Related papers: Generalized local frame transformation theory for …
We present a depletion imaging technique to map out the spatial and temporal dependency of the density distribution of an ultracold gas of Rydberg atoms. Locally resolved absorption depletion, observed through differential ground state…
Atoms in highly excited (Rydberg) states have a number of unique properties which make them attractive for applications in quantum information. These are large dipole moments, lifetimes and polarizabilities, as well as strong long-range…
The large electric dipole moments associated with highly excited Rydberg states of atoms and molecules make gas-phase samples in these states very well suited to deceleration and trapping using inhomogeneous electric fields. The methods of…
Under the local plasmonic excitation, the Raman images of a single molecule can now reach sub-nanometer resolution. We report here a theoretical description of the interaction between a molecule and a highly confined plasmonic field. It is…
We report on the formation of ultralong-range Rydberg D-state molecules via photoassociation in an ultracold cloud of rubidium atoms. By applying a magnetic offset field on the order of 10 G and high resolution spectroscopy, we are able to…
We perform a comparative analysis of different computational approaches employed to explore the electronic structure of ultralong-range Rydberg molecules. Employing the Fermi pseudopotential approach, where the interaction is approximated…
In this work we discuss the rotational structure of Rydberg molecules. We calculate the complete wave function in a laboratory fixed frame and derive the transition matrix elements for the pho- toassociation of free ground state atoms. We…
Non-invasive microwave field imaging--accurately mapping field distributions without perturbing them--is essential in areas such as aerospace engineering, biomedical imaging and integrated-circuit diagnostics. Conventional metal probes,…
We investigate polyatomic ultralong-range Rydberg molecules consisting of three ground state atoms bound to a Rydberg atom via $s$- and $p$-wave interactions. By employing the finite basis set representation of the unperturbed Rydberg…
We explore the external electric field control of a species of ultralong-range molecules that emerge from the interaction of a ground state polar molecule with a Rydberg atom. The external field mixes the Rydberg electronic states and…
We explore the electronic structure of ultralong-range pentaatomic Rydberg molecules from a merger of a Rydberg atom and two ground state heteronuclear diatomic molecules. Our focus is on the interaction of Rb($23s$) and Rb($n=20$, $l\ge…
Rydberg atomic electrometry leverages the extreme sensitivity of highly excited atoms for calibration-free electric field measurements. The technique uses a non-metallic vapor cell to link properties of an RF field to a spectroscopic…
Two-photon ionization of an alkali-metal atom in the presence of a uniform electric field is investigated using a standardized form of local frame transformation and generalized quantum defect theory. The relevant long-range quantum defect…
Rydberg atom-based electrometry enables traceable electric field measurements with high sensitivity over a large frequency range, from gigahertz to terahertz. Such measurements are particularly useful for the calibration of radio frequency…
We present photodissociation of ultracold long-range Rydberg molecules as a tool to characterize their electronic properties. We photoassociate K2 37P molecules with highly entangled electronic and nuclear spins of the two bound atoms and…
We introduce a computational method developed for study of long-range molecular Rydberg states of such systems that can be approximated by two electrons in a model potential of the atomic cores. Only diatomic molecules are considered. The…
The transfer of weakly bound KRb molecules from levels just below the dissociation threshold into the vibrational ground state with shaped laser pulses is studied. Optimal control theory is employed to calculate the pulses. The complexity…
Obtaining full control over the internal and external quantum states of molecules is the central goal of ultracold chemistry and allows for the study of coherent molecular dynamics, collisions and tests of fundamental laws of physics. When…
The ability to control and tune interactions in ultracold atomic gases has paved the way towards the realization of new phases of matter. Whereas experiments have so far achieved a high degree of control over short-ranged interactions, the…
Quantum reflection is a pure wave phenomena that predicts reflection of a particle at a changing potential for cases where complete transmission occurs classically. For a chemical bond, we find that this effect can lead to non-classical…