English

Shifting the Voltage Drop in Electron Transport through a Single Molecule

Mesoscale and Nanoscale Physics 2015-07-03 v2 Strongly Correlated Electrons

Abstract

A Mn-porphyrin was contacted on Au(111) in a low-temperature scanning tunneling microscope (STM). Differential conductance spectra show a zero-bias resonance that is due to an underscreened Kondo effect according to many-body calculations. When the Mn center is contacted by the STM tip, the spectrum appears to invert along the voltage axis. A drastic change in the electrostatic potential of the molecule involving a small geometric relaxation is found to cause this observation.

Keywords

Cite

@article{arxiv.1506.04618,
  title  = {Shifting the Voltage Drop in Electron Transport through a Single Molecule},
  author = {Sujoy Karan and David Jacob and Michael Karolak and Christian Hamann and Yongfeng Wang and Alexander Weismann and Alexander I. Lichtenstein and Richard Berndt},
  journal= {arXiv preprint arXiv:1506.04618},
  year   = {2015}
}

Comments

8 pages, 8 figures (including supplemental material); accepted in Phys. Rev. Lett

R2 v1 2026-06-22T09:53:47.925Z