Related papers: Comment on "Validity of path thermodynamics in rea…
The entropy production rate is a key quantity in non-equilibrium thermodynamics of both classical and quantum processes. No universal theory of entropy production is available to date, which hinders progress towards its full grasping. By…
The use of mathematical methods for the analysis of chemical reaction systems has a very long history, and involves many types of models: deterministic versus stochastic, continuous versus discrete, and homogeneous versus spatially…
We illustrate the mathematical theory of entropy production in repeated quantum measurement processes developed in a previous work by studying examples of quantum instruments displaying various interesting phenomena and singularities. We…
We introduce a class of random mechanical systems called random billiards to study the problem of quantifying the irreversibility of nonequilibrium macroscopic systems. In a random billiard model, a point particle evolves by free motion…
Thermalization is one of the most important phenomena in statistical physics. Often, the transition probabilities between different states in the phase space is or can be approximated by constants. In this case, the system can be described…
We respond to two sets of criticisms of our analysis in Noack & Niven, Journal of Fluid Mechanics 700, 187--213 (2012), made by Di Vita, Journal of Thermodynamics & Catalysis, 3: e108 (2012). We show that the criticisms are incorrect and…
Stochastic thermodynamics gives universal relations for microscopic entropy production, yet its critical behavior at macroscopic nonequilibrium transitions remains unclassified. We study well-mixed reversible chemical reaction networks in…
In this paper we review and extend our earlier recent work on thermostated systems. A description of nano-biological systems by Markov chains in coordinate space in the strongly overdamped limit is presented. Characterization of the most…
Using the stochastic thermodynamics, we determine the entropy production and the dynamic heat capacity of systems subject to a sinusoidally time dependent temperature, in which case the systems are permanently out of thermodynamic…
Peng et al.(2020) formulated one-way fluxes for a general chemical reaction far from equilibrium, with arbitrary complex mechanisms, multiple intermediates, and internal kinetic cycles. Species are classified into internal Y's and external…
The reaction coordinate describing a transition between reactant and product is a fundamental concept in the theory of chemical reactions. Within transition-path theory, a quantitative definition of the reaction coordinate is found in the…
We investigate the fundamental relation between entropy production rate and the speed of energy exchange between a system and baths in classical Markov processes. We establish the fact that quick energy exchange inevitably induces large…
In a recent paper Andrei N. Soklakov explained the foundations of the Lagrangian formulation of classical particle mechanics by means of Kolmogorov complexity. In the present paper we use some of Soklakov ideas in order to derive the second…
The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology,…
A set of core features is set forth as the essence of a thermodynamic description, which derive from large-deviation properties in systems with hierarchies of timescales, but which are \emph{not} dependent upon conservation laws or…
In a series of publications, Kocherginsky and Gruebele presented a systematic framework for chemical transport and thermodiffusion to predict the Soret coefficients from thermodynamics. A macroscopic derivation of the Onsager reciprocal…
This is a comment to a letter by D. Mandal, K. Klymko and M. R. DeWeese published as Phys. Rev. Lett. 119, 258001 (2017).
The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…
Recently, Elouard and Lombard Latune [PRX Quantum 4, 020309 (2023)] claimed to extend the laws of thermodynamics to "arbitrary quantum systems" valid "at any scale" using "consistent" definitions allowing them to "recover known results"…
The stochastic thermodynamics provides a framework for the description of systems that are out of thermodynamic equilibrium. It is based on the assumption that the elementary constituents are acted by random forces that generate a…