Related papers: Zeptosecond Birth Time Delay in Molecular Photoion…
The picosecond geminate recombination kinetics for hydrated electrons generated by 200 nm two photon absorption (12.4 eV total energy) has been measured in both light and heavy water. The geminate kinetics are observed to be almost…
In a recent paper [Phys. Rev. Lett. 125, 043201 (2020)] (Ref.1) Liao et al. propose a theory of the interferometric photoemission delay based on the concepts of the photoelectron phase and photoelectron effective mass. The present comment…
Recent angle-resolved RABBITT experiments have shown that the photoionization time delay depends on the emission angle of the photoelectron. In this work we demonstrate that for photoemission from helium accompanied by shake-up (correlation…
Photoionization is a key step in many attosecond processes. Accurately determining the photoionization time delay is critical to understanding electron dynamics during and after ionization and can guide future efforts to manipulate electron…
Tunnelling lies at the heart of quantum mechanics and is a fundamental process in attosecond science, molecular biology, and quantum devices. Whether tunnelling takes time and how a microscopic particle transits through a barrier have been…
Attosecond photoionization delays have mostly been interpreted within the single-particle approximation of multi-electron systems. The strong electron correlation between the photoionization channels associated with the 3p and 3s orbitals…
Photoionization of an atom $A$, in the presence of a neighboring atom $B$, can proceed via resonant excitation of $B$ with subsequent energy transfer to $A$ through two-center electron-electron correlation. We demonstrate that this…
We use the non-relativistic random phase approximation with exchange to perform calculations of valence shell photoionization of Ne, Ar, Kr and Xe from their respective thresholds to photon energy of 200 eV. The energy derivative of the…
Photoionization and its inverse, electron-ion recombination, are key processes that influence many astrophysical plasmas (and gasses), and the diagnostics that we use to analyse the plasmas. In this review we provide a brief overview of the…
We investigate the attosecond response of the electronic cloud of a molecular system to an outer-valence ionization. The time needed for the remaining electrons to respond to a sudden perturbation in the electronic structure of the molecule…
The photoionization of xenon atoms in the 70-100 eV range reveals several fascinating physical phenomena such as a giant resonance induced by the dynamic rearrangement of the electron cloud after photon absorption, an anomalous branching…
We consider photo ionization of an atom which, due to passing through a diffraction grating, is prepared in a multi-site state possessing a periodic space structure with alternating maxima and minima. It has been found that this process…
Photoelectron spectroscopy is a powerful method that provides insight into the quantum mechanical properties of a wide range of systems. The ionized electron wavefunction carries information on the structure of the bound orbital, the ionic…
We numerically investigate attosecond streaking time delays in the photoemission of valence and 2p core electrons of aluminum surface. We find that electron emission from the core level band is delayed by $\Delta \tau =100$ attoseconds…
We discuss the photon emission that occurs due to the radiative recombination of an electron on a nearby center after tunneling ionization. The model of an active electron is used, and analytical solution to three-dimensional problem is…
Excitonic transport in photosynthesis exhibits a wide range of time scales. Absorption and initial relaxation takes place over tens of femtoseconds. Excitonic lifetimes are on the order of a nanosecond. Hopping rates, energy differences…
Nuclear orbiting resonances have been revealed at the sub-barrier energies as an atomic phenomenon by means of x-ray spectroscopy experiments. This interpretation is supported by several phenomenological models and theoretical estimates of…
We theoretically study time-resolved photoemission in atoms as probed by attosecond streaking. We review recent advances in the study of the photoelectric effect in the time domain and show that the experimentally accessible time shifts can…
The initial insight into time delay in Mn photoionization in the region of the $3p \to 3d$ giant autoionization resonance is gained in the framework of the "spin-polarized" random phase approximation with exchange. The dramatic effect of…
A methodology is developed to compute photoionization cross-sections beyond the electric dipole (BED) approximation from response theory, using Gaussian type orbitals and plane waves for the initial and final states, respectively. The…