Related papers: Positive heat capacity in the microcanonical ensem…
Conventional thermo-statistics address infinite homogeneous systems within the canonical ensemble. However, some 170 years ago the original motivation of thermodynamics was the description of steam engines, i.e. boiling water. Its essential…
Nonequilibrium dynamics of a nonintegrable system without the eigenstate thermalization hypothesis is studied. It is shown that, in the thermodynamic limit, this model thermalizes after an arbitrary quantum quench at finite temperature,…
When two initially thermal many-body systems start interacting strongly, their transient states quickly become non-Gibbsian, even if the systems eventually equilibrate. To see beyond this apparent lack of structure during the transient…
We study the applicability of the finite temperature effective potential in the equation of motion of a homogeneous "misaligned" scalar condensate $\varphi$, and find important caveats that severely restrict its domain of validity: i:) the…
We consider the generic model of a finite-size quantum electron system connected to two (temperature and particle) reservoirs. The quantum open system is driven out of equilibrium by the presence of both a temperature and a chemical…
In this chapter we address the topic of quantum thermodynamics in the presence of additional observables beyond the energy of the system. In particular we discuss the special role that the generalized Gibbs ensemble plays in this theory,…
Electronic heat capacity was calculated for a mesoscopically disordered s-wave superconductor treated as a spatial ensemble of domains with a continuously varying superconducting properties. The domains are assumed to have sizes larger than…
The heat flow between a quantum system and its reservoir is analyzed when initially both are in a separable thermal state and asymptotically approach a correlated equilibrium. General findings are illustrated for specific systems and…
Local Shannon entropy lies at the heart of modern thermodynamics, with much discussion of trajectory-dependent entropy production. When taken at both boundaries of a process in phase space, it reproduces the second law of thermodynamics…
We consider the notion of thermal equilibrium for an individual closed macroscopic quantum system in a pure state, i.e., described by a wave function. The macroscopic properties in thermal equilibrium of such a system, determined by its…
It is well-known that equilibrium measures for uniformly hyperbolic dynamical systems have a local product structure, which plays an important role in their mixing properties. Existing proofs of this fact rely either on transfer operators…
A quantum system coupled to a bath at some fixed, finite temperature converges to its Gibbs state. This thermalization process defines a natural, physically-motivated model of quantum computation. However, whether quantum computational…
This paper is motivated by the recent paper M. Baldovin, S. Iubini, R. Livi and A. Vulpiani, Statistical mechanics of systems with negative temperature, arXiv:2103.12572. The authors suggest that negative absolute temperatures are…
At first glance, the title of this work seems to be improper. And the reason is well known. Since blackbody pressure depends only on temperature, one cannot take the derivative of the thermodynamic quantities with respect to one of them,…
The second Tisza-Callen postulate of equilibrium thermodynamics states that for any system exists a function of the system's extensive parameters, called entropy, defined for all equilibrium states and having the property that the values…
In this paper, we developed a thermodynamically consistent approach to account for the Gibbs energy of pure metallic element with thermal vacancy over wide temperature range. Taking body centered cubic (bcc) W for a demonstration, the…
For studying the thermodynamic properties of systems using statistical mechanics we propose an ensemble that lies in between the familiar canonical and microcanonical ensembles. From a comparative study of these ensembles we conclude that…
We show that for a two-dimensional gas of elastically interacting particles the thermoelectric efficiency reaches the Carnot efficiency in the thermodynamic limit. Numerical simulations, by means of the multi-particle collision dynamics…
The proper definition of entropy is fundamental to the relationship between statistical mechanics and thermodynamics. It also plays a major role in the recent debate about the validity of the concept of negative temperature. In this paper,…
We propose a novel witness of temporal quantum entanglement using the imaginary component of the complex heat capacity - a measurable thermodynamic quantity in temperature-modulated calorimetry. By establishing a direct correspondence…