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First-principles calculations for pristine neutral ferroelectric domain walls in BiFeO$_3$ reveal that excess electrons are selectively trapped by the domain walls, while holes are only weakly attracted. Such trapped excess electrons may be…

Materials Science · Physics 2018-10-03 Sabine Körbel , Jirka Hlinka , Stefano Sanvito

Magnesium nickel hydride films have earlier been suggested for several optoelectronic applications, but the optical properties and band gap have not been firmly established. In this work, the dielectric functions and the optical band gaps…

Materials Science · Physics 2012-09-07 J. H. Selj , T. Mongstad , B. Hauback , S. Karazhanov

Photocatalysis, a promising solution for environmental challenges, relies on the generation and utilization of photogenerated charge carriers within photocatalysts. However, recombination of these carriers often limits efficiency.…

Materials Science · Physics 2024-03-18 Mona Asadinamin , Aleksandar Živkovic , Nora H. De Leeuw , Steven P. Lewis

We present a unified ab-initio study of electronic and optical properties of TiO2 rutile and anatase phases, with a combination of Density Functional Theory and Many Body Perturbation Theory techniques. The consistent treatment of…

Oxygen deficient titanium dioxide (TiO$_{2-x}$) is a very attractive material for several applications ranging from photocatalysis to resistive switching. Oxygen vacancies turn insulating anatase titanium dioxide into a polaronic conductor,…

Amorphous films of tantalum oxide (Ta2O5) are widely applied to build highly reflective mirrors used in interferometric gravitational wave detectors, such as the Laser Interferometer Gravitational Wave Observatory (LIGO). Despite a large…

Materials Science · Physics 2021-11-29 Alberto Martinelli , Mauro Giovannini , Martina Neri , Gianluca Gemme

The presence of small hematite (Fe2O3) clusters at low coverage on titanium dioxide (TiO2) surface has been observed to enhance photocatalytic activity, while excess loading of hematite is detrimental. We conduct a comprehensive density…

Materials Science · Physics 2024-04-09 Kati Asikainen , Matti Alatalo , Marko Huttula , Bernardo Barbiellini , S. Assa Aravindh

A template-free process for the synthesis of nanocrystalline TiO2 hierarchical microstructures by reactive Pulsed Laser Deposition (PLD) is here presented. By a proper choice of deposition parameters a fine control over the morphology of…

Materials Science · Physics 2013-11-28 F. Di Fonzo , C. S. Casari , V. Russo , M. F. Brunella , A. Li Bassi , C. E. Bottani

The structural and electronic properties of amorphous silicon ($a$-Si) are investigated by first-principles calculations based on the density-functional theory (DFT), focusing on the intrinsic structural defects. By simulated melting and…

Materials Science · Physics 2017-10-11 Yoritaka Furukawa , Yu-ichiro Matsushita

The complex dielectric functions of LiNbO$_2$ were determined using optical transmittance and reflectance spectroscopies at room temperature. The measured dielectric function spectra reveal distinct structures at several bandgap energies.…

Materials Science · Physics 2023-10-30 T. Kurachi , T. Yamaguchi , E. Kobayashi , T. Soma , A. Ohtomo , T. Makino

We investigate the quasiparticle band structure of anatase TiO2, a wide gap semiconductor widely employed in photovoltaics and photocatalysis. We obtain GW quasiparticle energies starting from density-functional theory (DFT) calculations…

Materials Science · Physics 2012-04-23 Christopher E. Patrick , Feliciano Giustino

The band structure, optical and defects properties of Ba_{2}TeO are systematically investigated using density functional theory with a view to understanding its potential as an optoelectronic or trans- parent conducting material. Ba_{2}TeO…

Materials Science · Physics 2015-06-11 Jifeng Sun , Hongliang Shi , Mao-Hua Du , Theo Siegrist , David J. Singh

The rutile TiO$_2$ (110) surface reduced by the bridging oxygen vacancy, bridging hydroxyl group or Ti interstitial atom has been investigated by calculating their electronic structures using the density functional theory plus U method. It…

Materials Science · Physics 2015-10-13 Daoyu Zhang , Minnan Yang , Shuai Dong

The local-density approximation combined with the dynamical mean-field theory (LDA+DMFT) is applied to the paramagnetic phase of light actinide dioxides: UO2, NpO2, and PuO2. The calculated band gaps and the valence-band electronic…

Strongly Correlated Electrons · Physics 2015-08-25 Jindrich Kolorenc , Alexander B. Shick , Alexander I. Lichtenstein

The magneto-optical properties of titanium dioxide systems are related to the presence of impurity states in the band gap due to oxygen vacancies. To understand about the interplay between localized electrons and structural distortions at…

Materials Science · Physics 2023-05-10 C. Echeverria-Arrondo , H. Raebiger , J. Perez-Conde , C. Gomez-Polo , A. Ayuela

The sub-gap density of states of amorphous indium gallium zinc oxide ($a$-IGZO) is obtained using the ultrabroadband photoconduction (UBPC) response of thin-film transistors (TFTs). Density functional theory simulations classify the origin…

Titanium dioxide (TiO$_2$) has rich physical properties with potential implications in both fundamental physics and new applications. Up-to-date, the main focus of applied research is to tune its optical properties, which is usually done…

We report the results of experimental studies related to implantation of thorium ions into thin silicon dioxide by pulsed plasma fluxes expansion. Thorium ions were generated by laser ablation from a metal target, and the ionic component of…

Normal state resistivity and Hall effect are shown to be successfully modeled by a two-band model of holes and electrons that is applied self-consistently to (i) DC transport data reported for eight bulk-crystal and six oriented-film…

Superconductivity · Physics 2012-02-09 Dale R. Harshman , John D. Dow , Anthony T. Fiory

Amorphous silicon films prepared by electron beam evaporation have systematically and substantially greater atomic density for higher thickness, higher growth temperature, and slower deposition rate, reaching the density of crystalline Si…

Materials Science · Physics 2022-04-27 H. C. Jacks , M. Molina-Ruiz , M. H. Weber , J. J. Maldonis , P. M. Voyles , T. H. Metcalf , X. Liu , F. Hellman