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This article investigates entanglement of the motional states of massive coupled oscillators. The specific realization of an idealized diatomic molecule in one-dimension is considered, but the techniques developed apply to any massive…

Quantum Physics · Physics 2015-03-13 N. L. Harshman , W. F. Flynn

We study a LiCs strongly-interacting molecular gas loaded into an one-dimensional optical lattice at quarter filling. The molecules are in the lowest electronic and vibrational state, $X^{1}\Sigma$ ($\nu=0$). Due to the large intermolecular…

Quantum Gases · Physics 2017-03-28 Vanessa Olaya-Agudelo , Karen Rodriguez

We propose an alternative scenario for the generation of entanglement between rotational quantum states of two polar molecules. This entanglement arises from dipole-dipole interaction, and is controlled by a sequence of laser pulses…

Quantum Physics · Physics 2016-08-16 Eric Charron , Pérola Milman , Arne Keller , Osman Atabek

A rigorous quantum description of molecular dynamics with a particular emphasis on internal observables is developed accounting explicitly for kinetic couplings between nuclei and electrons. Rotational modes are treated in a genuinely…

Chemical Physics · Physics 2015-07-07 Sylvain D. Brechet , Francois A. Reuse , Klaus Maschke , Jean-Philippe Ansermet

We investigate the interaction between light and molecular systems modeled as quantum emitters coupled to a multitude of vibrational modes via a Holstein-type interaction. We follow a quantum Langevin equations approach that allows for…

Quantum Physics · Physics 2020-04-27 Michael Reitz , Christian Sommer , Claudiu Genes

Relying on the quantization rule of Raab and Friedrich [Phys. Rev. A (2009) in press], we derive simple and accurate formulae for the number of rotational states supported by a weakly bound vibrational level of a diatomic molecular ion. We…

Atomic Physics · Physics 2010-04-02 Mikhail Lemeshko , Bretislav Friedrich

The calculation of the hindered roton-phonon energy levels of a hydrogen molecule in a confining potential with different symmetries is systematized for the case when the rotational angular momentum $J$ is a good quantum number. One goal of…

Condensed Matter · Physics 2009-11-07 T. Yildirim , A. B. Harris

Light is the fundamental medium through which we perceive the world around us. In the modern era, light can not only be used in its raw form but can also be used as a versatile tool. Generally, light fields carry energy and momentum (both…

Optics · Physics 2025-12-18 Bikash K. Das , Camilo Granados , Marcelo F. Ciappina

Following the very recent experimental realisation of electron vortices, we consider their interaction with matter, in particular the transfer of orbital angular momentum in the context of electron energy loss spectroscopy, and the recently…

Quantum Physics · Physics 2015-06-03 Sophia Lloyd , Mohamed Babiker , Jun Yuan

While linear molecules in their vibrational ground state cannot carry angular momentum around their symmetry axis, the presence of vibrational excitations can induce deformations away from linearity and therefore also allow angular momentum…

Atomic and Molecular Clusters · Physics 2021-03-17 Klavs Hansen , Piero Ferrari

Coupling between molecules and vacuum photon fields inside an optical cavity has proven to be an effective way to engineer molecular properties, in particular reactivity. To ease the rationalization of cavity induced effects we introduce an…

Chemical Physics · Physics 2022-04-06 Rosario R. Riso , Tor S. Haugland , Enrico Ronca , Henrik Koch

Intermolecular van der Waals interactions are central to chemical and physical phenomena ranging from biomolecule binding to soft-matter phase transitions. However, there are currently very limited approaches to manipulate van der Waals…

We present a theoretical study of the impact of an electric field combined with a magnetic field on the rotational dynamics of open shell diatomic molecules. Within the rigid rotor approximation, we solve the time-independent Schr\"odinger…

Chemical Physics · Physics 2015-06-12 Martin Gärttner , Juan J. Omiste , Peter Schmelcher , Rosario González-Férez

We predict that it is possible to cool rotational, vibrational and translational degrees of freedom of molecules by coupling a molecular dipole transition to an optical cavity. The dynamics is numerically simulated for a realistic set of…

Quantum Physics · Physics 2007-08-13 Giovanna Morigi , Pepijn W. H. Pinkse , Markus Kowalewski , Regina de Vivie-Riedle

Whereas collisions between atoms and molecules are largely understood, collisions between two molecules have proven much harder to study. In both experiment and theory, our ability to determine quantum state-resolved bimolecular cross…

We explore the electronic structure and rovibrational properties of an ultralong-range triatomic Rydberg molecule formed by a Rydberg atom and a ground state heteronuclear diatomic molecule. We focus here on interaction of Rb($27s$) Rydberg…

Atomic Physics · Physics 2015-06-22 Rosario González-Férez , H. R. Sadeghpour , Peter Schmelcher

We present an extension of the Hamiltonian of the two dimensional limit of the vibron model encompassing all possible interactions up to four-body operators. We apply this Hamiltonian to the modeling of the experimental bending spectrum of…

Chemical Physics · Physics 2021-03-17 Jamil Khalouf-Rivera , Francisco Pérez-Bernal , Miguel Carvajal

We study here fractional orbital angular momentum (OAM) states in electron vortex beams (EVB) from the perspective of geometric phase. We have considered the skyrmionic model of an electron, where it is depicted as a scalar electron…

Mesoscale and Nanoscale Physics · Physics 2017-01-18 Pratul Bandyopadhyay , Banasri Basu , Debashree Chowdhury

The charge transfer reaction Ar+ + N2 --> Ar + N2+ has been investigated in a crossed beam experiment in combination with three-dimensional velocity map imaging. Angular differential state-to-state cross sections were determined as a…

Chemical Physics · Physics 2015-06-12 S. Trippel , M. Stei , J. A. Cox , R. Wester

We study the ground state phases of a rotating two-component, or binary Bose-Einstein condensate, wherein one component possesses a large magnetic dipole moment. A variety of non-trivial phases emerge in this system, including a…

Quantum Gases · Physics 2014-10-22 Wilbur E. Shirley , Brandon M. Anderson , Charles W. Clark , Ryan M. Wilson