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Single-ion magnetic anisotropy in molecular magnets leads to spin flip excitations that can be measured by inelastic scanning tunneling microscope (STM) spectroscopy. Here I present a semi ab initio scheme to compute the spectral features…

Mesoscale and Nanoscale Physics · Physics 2018-08-16 David Jacob

In the field of molecular electronics, particularly in quantum transport studies, the orientation of molecules plays a crucial role. This orientation, with respect to the electrodes, can be defined through the cavity of ring-shaped…

Materials Science · Physics 2023-02-17 A. Martinez-Garcia , T. de Ara , L. Pastor-Amat , C. Untiedt , E. B. Lombardi , W. Dednam , C. Sabater

Optical trapping can be used to manipulate the three-dimensional (3-D) motion of spherical particles based on the simple prediction of optical forces and the responding motion of samples. However, controlling the 3-D behaviour of…

Optics · Physics 2017-06-28 Kyoohyun Kim , YongKeun Park

We study the elementary processes behind one of the pioneering works on STM controlled reactions of single molecules [Stipe et al., Phys. Rev. Lett. 81, 1263 (1998)]. Using the Keldysh-Green function approach for the vibrational generation…

Mesoscale and Nanoscale Physics · Physics 2013-12-06 Yulia E. Shchadilova , Sergei G. Tikhodeev , Magnus Paulsson , Hiromu Ueba

A molecular rotation assisted non-sequential double ionization (MR-NSDI) mechanism is identified in the breakup of rotational H$_2$ molecules in a few-cycle intense laser pulse using a semi-classical trajectory Monte Carlo method. Applying…

Atomic Physics · Physics 2022-05-31 Ahai Chen

Semiconductor fabrication is a mainstay of modern civilization, enabling the myriad applications and technologies that underpin everyday life. However, while sub-10 nanometer devices are already entering the mainstream, the end of the…

We propose an objective and robust method to extract the electrical conductance of single molecules connected to metal electrodes from a set of measured conductance data. Our method roots in the physics of tunneling and is tested on…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 M. Teresa González , Songmei Wu , Roman Huber , Sense J. van der Molen , Christian Schönenberger , Michel Calame

We present a simple quantum mechanical model describing excited rotational states of molecules in superfluid helium nanodroplets, as recently studied in non-adiabatic molecular alignment experiments [Cherepanov et al., Phys. Rev. A 104,…

Flow-driven rotary motors drive functional processes in human society such as windmills and water wheels. Although examples of such rotary motors also feature prominently in cell biology, their synthetic construction at the nanoscale has…

We present a novel method for probing the alignment of the molecular axis of an ultracold, nonpolar dimer. These results are obtained using diatomic $^{87}\textrm{Rb}_2$ molecules in the vibrational ground state of the lowest triplet…

Atomic Physics · Physics 2015-01-15 Markus Deiß , Björn Drews , Benjamin Deissler , Johannes Hecker Denschlag

We put forward an enantioselective method for chiral nanoparticles using optical tweezers. We demonstrate that the optical trapping force in a typical, realistic optical tweezing setup with circularly-polarized trapping beams is sensitive…

Optics · Physics 2019-11-07 R. Ali , F. A. Pinheiro , F. S. S. Rosa , R. S. Dutra , P. A. Maia Neto

The magnetic properties of metal-organic complexes are strongly influenced by conformational changes in the ligand. The flexibility of Fe-tetra-pyridyl-porphyrin molecules leads to different adsorption configurations on a Au(111) surface.…

Mesoscale and Nanoscale Physics · Physics 2018-11-06 Daniela Rolf , Christian Lotze , Constantin Czekelius , Benjamin W. Heinrich , Katharina J. Franke

We provide a theory of the deflection of polar and non-polar rotating molecules by inhomogeneous static electric field. Rainbow-like features in the angular distribution of the scattered molecules are analyzed in detail. Furthermore, we…

Chemical Physics · Physics 2015-05-20 E. Gershnabel , I. Sh. Averbukh

We report measurements and theoretical analysis of resonant spin tunneling in randomly oriented nanospheres of a molecular magnet. Amorphous nanospheres of Mn$_{12}$ acetate have been fabricated and characterized by chemical, infrared, TEM,…

Mesoscale and Nanoscale Physics · Physics 2015-07-30 S. Lendinez , R. Zarzuela , J. Tejada , M. W. Terban , S. J. L. Billinge , J. Espin , I. Imaz , D. Maspoch , E. M. Chudnovsky

Laser cooling is used to produce ultracold atoms and molecules for quantum science and precision measurement applications. Molecules are more challenging to cool than atoms due to their vibrational and rotational internal degrees of…

Atomic Physics · Physics 2024-09-27 Grace K. Li , Christian Hallas , John M. Doyle

We characterized CO2 adsorption and diffusion on the missing row reconstructed Cu(100)-O surface using a combination of scanning tunneling microscopy (STM) and density functional theory (DFT) calculations with dispersion. We deposited CO2…

Mesoscale and Nanoscale Physics · Physics 2020-07-14 Steven J. Tjung , Qiang Zhang , Jacob J. Repicky , Simuck F. Yuk , Xiaowa Nie , Nancy M. Santagata , Aravind Asthagiri , Jay A. Gupta

A Mn-porphyrin was contacted on Au(111) in a low-temperature scanning tunneling microscope (STM). Differential conductance spectra show a zero-bias resonance that is due to an underscreened Kondo effect according to many-body calculations.…

Single-cycle optical pulses with a controlled electromagnetic waveform allow to steer the motion of low-energy electrons in atoms, molecules, nanostructures or condensed-matter on attosecond dimensions in time. However, high-energy…

Optics · Physics 2020-11-11 Yuya Morimoto , Peter Baum

Scanning tunneling microscopy using a CO-functionalized tip is combined with simulations to explore the impact of the CO tilt angle on topographies of a single Cu atom and CO molecule adsorbed on Cu(111). Images of the Cu atom acquired with…

Materials Science · Physics 2024-09-24 Ivan Abilio , Nicolas Néel , Jörg Kröger , Krisztián Palotás

We investigate a pair entanglement of electrons in diatomic molecule, modeled as a correlated double quantum dot attached to the leads. The low-temperature properties are derived from the ground state obtained by utilizing the Rejec-Ramsak…

Strongly Correlated Electrons · Physics 2008-05-03 Adam Rycerz