Related papers: Carbon isotopic fractionation in molecular clouds
We report measurements of the 12C/13C abundance ratio in the three galactic regions G 333.0-0.4, NGC 6334 A and G 351.6-1.3 from observations of the 12CI 3P2-3P1 transition and the hyperfine components of the corresponding 13CI transition…
Many interstellar complex organic molecules (COMs) are believed to be produced on the surfaces of icy grains at low temperatures. Atomic carbon is considered responsible for the skeletal evolution processes, such as C-C bond formation, via…
The time-dependent rate coefficients for the charge exchange reaction C+ + Si -> C + Si+ for doublet and quartet states have been determined with ab initio quantum calculations coupled with a non-adiabatic transition model based on a simple…
With the goal of deriving the physical and chemical conditions of star forming regions in the Large Magellanic Cloud (LMC), a spectral line survey of the prominent star forming region N113 is presented. The observations cover parts of the…
Carbon isotope ratios, along with carbon and nitrogen abundances, are derived in a sample of 11 red-giant members of one of the most metal-rich clusters in the Milky Way, NGC 6791. The selected red-giants have a mean metallicity and…
$^{12}$C$/^{13}$C line intensity ratios have been derived from several carbon-bearing molecules to confine the range of carbon and oxygen isotope abundance ratios toward the nuclear regions of two infrared bright galaxies. The most…
The isotopic ratio of nitrogen measured in primitive Solar System bodies shows a broad range of values, the origin of which remains unknown. One key question is whether these isotopic reservoirs of nitrogen predate the comet formation stage…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…
We use computational screening to systematically investigate the use of transition metal doped carbon nanotubes for chemical gas sensing. For a set of relevant target molecules (CO, NH3, H2S) and the main components of air (N2, O2, H2O), we…
Organic material found in meteorites and interplanetary dust particles is enriched in D and 15N. This is consistent with the idea that the functional groups carrying these isotopic anomalies, nitriles and amines, were formed by ion-molecule…
The proton radiative capture $^{12,13}$C$(p,{\gamma})$ reactions at astrophysical energies, key processes in the CNO cycle, are revisited in the potential model with the proton-nucleus potential for both the scattering and bound states…
Fusion data for $^{13}$C+$^{13}$C, $^{12}$C+$^{13}$C and $^{12}$C+$^{12}$C are analyzed by coupled-channels calculations that are based on the M3Y+repulsion, double-folding potential. The fusion is determined by ingoing-wave-boundary…
Among the silicon bearing species discovered in the interstellar medium, SiS and SiO stand out as key tracers due to their distinct chemistry and abundances in interstellar and circumstellar environments. Our objective is to enhance the…
Zinc metal-silicate fractionation provides experimental access to the conditions of core formation and Zn has been used to estimate the S contents of the Earth's core and of the bulk Earth, assuming that they share similar volatility and…
The 12C/13C isotope ratio has been derived towards numerous cold clouds (20-50 K) and a couple protoplanetary disks and exoplanet atmospheres. However, direct measurements of this ratio in the warm gas (>100 K) around young low-mass…
When two phases of water are at equilibrium, the ratio of hydrogen isotopes in each is slightly altered due to their different phase affinities. This isotopic fractionation process can be utilized to analyze water's movement in the world's…
Absorption lines of the 12CO and 13CO molecular bands (Delta v = 2) at 2.29 -- 2.45 micron are modelled in spectrum of Arcturus (K2III). We compute a grid of model atmospheres and synthetic spectra for giant of Teff = 4300, log g = 1.5, and…
We present an extended version of the 2-phase gas-grain code NAUTILUS to the 3-phase modelling of gas and grain chemistry of cold cores. In this model, both the mantle and the surface are considered as chemically active. We also take into…
The 12C/13C isotope ratio is a tracer of stellar yields and the efficiency of mixing in the ISM. 12CH+/13CH+ is not affected by interstellar chemistry, and is the most secure way of measuring 12C/13C in the diffuse ISM. R= 12C/13C is 90 in…
We model emissivities of the HCN and CO $J=1-0$ transitions using measured properties of clouds found in normal star forming galaxies and more extreme systems. These models are compared with observations of HCN and CO $J=1-0$ transitions.…