English

Towards Rigorous Validation of Li-S Battery Models

Chemical Physics 2021-12-17 v1

Abstract

Achieving Li-S batteries' promise of significantly higher gravimetric energy density and lower cost than Li-ion batteries requires researchers to delineate the most important factors affecting the performance of this technology. By encoding this knowledge into a mathematical model, understanding is made precise, quantitative, and predictive. However, the complex and unknown mechanisms of Li-S batteries have multiple proposed models with relatively few informative quantitative comparisons to experimental data. Consequently, a minimum set of testing procedures for model validation is proposed. Moreover, in the absence of an accepted standard model, a zero dimensional model is proposed in this work. The model improves upon several existing models while remaining as simple as possible. The model is quantitatively predictive, as demonstrated by out-of-sample predictions of experimental discharge resistance. Finally, this model and others have been implemented using PyBaMM. Therefore, the open access code allows rapid modifications of this model by all researchers.

Keywords

Cite

@article{arxiv.2112.08722,
  title  = {Towards Rigorous Validation of Li-S Battery Models},
  author = {Michael Cornish and Monica Marinescu},
  journal= {arXiv preprint arXiv:2112.08722},
  year   = {2021}
}

Comments

15 pages, 10 figures, 2 tables

R2 v1 2026-06-24T08:19:57.787Z