Related papers: Enhancing vibrational light-matter coupling streng…
Selectively exciting target molecules to high vibrational states is inefficient in the liquid phase, which restricts the use of IR pumping to catalyze ground-state chemical reactions. Here, we demonstrate that this inefficiency can…
We demonstrate strong coupling between molecular excited states and surface plasmon modes of a slit array in a thin metal film. The coupling manifests itself as an anti-crossing behavior of the two newly formed polaritons. As the coupling…
We consider a simple cubic array of metallic nanoparticles supporting extended collective plasmons that arise from the near-field dipolar interaction between localized surface plasmons in each nanoparticle. We develop a fully analytical…
Spin defects in hexagonal boron nitride, and specifically the negatively charged boron vacancy (VB) centres, are emerging candidates for quantum sensing. However, the VB defects suffer from low quantum efficiency and as a result exhibit…
When the collective coupling of the rovibrational states in organic molecules and confined electromagnetic modes is sufficiently strong, the system enters into vibrational strong coupling, leading to the formation of hybrid light-matter…
We introduce a prototypical model for cavity polaritonic control of ultracold photochemistry by considering the resonant vibrational strong coupling of a rubidium dimer to a terahertz cavity. We demonstrate that at avoided crossings between…
The achievement of large values of the light-matter coupling in nanoengineered photonic structures can lead to multiple photonic resonances contributing to the final properties of the same hybrid polariton mode. We develop a general theory…
Intermixed light-matter quasiparticles - polaritons - possess unique optical properties owned to their compositional nature. These intriguing hybrid states have been extensively studied over the past decades in a wide range of realizations…
Localized plasmonic modes of metallic nanoparticles may hybridize like those of atoms forming a molecule. However, the rapid decay of the plasmonic fields outside the metal severely limits the range of these interactions to tens of…
The strong coupling between molecules and photonic modes in a Fabry-P\'{e}rot optical cavity, which forms hybrid light-matter states called polaritons, has been demonstrated as a promising route to control the rates of chemical reactions.…
In this work, the plasmon coupling effect between two gold nanospheres on a gold slab is investigated. At plasmon resonance frequencies, electrons on the surface of the slab are absorbed into spheres and contribute to plasmon oscillation.…
In this article, we present a numerical study of the optical properties of a metal nanowire interacting with a localized cavity in a two dimensional photonic crystal. The nature of the modes, their wavelength and width are investigated as a…
Polaritonic chemistry exploits strong light-matter coupling between molecules and confined electromagnetic field modes to enable new chemical reactivities. In systems displaying this functionality, the choice of the cavity determines both…
Crystals of plasmonic metal nanoparticles have intriguing optical properties. They reach the regimes of ultrastrong and deep strong light-matter coupling, where the photonic states need to be included in the simulation of material…
Despite the potential paradigm breaking capability of microcavities to control chemical processes, the extent to which photonic devices change properties of molecular materials is still unclear, in part due to challenges in modeling hybrid…
We study the strong coupling between the molecular excited state and the plasmonic modes of silver hole arrays with a resonant frequency very close to the asymptotic line of the plasmonic dispersion relation, at the nonlinear regime. We…
We study a system of interacting matter quasiparticles strongly coupled to photons inside an optomechanical cavity. The resulting normal modes of the system are represented by hybrid polaritonic quasiparticles, which acquire effective…
Strong coupling between light and matter is possible with a variety of organic materials. In contrast to the simpler inorganic case, organic materials often have a complicated spectrum, with vibrationally dressed electronic transitions.…
In this work, we combine the density functional tight-binding (DFTB) approach with a light-matter Hamiltonian beyond the long-wavelength approximation to propagate the dynamics of vibrational polaritons formed by coupling molecular…
This work presents numerical and experimental results of plasmonic Metal-Insulator optical nano-cavities. The systems are composed of Silver as metal, polyvinylpyrrolidone or indium tin oxide or zinc oxide as insulator. The proposed…