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Related papers: Comment on "Validity of path thermodynamics in rea…

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Polydisperse systems are commonly encountered when dealing with soft matter in general or any non simple fluid. Yet their treatment within the framework of statistical thermodynamics is a delicate task as the latter has been essentially…

Statistical Mechanics · Physics 2015-06-22 Fabien Paillusson , Ignacio Pagonabarraga

We briefly review the recently developed, Markov process based isothermal chemical thermodynamics for nonlinear, driven mesoscopic kinetic systems. Both the instantaneous Shannon entropy {\boldmath $S[p_{\alpha}(t)]$} and relative entropy…

Statistical Mechanics · Physics 2017-01-10 David B. Saakian , Hong Qian

We reformulate the result for the entropy production given in Phys. Rev. Lett. 98, 080602 (2007) in terms of the relative entropy of microscopic trajectories. By a combination with the Crook's theorem, we identify the path variables that…

Statistical Mechanics · Physics 2009-11-13 A. Gomez-Marin , J. M. R. Parrondo , C. Van den Broeck

After the justification of the maximum entropy approach for equilibrium thermodynamic system, and of a maximum path entropy algorithm for nonequilibrium thermodynamic systems by virtue of the principle of virtual work, we present in this…

Statistical Mechanics · Physics 2007-12-18 Qiuping A. Wang

Enzyme kinetics is very often characterised by the irreversible Michaelis-Menten (MM) equation. However, in open chemical reaction networks such as metabolic pathways, this approach can lead to significant kinetic and thermodynamic…

Biological Physics · Physics 2020-06-12 Valérie Voorsluijs , Francesco Avanzini , Massimiliano Esposito

Using stochastic thermodynamics, the properties of interacting linear chains subject to periodic drivings are investigated. The systems are described by Fokker-Planck-Kramers equation and exact (explicit) solutions are obtained for periodic…

Statistical Mechanics · Physics 2020-02-05 Bruno A. N. Akasaki , M. J. de Oliveira , Carlos E. Fiore

The rate of entropy production by a stochastic process quantifies how far it is from thermodynamic equilibrium. Equivalently, entropy production captures the degree to which detailed balance and time-reversal symmetry are broken. Despite…

Statistical Mechanics · Physics 2020-12-02 Luca Cocconi , Rosalba Garcia-Millan , Zigan Zhen , Bianca Buturca , Gunnar Pruessner

At the microscopic scale, open chemical reaction networks are described by stochastic reactions that follow mass-action kinetics and are coupled to chemostats. We show that closed chemical reaction networks -- with specific stoichiometries…

Molecular Networks · Quantitative Biology 2025-06-30 Benedikt Remlein , Massimiliano Esposito , Francesco Avanzini

In this paper, we present criteria for non-exponential ergodicity of continuous-time Markov chains on a countable state space. These criteria can be verified by examining the ratio of transition rates over certain paths. We applied this…

Probability · Mathematics 2024-02-09 Minjoon Kim , Jinsu Kim

The laws of thermodynamics apply to biophysical systems on the nanoscale as described by the framework of stochastic thermodynamics. This theory provides universal, exact relations for quantities like work, which have been verified in…

Statistical Mechanics · Physics 2024-09-26 Julius Degünther , Jann van der Meer , Udo Seifert

We show that the analysis presented in a recent comment by Coll and Ferrando \cite{comment} (qr-qc/0312058) is based on the erroneous assumption that the chemical potential and fractional concentration of a {\it mixture} of perfect fluids…

General Relativity and Quantum Cosmology · Physics 2007-05-23 Hernando Quevedo , Ruben D. Zarate

The inexorable development of ever more powerful laser systems has re-ignited interest in electromagnetic radiation reaction and its significance for the collective behaviour of charged matter interacting with intense electromagnetic…

Plasma Physics · Physics 2014-03-03 David A Burton , Adam Noble

We comment on various incorrect claims made in a recent paper by Grosu et al. (cond-mat/0101392).

Statistical Mechanics · Physics 2007-05-23 D. Belitz , T. R. Kirkpatrick

If the von Neumann equation is modified by time dependent statistical weights, the time rate of entropy, the entropy exchange and production of a Schottky system are derived whose Hamiltonian does not contain the interaction with the…

Quantum Physics · Physics 2019-01-30 Wolfgang Muschik

I formulate a quantum stochastic thermodynamics for the quantum trajectories of a continuously-monitored forced harmonic oscillator coupled to a thermal reservoir. Consistent trajectory-dependent definitions are introduced for work, heat,…

Statistical Mechanics · Physics 2015-06-03 Jordan M. Horowitz

A path information is defined in connection with different possible paths of irregular dynamic systems moving in its phase space between two points. On the basis of the assumption that the paths are physically differentiated by their…

Statistical Mechanics · Physics 2007-05-23 Qiuping A. Wang

The article compares traditional coefficients of thermodynamic activity as a parameter related to individual chemical species to newly introduced reduced chaotic temperatures as system characteristics, both regarding their usage in…

Chemical Physics · Physics 2007-05-23 B. Zilbergleyt

Statistical thermodynamics delivers the probability distribution of the equilibrium state of matter through the constrained maximization of a special functional, entropy. Its elegance and enormous success have led to numerous attempts to…

Statistical Mechanics · Physics 2023-06-22 Themis Matsoukas

The issue of the thermodynamics of a system of distinguishable particles is discussed in this paper. In constructing the statistical mechanics of distinguishable particles from the definition of Boltzmann entropy, it is found that the…

Chemical Physics · Physics 2009-12-03 Chi-Ho Cheng

This is a reply to the comment to a letter by D. Mandal, K. Klymko and M. R. DeWeese published as Phys. Rev. Lett. 119, 258001 (2017).

Soft Condensed Matter · Physics 2018-09-11 Dibyendu Mandal , Katherine Klymko , Michael R. DeWeese