Related papers: Carbon isotopic fractionation in molecular clouds
The origin of the heavily fractionated reservoir of nitrogen in comets remains an issue in the theory of their formation and hence of the solar system. Whether the fractionated reservoir traced by comets is inherited from the interstellar…
CO isotopologue transitions are routinely observed in molecular clouds to probe the column density of the gas, the elemental ratios of carbon and oxygen, and to trace the kinematics of the environment. We aim at estimating the abundances,…
Chemical networks used for models of interstellar clouds contain many reactions, some of them with poorly determined rate coefficients and/or products. In this work, we report a method for improving the predictions of molecular abundances…
Understanding gas-grain chemistry of deuterium in star-forming objects may help to explain their history and present state. We aim to clarify how processes in ices affect the deuterium fractionation. In this regard, we investigate a…
We present synthetic line observations of a simulated molecular cloud, utilising a self-consistent treatment of the dynamics and time-dependent chemical evolution. We investigate line emission from the three most common CO isotopologues…
Based on the medium resolution near infrared spectra of 13CO (3,1) band, carbon isotopic ratios are estimated in 48 M dwarfs, for which we had determined the carbon and oxygen abundances from CO and H2O lines, respectively. We find clear…
Context. The nitrogen isotopic ratio is considered an important diagnostic tool of the star formation process, and $N_2H^+$ is particularly important because it is directly linked to molecular nitrogen $N_2$. However, theoretical models…
Deuterium fractionation in molecular ions, in particular HCO+, has been extensively used to estimate the degree of ionization in molecular clouds. This paper reviews recent work on ionization degree in homogeneous clouds. We will show that…
Nitrogen is one of the most abundant elements in the Universe and its 14N/15N isotopic ratio has the potential to provide information about the initial environment in which our Sun formed. Recent findings suggest that the Solar System may…
We present the first determination of the abundance ratios of $^{13}$C substitutions of cyanoacetylene (HC$_{3}$N), [H$^{13}$CCCN]:[HC$^{13}$CCN]:[HCC$^{13}$CN] in Titan's atmosphere measured using millimeter-wave spectra obtained by the…
We observed the $J=5-4$ rotational lines of the normal species and three $^{13}$C isotopologues of HC$_{3}$N at the 45 GHz band toward two low-mass starless cores, L1521B and L134N (L183), using the Nobeyama 45 m radio telescope in order to…
In dense clouds of the interstellar medium, dust grains are covered by ice mantles, dominated by H$_2$O. CO and CO$_2$ are common ice components observed in infrared spectra, while infrared inactive N$_2$ is expected to be present in the…
This work examines the carbon defects associated with recently reported and novel peaks of infrared (IR) absorption and Raman scattering appearing in GaN crystals at carbon ($^{12}C$) doping in the range of concentrations from $3.2*10^{17}$…
The search for signs of life on other worlds has largely focused on terrestrial planets. Recent work, however, argues that life could exist in the atmospheres of temperate sub-Neptunes. Here, we evaluate the usefulness of carbon dioxide…
We observed the J=9-8 and 10-9 rotational lines of three13C isotopologues of HC3N in L1527 and G28.28-0.36 with the 45-m radio telescope of the Nobeyama Radio Observatory in order to constrain the main formation mechanisms of HC3N in each…
We present a new constraint on the Galactic $^{12}$C/$^{13}$C gradient with sensitive HCO$^+$ absorption observations against strong continuum sources. The new measurements suffer less from beam dilution, optical depths, and chemical…
We present observations of circumstellar millimetre-wave 13CO line emission towards a sample of 20 cool carbon stars. Using a detailed radiative transfer model we estimate the circumstellar 12CO/13CO-ratios, which we believe accurately…
Estimating molecular abundances ratios from the direct measurement of the emission of the molecules towards a variety of interstellar environments is indeed very useful to advance in our understanding of the chemical evolution of the…
The deuterium fractionation of gas-phase molecules in hot cores is believed to reflect the composition of interstellar ices. The deuteration of methanol is a major puzzle, however, because the isotopologue ratio [CH2DOH]/[CH3OD], which is…
Context: CO is an abundant species in comets, creating CO$^+$ ion with emission lines that can be observed in the optical spectral range. A good modeling of its fluorescence spectrum is important for a better measurement of the CO$^+$…