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Room temperature ionic liquids are attractive to numerous applications and particularly, to renewable energy devices. As solvent free electrolytes, they demonstrate a paramount connection between the material morphology and Coulombic…

Chemical Physics · Physics 2016-03-15 Nir Gavish , Arik Yochelis

It is believed at present that the chiral transition changes from a smooth crossover to a first-order transition at low temperatures and high densities. Such regime is commonly analyzed using effective models since first principle…

Nuclear Theory · Physics 2025-11-20 R. M. Aguirre

We formulate a continuum electro-chemo-mechanical gradient theory which couples electrochemical reactions with mechanical deformation and damage in solids. The framework models species transport across the host due to diffusion/migration…

Materials Science · Physics 2023-04-05 Donald Bistri , Claudio V. Di Leo

We present a phase field-based electro-chemo-mechanical formulation for modelling mechanics-enhanced corrosion and hydrogen-assisted cracking in elastic-plastic solids. A multi-phase-field approach is used to present, for the first time, a…

Materials Science · Physics 2022-06-22 C. Cui , R. Ma , E. Martínez-Pañeda

The Cahn--Hilliard equation is one of the most common models to describe phase separation processes of a mixture of two materials. For a better description of short-range interactions between the material and the boundary, various dynamic…

Analysis of PDEs · Mathematics 2021-04-27 Patrik Knopf , Kei Fong Lam , Chun Liu , Stefan Metzger

Differences in activities in colloidal particles are sufficient to drive phase separation between active and passive (or less active) particles, even if they have only excluded volume interactions. In this paper, we study the phase…

Soft Condensed Matter · Physics 2020-05-27 Efe Ilker , Jean-François Joanny

Modeling microstructure evolution in electrochemical systems is vital for understanding the mechanism of various electrochemical processes. In this work, we propose a general phase field framework that is fully variational and thus…

Materials Science · Physics 2023-12-12 Jin Zhang , Alexander F. Chadwick , Peter W. Voorhees

An electric-field-induced phase transition and pattern formation in a binary dielectric fluid layer are studied using a coarse-grained free energy functional. The electrostatic part of the free energy is a nonlinear functional of the…

Soft Condensed Matter · Physics 2007-05-23 M. D. Johnson , X. Duan , Brett Riley , Aniket Bhattacharya , Weili Luo

In the present work, we address a class of Cahn-Hilliard equations characterized by a nonlinear diffusive dynamics and possibly containing an additional sixth order term. This model describes the separation properties of oil-water mixtures,…

Analysis of PDEs · Mathematics 2012-06-26 Giulio Schimperna , Irena Pawlow

The mathematical analysis of diffuse-interface models for multiphase flows has attracted significant attention due to their ability to capture complex interfacial dynamics, including curvature effects, within a unified, energetically…

Analysis of PDEs · Mathematics 2025-09-25 Pierluigi Colli , Gianni Gilardi , Andrea Signori , Jürgen Sprekels

We study dynamic heterogeneities in a model glass-former whose overlap with a reference configuration is constrained to a fixed value. The system phase-separates into regions of small and large overlap, so that dynamical correlations remain…

Disordered Systems and Neural Networks · Physics 2012-07-19 C. Cammarota , A. Cavagna , I. Giardina , G. Gradenigo , T. S. Grigera , G. Parisi , P. Verrocchio

The phase behavior is investigated for systems composed of a large number of macromolecular components N, with N greater or equal to 2. Liquid-liquid phase separation is modelled using a virial expansion up to the second order of the…

Soft Condensed Matter · Physics 2024-05-29 Arjen Bot , Erik van der Linden , Paul Venema

The Cahn-Hilliard system has been used to describe a wide number of phase separation processes, from co-polymer systems to lipid membranes. In this work the convergence properties of a closest-point based scheme is investigated. In place of…

Numerical Analysis · Mathematics 2017-02-28 Prerna Gera , David Salac

Phase transition kinetics of aqueous hydroxypropyl cellulose solution was studied by using turbidimetric monitoring and mathematical modelling techniques. Based on the nonlinear Cahn-Hilliard equation with a mobility depending on the…

Soft Condensed Matter · Physics 2021-12-21 V. I. Kovalchuk

A thermodynamically consistent framework able to model either diffusive and displacive phase transitions is proposed. The first law of thermodynamics, the balance of linear momentum equation and the Cahn-Hilliard equation for solute mass…

Materials Science · Physics 2015-03-17 Mirko Maraldi , Luisa Molari , Diego Grandi

In this paper, we derive the time-fractional Cahn-Hilliard equation from continuum mixture theory with a modification of Fick's law of diffusion. This model describes the process of phase separation with nonlocal memory effects. We analyze…

Analysis of PDEs · Mathematics 2022-10-10 Marvin Fritz , Mabel L. Rajendran , Barbara Wohlmuth

We study the long-time dynamics of a bulk-surface convective Cahn--Hilliard system describing phase separation processes with bulk-surface interaction. The presence of convection terms leads to a non-autonomous dynamical system and prevents…

Analysis of PDEs · Mathematics 2026-03-12 Patrik Knopf , Andrea Poiatti , Jonas Stange , Sema Yayla

Biomembranes and vesicles consisting of multiple phases can attain a multitude of shapes, undergoing complex shape transitions. We study a Cahn--Hilliard model on an evolving hypersurface coupled to Navier--Stokes equations on the surface…

Numerical Analysis · Mathematics 2019-11-01 John W. Barrett , Harald Garcke , Robert Nürnberg

Phase field theory for fracture is developed at large strains with an emphasis on a correct introduction of surface stresses. This is achieved by multiplying the cohesion and gradient energies by the local ratio of the crack surface areas…

Applied Physics · Physics 2020-11-30 Hossein Jafarzadeh , Gholam Hossein Farrahi , Valery I. Levitas , Mahdi Javanbakht

The stability of organic solar cells is strongly affected by the morphology of the photoactive layers, whose separated crystalline and/or amorphous phases are kinetically quenched far from their thermodynamic equilibrium during the…

Materials Science · Physics 2020-03-31 Olivier J. J. Ronsin , Jens Harting