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Lithium-sulfur (Li-S) batteries have become one of the most attractive alternatives over conventional Li-ion batteries due to their high theoretical specific energy density (2500 Wh/kg for Li-S vs. $\sim$250 Wh/kg for Li-ion). Accurate…

Systems and Control · Electrical Eng. & Systems 2021-09-21 Zhijia Huang , Dong Zhang , Luis D. Couto , Quan-Hong Yang , Scott J. Moura

Achieving Li-S batteries' promise of significantly higher gravimetric energy density and lower cost than Li-ion batteries requires researchers to delineate the most important factors affecting the performance of this technology. By encoding…

Chemical Physics · Physics 2021-12-17 Michael Cornish , Monica Marinescu

This article examines the problem of Lithium-Sulfur (Li-S) battery state estimation. Such estimation is important for the online management of this energy-dense chemistry. The literature uses equivalent circuit models (ECMs) for Li-S state…

Systems and Control · Electrical Eng. & Systems 2021-02-17 Chu Xu , Timothy Cleary , Daiwei Wang , Guoxing Li , Christopher Rahn , Donghai Wang , Rajesh Rajamani , Hosam K. Fathy

Lithium-sulfur (Li-S) batteries offer a promising alternative to current lithium-ion (Li-ion) batteries, with a high theoretical energy density, improved safety and high abundance, low cost of materials. For Li-S to reach commercial…

Materials Science · Physics 2025-03-12 Miss. Elizabeth Olisa Monica Marinescu

Lithium-ion battery (LIB) sources have played an essential role in self-sustained transportation energy systems and have been widely deployed in the last few years. To realize reliable battery maintenance, identifying its electrochemical…

Systems and Control · Electrical Eng. & Systems 2023-03-15 Yuxuan Gu , Jianxiao Wang , Yuanbo Chen , Kedi Zheng , Zhongwei Deng , Qixin Chen

In this work we analyse the local nonlinear electrochemical impedance spectroscopy (NLEIS) response of a lithium-ion battery and estimate model parameters from measured NLEIS data. The analysis assumes a single-particle model including…

Chemical Physics · Physics 2023-04-24 T. L. Kirk , A. Lewis-Douglas , D. A. Howey , C. P. Please , S. J. Chapman

Physics-based electrochemical battery models derived from porous electrode theory are a very powerful tool for understanding lithium-ion batteries, as well as for improving their design and management. Different model fidelity, and thus…

The performance of modern lithium-sulfur (Li/S) battery systems critically depends on the electrolyte and solvent compositions. For fundamental molecular insights and rational guidance of experimental developments, efficient and…

Growing demand for fast charging and optimised battery designs is fuelling significant interest in electrochemical models of Li-ion batteries. However, estimating parameter values for these models remains a major challenge. In this paper, a…

Systems and Control · Electrical Eng. & Systems 2020-12-04 Ross Drummond , Stephen R. Duncan

Renewable energy researchers use computer simulation to aid the design of lithium ion storage devices. The underlying models contain several physical input parameters that affect model predictions. Effective design and analysis must…

Computational Physics · Physics 2017-03-03 Paul G. Constantine , Alireza Doostan

All solid state batteries are claimed to be the next-generation battery system, in view of their safety accompanied by high energy densities. A new advanced, multiscale compatible, and fully three dimensional model for solid electrolytes is…

Applied Physics · Physics 2022-03-15 L. Cabras , D. Danilov , W. Subber , V. Oancea , A. Salvadori

Simulation models are nowadays indispensable to efficiently assess or optimize novel battery cell concepts during the development process. Electro-chemo-mechano models are widely used to investigate solid-state batteries during cycling and…

Materials Science · Physics 2024-08-13 Stephan Sinzig , Christoph P. Schmidt , Wolfgang A. Wall

This study examines the discharge behaviour of a cylindrical LiFeS2 cell to evaluate the parameters that can be used to predict and estimate the nonlinear dynamic response of a battery. A linear model is developed to simulate the discharge…

Systems and Control · Electrical Eng. & Systems 2023-11-07 Khaled I Alsharif , Alexander H Pesch , Vamsi Borra , Pedro Cortes , Eric MacDonald , Frank X Li , Kyosung Choo

This paper investigates the identifiability and estimation of the parameters of the single particle model (SPM) for lithium-ion battery simulation. Identifiability is addressed both in principle and in practice. The approach begins by…

Systems and Control · Computer Science 2018-10-03 Adrien M. Bizeray , Jin-Ho Kim , Stephen R. Duncan , David A. Howey

The reliability and safety of Lithium-ion batteries (LiBs) are of great concern in the energy storage industry. Nevertheless, the real-time monitoring of their degradation remains challenging due to limited quantitative metrics available…

Lithium-ion batteries (LIBs) have found wide applications in a variety of fields such as electrified transportation, stationary storage and portable electronics devices. A battery management system (BMS) is critical to ensure the…

Systems and Control · Electrical Eng. & Systems 2024-02-02 Yiming Xu , Xiaohua Ge , Ruohan Guo , Weixiang Shen

We demonstrate that for polycrystalline LiNi0.33Mn0.33Co0.33O2 c-axis textured thin film cathodes of rechargeable lithium-ion batteries, the kinetics of Li storage and release including maximum specific capacity is determined by Li…

Materials Science · Physics 2025-09-11 Erwin Hüger , Harald Schmidt

This study presents a comprehensive Multiphysics model for zinc-ion batteries (ZIBs), incorporating electrochemical aspects. The model integrates the mass transport of Zn2+ ions, charge transfer, and solid diffusion to predict performance…

Materials Science · Physics 2025-05-06 Roya Rajabi , Shichen Sun , Booker Wu , Jamil Khan , Kevin Huang

This paper presents the current state of mathematical modelling of the electrochemical behaviour of lithium-ion batteries as they are charged and discharged. It reviews the models developed by Newman and co-workers, both in the cases of…

Chemical Physics · Physics 2020-02-04 Giles W Richardson , Jamie M Foster , Rahifa Ranom , Colin P Please , Angel M Ramos

Lithium-bismuth bimetallic cells are amongst the best explored liquid metal batteries. A simple and fast quasi-one-dimensional cell voltage model for such devices is presented. The equilibrium cell potential is obtained from a complex…

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