Related papers: Positive heat capacity in the microcanonical ensem…
Systems with long-range as well with short-range interactions should necessarily have a convex entropy S(E) at proper phase transitions of first order, i.e. when a separation of phases occurs. Here the microcanonical heat capacity c(E)=…
It is shown that negative heat capacity in nanoclusters is an artifact of applying equilibrium thermodynamic formalism on a small system trapped out of equilibrium in a particular structural motif representing only part of the energetically…
Thermodynamics dictates that the specific heat of a system is strictly non-negative. However, in finite classical systems there are well known theoretical and experimental cases where this rule is violated, in particular finite atomic…
It is shown that there is no proof of negativity of specific heat of the system placed in thermostat. It is proved that for the system of particles placed in the thermostat and interacting with each other via uniform potential energy the…
Heat capacities of model systems with finite numbers of effective degrees of freedom are evaluated using canonical and microcanonical thermodynamics. Discrepancies between both approaches, which are observed even in the infinite-size limit,…
We study non-canonical relaxation in a composite cold atoms system, consisting of subsystems that possess negative microcanonical specific heat. The system exhibits pre-thermalization far away from integrability due to the appearance of a…
We show that the vacuum (zero-point) energy of a low-temperature quantum liquid is a variable property which changes with the state of the system, in notable contrast to the static vacuum energy in solids commonly considered. We further…
The limit of small entropy production is reached in relaxing systems long after preparation, and in stationary driven systems in the limit of small driving power. Surprisingly, for extended systems this limit is not in general the…
We demonstrate that the presence of entanglement in macroscopic bodies (e.g. solids) in thermodynamical equilibrium could be revealed by measuring heat-capacity. The idea is that if the system were in a separable state, then for certain…
Very recently, the validity of the concept of negative temperature has been challenged by several authors since they consider Boltzmann's entropy (that allows negative temperatures) inconsistent from a mathematical and statistical point of…
Recently, we have derived a generalization of the known canonical fluctuation relation $k_{B}C=\beta^{2}< \delta U^{2} >$ between heat capacity $C$ and energy fluctuations, which can account for the existence of macrostates with negative…
A Hamiltonian model living in a bounded phase space and with long-range interactions is studied. It is shown, by analytical computations, that there exists an energy interval in which the microcanonical entropy is a decreasing convex…
In this paper we study macroscopic thermodynamic properties of a stochastic microscopic heat conduction model that is reduced from deterministic problems. Our goal is to numerically check how the `low energy site effect' inherited from the…
We study the capacity of entanglement in the microcanonical ensemble for an effectively additive bipartite system. Using typicality and the block structure of the microcanonical reduced state, we show that in the thermodynamic regime the…
Small systems consisting of a few particles are increasingly technologically relevant. In such systems, an intense debate in microcanonical statistical mechanics has been about the correctness of Boltzmann's surface entropy versus Gibbs'…
Depending on the exact experimental conditions, the thermodynamic properties of physical systems can be related to one or more thermostatistical ensembles. Here, we survey the notion of thermodynamic temperature in different statistical…
According to thermodynamics, the specific heat of Boltzmannian short-range interacting systems is a positive quantity. Less intuitive properties are instead displayed by systems characterized by long-range interactions. In that case, the…
Steady nonequilibria dissipate energy and, when changing external parameters, an extra or excess heat accompanies the relaxation to the new nonequilibrium condition. For nonequilibrium systems in contact with a thermal bath, the heat…
We show how to extend the concept of heat capacity to nonequilibrium systems. The main idea is to consider the excess heat released by an already dissipative system when slowly changing the environment temperature. We take the framework of…
Development of steady state thermodynamics and statistical mechanics depends crucially on our ability to develop notions of equilibrium thermodynamics for nonequilibrium steady states (NESS). The present paper considers the development of…