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Measuring the time it takes to remove an electron from an atom or molecule during photoionization using newly developed attosecond spectroscopies has been a focus of many recent experiments. However, the outcome of such measurement depends…

Atomic Physics · Physics 2017-03-08 Lisa Torlina , Olga Smirnova

We consider the time delay of electron detachment from a Coulomb center and two-center systems in the process of ionization. It is shown that the attosecond streaking, most usual method of time delay measure, can be formally described by…

Atomic Physics · Physics 2015-06-15 Vladislav V. Serov , Vladimir L. Derbov , Tatyana A. Sergeeva

We present a combined theoretical and experimental work investigating the angle-resolved phases of the photoionization process driven by a two-color field consisting of an attosecond pulse train and an infrared pulse in an ensemble of…

Electronic processes within atoms and molecules reside on the timescale of attoseconds. Recent advances in the laser-based pump-probe interrogation techniques have made possible the temporal resolution of ultrafast electronic processes on…

Atomic Physics · Physics 2024-02-16 Yongzhe Ma , Hongcheng Ni , Jian Wu

Using a spectrally resolved electron interferometry technique, we measure photoionization time delays between the $3s$ and $3p$ subshells of argon over a large 34-eV energy range covering the Cooper minima in both subshells. The observed…

We have performed calculations of attosecond laser-atom interactions for laser intensities where interesting two and three photon effects become relevant. In particular, we examine the case of "hole burning" in the initial orbital. Hole…

Atomic Physics · Physics 2014-06-02 P. L. Price , L. D. Noordam , H. B. van Linden van den Heuvell , F. Robicheaux

Photoionization using attosecond pulses can lead to the formation of coherent superpositions of the electronic states of the parent ion. However, ultrafast electron ejection triggers not only electronic but also nuclear dynamics---leading…

Chemical Physics · Physics 2017-03-29 Caroline Arnold , Oriol Vendrell , Robin Santra

We present analytical expressions of momentum-resolved core-level photoemission time delay in a molecular frame of a heteronuclear diatomic molecule upon photoionization by a linearly polarized soft x-rays attosecond pulse. For this…

Chemical Physics · Physics 2022-05-31 Y. Tamura , K. Yamazaki , K. Ueda , K. Hatada

We investigate theoretically the relative time delay of photoelectrons originating from the different subshells (2s and 2p) of neon. This quantity was measured via attosecond streaking and studied theoretically by Schultze et al. [Science…

Atomic Physics · Physics 2017-02-15 J. Wätzel , A. S. Moskalenko , Y. Pavlyukh , J. Berakdar

We study photoionization of various noble gas atoms by attosecond pulses produced in High Harmonic Generation (HHG). We use a pump-probe experiment to measure the time delays of electrons photoionized from Neon, Argon, and Krypton relative…

Atomic Physics · Physics 2013-08-01 Caryn A. Palatchi , Dietrich Kiesewetter , Daniel M. Canaday , Louis . F. DiMauro

We present calculations for attosecond atomic delays in photoionization of noble gas atoms based on full two-color two-photon Random-Phase Approximation with Exchange in both length and velocity gauge. Gauge invariant atomic delays are…

Atomic Physics · Physics 2019-11-06 Jimmy Vinbladh , Jan Marcus Dahlström , Eva Lindroth

In scattering theory, the Wigner-Smith time delay, calculated through a phaseshift derivative or its multichannel generalization, has been demonstrated to measure the amount of delay or advance experienced by colliding particles during…

Atomic Physics · Physics 2025-11-25 Karim I. Elghazawy , Chris H. Greene

First time-resolved photoemission experiments employing attosecond streaking of electrons emitted by an XUV pump pulse and probed by a few-cycle NIR pulse found a time delay of about 100 attoseconds between photoelectrons from the…

Other Condensed Matter · Physics 2015-05-13 C. Lemell , B. Solleder , K. Tokesi , J. Burgdoerfer

We use a large set of hydrodynamical simulations, combined with measurements of the Lyman alpha opacity of the IGM taken from the literature, to obtain robust estimates for the photoionization rate per hydrogen atom at z=5 and 6. We find…

Astrophysics · Physics 2009-11-13 James S. Bolton , Martin G. Haehnelt

Resonances leave prominent signatures in atomic and molecular ionization triggered by the absorption of single or multiple photons. These signatures reveal various aspects of the ionization process, characterizing both the initial and final…

Atomic Physics · Physics 2026-03-03 Anatoli S. Kheifets

When a single photon traverses a cloud of 2-level atoms, the average time it spends as an atomic excitation -- as measured by weakly probing the atoms -- can be shown to be the spontaneous lifetime of the atoms multiplied by the probability…

Shape resonances in photoionization of atoms and molecules arise from a particular geometry of the ionic potential which traps the receding photoelectron in a quasi-bound state in a particular partial wave. This mechanism allows us to…

Atomic Physics · Physics 2026-03-03 Anatoli S. Kheifets , Stephen Catsamas

Sudden ionisation of a relatively large molecule can initiate a correlation-driven process dubbed charge migration, where the electron density distribution is expected to rapidly change. Capturing this few-femtosecond/attosecond charge…

We describe in detail how attosecond delays in laser-assisted photoionization can be computed using perturbation theory based on two-photon matrix elements. Special emphasis is laid on above-threshold ionization, where the electron…

Atomic Physics · Physics 2015-06-19 J. M. Dahlström , E. Lindroth

Streaked photoemission metrology allows the observation of an apparent relative time delay between the detection of photoelectrons from different initial electronic states. This relative delay is obtained by recording the photoelectron…

Other Condensed Matter · Physics 2015-05-28 Chang-hua Zhang , Uwe Thumm