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In the present study, a new set of dimensionless coefficients is introduced through non-dimensionalization of electrochemical equations of lead-acid batteries. Non-dimensionalization process has been applied to the electrochemical governing…

Chemical Physics · Physics 2019-02-13 Tayyeb Nazghelichi , Farschad Torabi , Vahid Esfahanian

Batteries are pivotal components in overcoming some of today's greatest technological challenges. Yet to date there is no self-consistent atomistic description of a complete battery. We take first steps toward modeling of a battery as a…

Materials Science · Physics 2013-08-16 Wolf B. Dapp , Martin H. Müser

Batteries are nonlinear dynamical systems that can be modeled by Porous Electrode Theory models. The aim of optimal fast charging is to reduce the charging time while keeping battery degradation low. Most past studies assume that model…

Systems and Control · Electrical Eng. & Systems 2024-10-14 Minsu Kim , Joachim Schaeffer , Marc D. Berliner , Berta Pedret Sagnier , Rolf Findeisen , Richard D. Braatz

This contribution presents a diagnosis scheme for batteries to detect and isolate internal faults in the form of small parameter changes. This scheme is based on an electrochemical reduced-order model of the battery, which allows the…

Systems and Control · Electrical Eng. & Systems 2021-03-19 Luis D. Couto , Jorn M. Reniers , David A. Howey , Michel Kinnaert

Solid-state electrolyte batteries are expected to replace liquid electrolyte lithium-ion batteries in the near future thanks to their higher theoretical energy density and improved safety. However, their adoption is currently hindered by…

Management of heat during charging and discharging of Li-ion batteries is critical for their safety, reliability, and performance. Understanding the thermal conductivity of the materials comprising batteries is crucial for controlling the…

Materials Science · Physics 2021-03-17 Zhe Cheng , Beniamin Zahiri , Xiaoyang Ji , Chen Chen , Darshan Chalise , Paul V. Braun , David G. Cahill

Reliable health assessment of retired lithium-ion batteries is essential for safe and economically viable second-life deployment, yet remains difficult due to sparse measurements, incomplete historical records, heterogeneous chemistries,…

Signal Processing · Electrical Eng. & Systems 2025-12-02 Song Zhang , Ruohan Guo , Xiaohua Ge , Perter Mahon , Weixiang Shen

Modeling of Li-ion cells is used in battery management systems (BMS) to determine key states such as state-of-charge (SoC), state-of-health (SoH), etc. Accurate models are also useful in developing a cell-level digital-twin that can be used…

Systems and Control · Electrical Eng. & Systems 2024-05-27 Abhijit Kulkarni , Ahsan Nadeem , Roberta Di Fonso , Yusheng Zheng , Remus Teodorescu

The reversible heat in lithium-ion batteries (LIBs) due to entropy change is fundamentally important for understanding the chemical reactions in LIBs and developing proper thermal management strategies. However, the direct measurements of…

Applied Physics · Physics 2021-07-02 Zhe Cheng , Xiaoyang Ji , David G. Cahill

Redox flow batteries (RFBs) offer the capability to store large amounts of energy cheaply and efficiently, however, there is a need for fast and accurate models of the charge-discharge curve of a RFB to potentially improve the battery…

Chemical Physics · Physics 2021-06-18 Amanda A. Howard , Alexandre M. Tartakovsky

The lithium bis(trifluoromethylsulfonyl)azanide-triglyme electrolyte plays a critical role in the performance of lithium-ion batteries. However, its solvation structure and transport properties at the atomic scale remain incompletely…

Materials Science · Physics 2025-04-01 Chenyang Cao , Liyi Bai , Shuo Cao , Ye Su , Yanzhou Wang , Zheyong Fan , Ping Qian

Electrochemical Impedance Spectroscopy (EIS) is a non-invasive technique widely used for understanding charge transfer and charge transport processes in electrochemical systems and devices. Standard approaches for the interpretation of EIS…

The physics-based Doyle-Fuller-Newman (DFN) model, widely adopted for its precise electrochemical modeling, stands out among various simulation models of lithium-ion batteries (LIBs). Although the DFN model is powerful in forward predictive…

Computational Engineering, Finance, and Science · Computer Science 2025-04-30 Weipeng Xu , Kaiqi Yang , Yuzhi Zhang , Shichao Sun , Sheng Mao , Tianju Xue

This work demonstrates the potential of fiber optic sensors for measuring thermal effects in lithium-ion batteries, using a fiber optic measurement method of Optical Frequency Domain Reflectometry (OFDR). The innovative application of fiber…

Renewable energy is critical for combating climate change, whose first step is the storage of electricity generated from renewable energy sources. Li-ion batteries are a popular kind of storage units. Their continuous usage through…

Methodology · Statistics 2024-11-05 Youngjin Cho , Quyen Do , Pang Du , Yili Hong

We have demonstrated a fiber lithium ion battery (LIB) fabricated by co-twisting a LiFePO4 composite-coated copper wire (cathode) together with an aluminum wire (anode). An all-solid LiPF6 composite layer functioning both as the electrolyte…

Applied Physics · Physics 2019-03-20 H. Qu , X. Lu , M. Skorobogatiy

This paper presents findings on dynamic cell modeling for state-of-charge (SOC) estimation in an autonomous electric vehicle (AEV). The studied cells are Lithium-Ion Polymer-based with a nominal capacity of around 8Ah, optimized for…

Systems and Control · Electrical Eng. & Systems 2023-06-21 Qasim Ajao , Lanre Sadeeq

Lithium (Li) plating on graphite is a significant degradation mechanism in Li-ion batteries. While numerous experimental techniques have been used to study Li plating in laboratory cells, investigations of commercial high-energy cells often…

An extensive search for low-energy lithium defects in crystalline silicon using density-functional-theory methods and the ab initio random structure searching (AIRSS) method shows that the four-lithium-atom substitutional point defect is…

Materials Science · Physics 2013-05-28 Andrew J. Morris , R. J. Needs , Elodie Salager , C. P. Grey , Chris J. Pickard

Non-destructive characterization of lithium-ion batteries provides critical insights for optimizing performance and lifespan while preserving structural integrity. Optimizing electrolyte design in commercial LIBs requires consideration of…

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