Related papers: Carbon isotopic fractionation in molecular clouds

The carbon isotope ratio is a powerful tool for studying the evolution of stellar systems. Recent detections of CO isotopologues in disks and exoplanet atmospheres pointed towards significant fractionation in these systems. In order to…

Despite a rich observational background, few spectroscopic studies have dealt with the measurement of the carbon isotopic ratio in giant stars. However, it is a key element in understanding the mixing mechanisms that occur in the interiors…

The isotopic signature of atmospheric carbon offers a unique tracer for the history of the Martian atmosphere and the origin of organic matter on Mars. Photolysis of CO$_{2}$ is known to induce strong isotopic fractionation of carbon…

Observations of deuterated species are useful in probing the temperature, ionization level, evolutionary stage, chemistry, and thermal history of astrophysical environments. The analysis of data from ALMA and other new telescopes requires…

Nitrogen abundances and carbon isotope ratios (12C/13C) in the atmospheres of red giants are known to be influenced by dredge-up of H-burning products and serve as useful probes to study the nature of evolution-induced envelope mixing. We…

Clouds of high infrared extinction are promising sites of massive star/cluster formation. A large number of cloud cores discovered in recent years allows investigation of possible evolutionary sequence among cores in early phases. We have…

Tracer diffusion of the substitutional components in (CoCrFeNiMn)$_{1-x}$C$_x$ high-entropy alloys with x = 0.002, 0.005 and 0.008 (in at. fractions) is measured at elevated temperatures from 1173 to 1373 K. Two different characteristic…

We present high-resolution (FWHM ~ 0.3-1.5 km/s) spectra of interstellar Ca I absorption toward 30 Galactic stars. Comparisons of the column densities of Ca I, Ca II, K I, and other species -- for individual components identified in the…

We systematically analyze total reaction cross sections of carbon isotopes with N=6--16 on a $^{12}$C target for wide range of incident energy. The intrinsic structure of the carbon isotope is described by a Slater determinant generated…

In the interstellar medium (ISM), the formation of complex organic molecules (COMs) is largely facilitated by surface reactions. However, in cold dark clouds, thermal desorption of COMs is inefficient because of the lack of thermal energy…

Molecules and particles make up $\sim 40 - 70\%$ of carbon in the interstellar medium, yet the exact chemical structure of these constituents remains unknown. We present carbon K-shell absorption spectroscopy of the Galactic Interstellar…

A line list of vibration-rotation transitions for 13C substituted HCN is presented. The line list is constructed using known experimental levels where available, calculated levels and ab initio line intensities originally calculated for the…

Carbon-rich grains with isotopic anomalies compared to the Sun are found in primitive meteorites. They were made by stars, and carry the original stellar nucleosynthesis signature. Silicon carbide grains of Type X and C, and low-density…

Grain surface chemistry and its treatment in gas-grain chemical models is an area of large uncertainty. Whilst laboratory experiments are making progress, there is still much that is unknown about grain surface chemistry. Further, the…

Context: Dark cloud chemical models usually predict large amounts of O2, often above observational limits. Aims: We investigate the reason for this discrepancy from a theoretical point of view, inspired by the studies of Jenkins and Whittet…

We present a systematic study of the HNCO, C18O, 13CS, and C34S emission towards 13 selected molecular clouds in the Galactic center region. The molecular emission in these positions are used as templates of the different physical and…

The 12C14N/12C15N and 12C14N/13C14N isotopic ratios are determined for the first time in a Jupiter-family comet, 88P/1981 Q1 Howell, and in the chemically peculiar Oort Cloud comet C/1999 S4 (LINEAR). By comparing these measurements to…

We show that the12CO/13CO intensity ratio in nearby galaxies varies systematically as a function of the star formation rate surface density and gas surface density. The same effect is observed in different transitions, and in the 12CO/C18O…

We review the reactions between carbon chain molecules and radicals, namely Cn, CnH, CnH2, C2n+1O, CnN, HC2n+1N, with C, N and O atoms. Rate constants and branching ratios for these processes have been re-evaluated using experimental and…

We have studied deuterium fractionation on interstellar grains with the use of an exact method known as the direct master equation approach. We consider conditions pertinent to dense clouds at late times when the hydrogen is mostly in…