Science · Physics 2011-12-02 Mirko Maraldi , Garth N. Wells , Luisa Molari

The paper presents a versatile framework for solids which undergo nonisothermal processes with irreversibly changing microstructure at large strains. It outlines rate-type and incremental variational principles for the full thermomechanical…

Numerical Analysis · Mathematics 2022-04-12 Stephan Teichtmeister , Marc-Andre Keip

We present a phase-field model based on the Cahn-Hilliard equation to investigate the properties of phase separation in DNA nanostar systems. Leveraging a realistic free-energy functional derived from Wertheim theory, our model captures the…

Soft Condensed Matter · Physics 2025-04-23 Marco Cappa , Francesco Sciortino , Lorenzo Rovigatti

The Cahn--Hilliard equation is a fundamental model that describes phase separation processes of binary mixtures. In recent years, several types of dynamic boundary conditions have been proposed in order to account for possible short-range…

Analysis of PDEs · Mathematics 2023-07-28 Chun Liu , Hao Wu

A Cahn-Hilliard-type theory for hydrodynamic fluctuations is proposed that gives a quantitative description of the slowly evolving spatial correlations and structures in density and flow fields in the early stages of evolution of freely…

Statistical Mechanics · Physics 2009-10-31 T. P. C. van Noije , M. H. Ernst

In this work, we propose a new model for flow through deformable porous media, where the solid material has two phases with distinct material properties. The two phases of the porous material follow a Cahn-Hilliard type evolution, with…

Mathematical Physics · Physics 2021-09-09 Erlend Storvik , Jakub Wiktor Both , Jan Martin Nordbotten , Florin Adrian Radu

We propose a phase-field theory for enriched continua. To generalize classical phase-field models, we derive the phase-field gradient theory based on balances of microforces, microtorques, and mass. We focus on materials where second…

Mathematical Physics · Physics 2020-02-12 Luis Espath , Victor Calo

The phase separation between two immiscible liquids advected by a bidimensional velocity field is investigated numerically by solving the corresponding Cahn-Hilliard equation. We study how the spinodal decomposition process depends on the…

Statistical Mechanics · Physics 2009-10-31 Ludovic Berthier , Jean-Louis Barrat , Jorge Kurchan

We focus on the derivation and analysis of a model for multi-component phase separation occurring on biological membranes, inspired by observations of lipid raft formation. The model integrates local membrane composition with local membrane…

Analysis of PDEs · Mathematics 2025-07-08 Diogo Caetano , Charles M. Elliott , Maurizio Grasselli , Andrea Poiatti

In order to find a measure of the dynamical features of phase separation kinetics during spinodal decomposition of a liquid binary mixture (like water and cyclohexane , water and 2,6 lutidiene or methanol and cyclohexane), we study both the…

Soft Condensed Matter · Physics 2016-04-21 Milan K. Hazra , Sarmistha Sarkar , Biman Bagchi

In this paper general dynamic equations describing the time evolution of isothermal quasi-incompressible multicomponent liquids are derived in the framework of the classical Ginzburg-Landau theory of first order phase transformations. Based…

Soft Condensed Matter · Physics 2016-09-28 Gyula I. Toth

We study a diffuse-interface model for thermally driven phase separation in viscous incompressible mixtures. The system couples a convective Cahn-Hilliard equation for the order parameter with a Stokes subsystem for the velocity-pressure…

Analysis of PDEs · Mathematics 2026-04-24 Maria Deliyianni , Boris Muha , Andrej Novak

In this paper we present a mathematical model to describe the phenomenon of phase separation, which is modelled as space regions where an order parameter changes smoothly. The model proposed, including thermal and mixing effects, is deduced…

Mathematical Physics · Physics 2011-02-08 Alessia Berti , Ivana Bochicchio

This Article presents a nonequilibrium thermodynamic theory for the mean-field precipitation, aggregation and pattern formation of colloidal clusters. A variable gradient energy coefficient and the arrest of particle diffusion upon…

Soft Condensed Matter · Physics 2018-10-17 Thomas Petersen , Martin Z. Bazant , Roland J. M. Pellenq , Franz-Josef Ulm

We study a Cahn-Hilliard model for phase separation in composite materials with multiple periodic microstructures. These are modeled by considering a highly oscillating potential. The focus of this paper is in the case where the scales of…

Analysis of PDEs · Mathematics 2026-02-16 Riccardo Cristoferi , Luca Pignatelli